Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 13, Problem 13.2E
Interpretation Introduction
Interpretation:
The general formula for ether, emphasizing the
Concept introduction:
The most important organic compounds include ethers. They occur naturally or can be obtained synthetically also. They are used for industrial and pharmaceutical purposes. An alcoholic functional group is present in alcohols and phenols.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
200
160
120
80
40
0
200
160
120
80
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0
DEPT 135
T
200
160
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Draw the unknown amide.
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Chapter 13 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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