Chances Ad ~stract one 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $4th total Statistical pro 21 total 2 H A 2H 래 • 4H totul < 3°C-H werkest bund - abstraction he leads to then mo fac a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? рос 6 -વા J Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl
Chances Ad ~stract one 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $4th total Statistical pro 21 total 2 H A 2H 래 • 4H totul < 3°C-H werkest bund - abstraction he leads to then mo fac a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? рос 6 -વા J Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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