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Interpretation: The Lewis structures of the small compounds have to be found by using their Lewis dot structures of involving atoms and by following the octet rule.
Concept introduction: The arrangement of atoms that are bonded together determines its constitution and molecular formula of that particular compound. This concept is referred as structural isomers or in more modern term constitutional isomers. Each atom has a typical valency or valence which is defined as the ability of an atom to form a chemical bond with other atoms. For example, carbon has four valence or tetravalent that means carbon has the capacity to form four bonds with other elements or other atoms. Nitrogen atom is trivalent. Hydrogen is monovalent in nature.
Lewis dot structures are also called electron dot structures. The diagrams are named after Gilbert N. Lewis, who described them in his 1916 article entitled The Atom and the Molecule. The number of electrons present in the outermost shell of an atom that participate in forming
The Lewis structure of small compounds can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound. In order to achieve complete noble gas configuration, octet rule is followed to find bonding nature of atoms. Octet means 8 electrons in their valence shells. The compounds which obey the octet rule are called stable compounds.
To find: The four constitutional isomers of C3H9N, their Lewis structures and the number of lone pair of electrons on the nitrogen atom in each isomer
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Chapter 1 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
- Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? H Br H Br (S) CH3 (R) CH3 H3C (S) H3C H Br Br H A C enantiomers H Br H Br (R) CH3 H3C (R) (S) CH3 H3C H Br Br H B D identicalarrow_forward2. Histamine (below structure) is a signal molecule involved in immune response and is a neurotransmitter. Histamine features imidazole ring which is an aromatic heterocycle. Please answer the following questions regarding Histamine. b a HN =N C NH2 a. Determine hybridization of each N atom (s, p, sp, sp², sp³, etc.) in histamine N-a hybridization: N-b hybridization: N-c hybridization: b. Determine what atomic orbitals (s, p, sp, sp², sp³, etc.) of the lone pair of each N atom resided in N-a hybridization: N-b hybridization: N-c hybridization:arrow_forwardNonearrow_forward
- 29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or forbidden. +arrow_forward30.0 mL of 0.10 mol/L iron sulfate and 20.0 mL of 0.05 mol/L of silver nitrate solutions are mixed together. Justify if any precipitate would formarrow_forwardDoes the carbonyl group first react with the ethylene glycol, in an intermolecular reaction, or with the end alcohol, in an intramolecular reaction, to form a hemiacetal? Why does it react with the alcohol it does first rather than the other one? Please do not use an AI answer.arrow_forward
- The number of noncyclic isomers that have the composition C4H8Owith the O as part of an OH group, counting a pair of stereoisomers as1, is A. 8; B. 6; C. 9; D. 5; E. None of the other answers is correct.arrow_forwardNonearrow_forwardThe number of carbon skeletons that have 8 carbons, one of which istertiary is A. 7; B. More than 7; C. 6; D. 5; E. 4arrow_forward
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