Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 1, Problem 42PP
Interpretation Introduction
Interpretation:
Constitutional isomer need to be found out for cyclopropane
Concept introduction:
Constitutional isomers are the compounds which have same molecular formula but differ in connectivity between the atoms present in it.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
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52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
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80
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140
160
180
200 220
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99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
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169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
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200.
784
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2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
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4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 1 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
Ch. 1.2 - Prob. 1LTSCh. 1.2 - Prob. 1PTSCh. 1.2 - Prob. 2ATSCh. 1.2 - Prob. 3ATSCh. 1.2 - Prob. 4ATSCh. 1.3 - Prob. 2LTSCh. 1.3 - Prob. 5PTSCh. 1.3 - Prob. 6ATSCh. 1.3 - Prob. 7ATSCh. 1.3 - Prob. 8ATS
Ch. 1.3 - Prob. 9ATSCh. 1.3 - Prob. 3LTSCh. 1.3 - Prob. 10PTSCh. 1.3 - Prob. 11ATSCh. 1.3 - Prob. 12ATSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 13PTSCh. 1.4 - Prob. 14ATSCh. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 15PTSCh. 1.5 - Prob. 16ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 17PTSCh. 1.6 - Prob. 18ATSCh. 1.9 - Prob. 19CCCh. 1.9 - Prob. 20CCCh. 1.9 - Prob. 21CCCh. 1.9 - Prob. 7LTSCh. 1.9 - Prob. 22PTSCh. 1.9 - Prob. 23ATSCh. 1.9 - Prob. 24CCCh. 1.10 - Prob. 8LTSCh. 1.10 - Prob. 25PTSCh. 1.10 - Prob. 26PTSCh. 1.10 - Prob. 27ATSCh. 1.10 - Prob. 28ATSCh. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 29PTSCh. 1.11 - Prob. 30ATSCh. 1.11 - Prob. 31ATSCh. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 32PTSCh. 1.12 - Prob. 33ATSCh. 1 - Prob. 34PPCh. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 43PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Prob. 55PPCh. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 58PPCh. 1 - Prob. 59PPCh. 1 - Prob. 60PPCh. 1 - Prob. 61PPCh. 1 - Prob. 62PPCh. 1 - Prob. 63IPCh. 1 - Prob. 67IPCh. 1 - Prob. 68IPCh. 1 - Prob. 69IPCh. 1 - Prob. 70CPCh. 1 - Prob. 71CPCh. 1 - Prob. 72CPCh. 1 - Prob. 73CPCh. 1 - Prob. 74CPCh. 1 - Prob. 75CPCh. 1 - Prob. 76CPCh. 1 - Prob. 77CP
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