Organic And Biological Chemistry
7th Edition
ISBN: 9781305638686
Author: H. Stephen Stoker
Publisher: Brooks Cole
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Chapter 12.9, Problem 2QQ
Interpretation Introduction
Interpretation: To determine the number of proton transfer across the inner mitochondrial membrane that is effected by one NADH molecule in the electron transport chain.
Concept introduction: Oxidative phosphorylation is the biochemical process for the synthesis of ATP from ADP and
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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
Chapter 12 Solutions
Organic And Biological Chemistry
Ch. 12.1 - Prob. 1QQCh. 12.1 - Prob. 2QQCh. 12.2 - Which of the following is not found within the...Ch. 12.2 - Which of the following is not an organelle? a....Ch. 12.2 - Prob. 3QQCh. 12.2 - Which of the following statements about...Ch. 12.3 - Prob. 1QQCh. 12.3 - Prob. 2QQCh. 12.3 - Which of the following statements concerning...Ch. 12.3 - Which of the following statements concerning...
Ch. 12.3 - Which of the following statements concerning...Ch. 12.4 - Prob. 1QQCh. 12.4 - Prob. 2QQCh. 12.5 - Prob. 1QQCh. 12.5 - Prob. 2QQCh. 12.5 - Prob. 3QQCh. 12.6 - Which of the following occurs in the second stage...Ch. 12.6 - Which of the following stages in the biochemical...Ch. 12.6 - Prob. 3QQCh. 12.7 - Prob. 1QQCh. 12.7 - Prob. 2QQCh. 12.7 - Prob. 3QQCh. 12.7 - How many NADH and FADH2 molecules are produced,...Ch. 12.7 - Which of the following citric acid cycle...Ch. 12.7 - In which of the following listings of citric acid...Ch. 12.8 - Which of the following is a fuel for the electron...Ch. 12.8 - Which of the following is a mobile electron...Ch. 12.8 - What is the substrate that initially interacts...Ch. 12.8 - The number of fixed enzyme sites in the electron...Ch. 12.8 - Prob. 5QQCh. 12.8 - In which step in the electron transport chain does...Ch. 12.9 - Prob. 1QQCh. 12.9 - Prob. 2QQCh. 12.9 - Prob. 3QQCh. 12.10 - Prob. 1QQCh. 12.10 - Prob. 2QQCh. 12.11 - Prob. 1QQCh. 12.11 - Prob. 2QQCh. 12.11 - Prob. 3QQCh. 12.12 - How many different B vitamins participate in the...Ch. 12.12 - Prob. 2QQCh. 12 - Classify anabolism and catabolism as synthetic or...Ch. 12 - Classify anabolism and catabolism as...Ch. 12 - What is a metabolic pathway?Ch. 12 - Prob. 12.4EPCh. 12 - Classify each of the following processes as...Ch. 12 - Prob. 12.6EPCh. 12 - Prob. 12.7EPCh. 12 - Prob. 12.8EPCh. 12 - Prob. 12.9EPCh. 12 - Indicate whether each of the following statements...Ch. 12 - Prob. 12.11EPCh. 12 - Prob. 12.12EPCh. 12 - Prob. 12.13EPCh. 12 - Prob. 12.14EPCh. 12 - Prob. 12.15EPCh. 12 - Prob. 12.16EPCh. 12 - Prob. 12.17EPCh. 12 - Prob. 12.18EPCh. 12 - Prob. 12.19EPCh. 12 - Prob. 12.20EPCh. 12 - Prob. 12.21EPCh. 