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Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Decide the large dipole moment value for a compound in a given pair of compounds
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Chapter 1 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
- X Draw the major products of the elimination reaction below. If elimination would not occur at a significant rate, check the box under the drawing area instead. ది www. Cl + OH Elimination will not occur at a significant rate. Click and drag to start drawing a structure.arrow_forwardNonearrow_forward1A H 2A Li Be Use the References to access important values if needed for this question. 8A 3A 4A 5A 6A 7A He B C N O F Ne Na Mg 3B 4B 5B 6B 7B 8B-1B 2B Al Si P 1B 2B Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe * Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Ha ****** Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Analyze the following reaction by looking at the electron configurations given below each box. Put a number and a symbol in each box to show the number and kind of the corresponding atom or ion. Use the smallest integers possible. cation anion + + Shell 1: 2 Shell 2: 8 Shell 3: 1 Shell 1 : 2 Shell 2 : 6 Shell 1 : 2 Shell 2: 8 Shell 1: 2 Shell 2: 8arrow_forward
- Nonearrow_forwardIV. Show the detailed synthesis strategy for the following compounds. a. CH3CH2CH2CH2Br CH3CH2CCH2CH2CH3arrow_forwardDo the electrons on the OH participate in resonance with the ring through a p orbital? How many pi electrons are in the ring, 4 (from the two double bonds) or 6 (including the electrons on the O)?arrow_forward
- Predict and draw the product of the following organic reaction:arrow_forwardNonearrow_forwardRedraw the molecule below as a skeletal ("line") structure. Be sure to use wedge and dash bonds if necessary to accurately represent the direction of the bonds to ring substituents. Cl. Br Click and drag to start drawing a structure. : ☐ ☑ Parrow_forward
- K m Choose the best reagents to complete the following reaction. L ZI 0 Problem 4 of 11 A 1. NaOH 2. CH3CH2CH2NH2 1. HCI B OH 2. CH3CH2CH2NH2 DII F1 F2 F3 F4 F5 A F6 C CH3CH2CH2NH2 1. SOCl2 D 2. CH3CH2CH2NH2 1. CH3CH2CH2NH2 E 2. SOCl2 Done PrtScn Home End FA FQ 510 * PgUp M Submit PgDn F11arrow_forwardNonearrow_forwardPlease provide a mechanism of synthesis 1,4-diaminobenzene, start from a benzene ring.arrow_forward
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