12 - Prob. 12.22EPCh. 12 - Prob. 12.23EPCh. 12 - Write a generalized chemical equation, containing...Ch. 12 - Prob. 12.25EPCh. 12 - Prob. 12.26EPCh. 12 - Prob. 12.27EPCh. 12 - Prob. 12.28EPCh. 12 - Prob. 12.29EPCh. 12 - Prob. 12.30EPCh. 12 - Prob. 12.31EPCh. 12 - Prob. 12.32EPCh. 12 - Prob. 12.33EPCh. 12 - Prob. 12.34EPCh. 12 - What identical structural subunits do the...Ch. 12 - Prob. 12.36EPCh. 12 - Prob. 12.37EPCh. 12 - Prob. 12.38EPCh. 12 - Prob. 12.39EPCh. 12 - Prob. 12.40EPCh. 12 - Prob. 12.41EPCh. 12 - Prob. 12.42EPCh. 12 - Classify each of the following molecules as (1) an...Ch. 12 - Prob. 12.44EPCh. 12 - Prob. 12.45EPCh. 12 - Prob. 12.46EPCh. 12 - Prob. 12.47EPCh. 12 - Prob. 12.48EPCh. 12 - Prob. 12.49EPCh. 12 - Prob. 12.50EPCh. 12 - Prob. 12.51EPCh. 12 - Prob. 12.52EPCh. 12 - Prob. 12.53EPCh. 12 - Prob. 12.54EPCh. 12 - Prob. 12.55EPCh. 12 - Prob. 12.56EPCh. 12 - Prob. 12.57EPCh. 12 - Prob. 12.58EPCh. 12 - List, by name, the four general stages of the...Ch. 12 - Which, by name, of the four general stages of the...Ch. 12 - Prob. 12.61EPCh. 12 - Prob. 12.62EPCh. 12 - Prob. 12.63EPCh. 12 - Prob. 12.64EPCh. 12 - Prob. 12.65EPCh. 12 - Prob. 12.66EPCh. 12 - Prob. 12.67EPCh. 12 - Prob. 12.68EPCh. 12 - Prob. 12.69EPCh. 12 - Prob. 12.70EPCh. 12 - Prob. 12.71EPCh. 12 - Prob. 12.72EPCh. 12 - Prob. 12.73EPCh. 12 - Prob. 12.74EPCh. 12 - Prob. 12.75EPCh. 12 - Prob. 12.76EPCh. 12 - Prob. 12.77EPCh. 12 - Prob. 12.78EPCh. 12 - Prob. 12.79EPCh. 12 - Prob. 12.80EPCh. 12 - Prob. 12.81EPCh. 12 - Prob. 12.82EPCh. 12 - Prob. 12.83EPCh. 12 - Prob. 12.84EPCh. 12 - Prob. 12.85EPCh. 12 - Prob. 12.86EPCh. 12 - Prob. 12.87EPCh. 12 - Prob. 12.88EPCh. 12 - Prob. 12.89EPCh. 12 - Indicate whether each of the following changes...Ch. 12 - Prob. 12.91EPCh. 12 - Prob. 12.92EPCh. 12 - Prob. 12.93EPCh. 12 - Prob. 12.94EPCh. 12 - Prob. 12.95EPCh. 12 - Prob. 12.96EPCh. 12 - Prob. 12.97EPCh. 12 - Prob. 12.98EPCh. 12 - Prob. 12.99EPCh. 12 - Prob. 12.100EPCh. 12 - Prob. 12.101EPCh. 12 - Prob. 12.102EPCh. 12 - Prob. 12.103EPCh. 12 - Prob. 12.104EPCh. 12 - Prob. 12.105EPCh. 12 - Prob. 12.106EPCh. 12 - Prob. 12.107EPCh. 12 - Prob. 12.108EPCh. 12 - Prob. 12.109EPCh. 12 - Prob. 12.110EPCh. 12 - Prob. 12.111EPCh. 12 - Prob. 12.112EPCh. 12 - Prob. 12.113EPCh. 12 - Prob. 12.114EPCh. 12 - Prob. 12.115EPCh. 12 - Prob. 12.116EPCh. 12 - Prob. 12.117EPCh. 12 - Prob. 12.118EPCh. 12 - Prob. 12.119EPCh. 12 - Prob. 12.120EPCh. 12 - Prob. 12.121EPCh. 12 - Prob. 12.122EPCh. 12 - Prob. 12.123EPCh. 12 - Prob. 12.124EPCh. 12 - Prob. 12.125EPCh. 12 - Prob. 12.126EPCh. 12 - Prob. 12.127EPCh. 12 - Prob. 12.128EPCh. 12 - Indicate whether or not each of the following B...Ch. 12 - Prob. 12.130EPCh. 12 - Prob. 12.131EPCh. 12 - Prob. 12.132EP
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