CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
7th Edition
ISBN: 9781119497325
Author: JESPERSEN
Publisher: WILEY
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Chapter 12, Problem 29PE
Calculate the freezing point of aqueous
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Chapter 12 Solutions
CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
Ch. 12 - Which substances will be soluble in water? (a)...Ch. 12 - Which substances will be soluble in nonpolar...Ch. 12 - Draw an enthalpy diagram for the endothermic...Ch. 12 - When potassium hydroxide is dissolved in water,...Ch. 12 - Prob. 5PECh. 12 - When sodium hydroxide is dissolved in water, the...Ch. 12 - At 25C and standard pressure, a hydrogen sulfide...Ch. 12 - How many grams of nitrogen and oxygen are...Ch. 12 - What volume of water at 20.0C(d=0.9982gmL-1) is...Ch. 12 - Prob. 10PE
Ch. 12 - Prob. 11PECh. 12 - Water freezes at a lower temperature when it...Ch. 12 - Prob. 13PECh. 12 - Prob. 14PECh. 12 - Prob. 15PECh. 12 - Prob. 16PECh. 12 - Dibutyl phthalate, C16H22O4 (molar mass...Ch. 12 - Prob. 18PECh. 12 - At , the vapor pressure of cyclohexane, a nonpolar...Ch. 12 - Using the information from Practice Exercise...Ch. 12 - In making candy, a certain recipe calls for...Ch. 12 - How many grams of glucose (molar mass = 180.9 g...Ch. 12 - A solution made by dissolving 3.46 g of an unknown...Ch. 12 - Prob. 24PECh. 12 - What is the osmotic pressure, in mm Hg and mm H2O,...Ch. 12 - What is the osmotic pressure in torr of a 0.0115 M...Ch. 12 - Estimate the molecular mass of a protein when...Ch. 12 - Prob. 28PECh. 12 - Calculate the freezing point of aqueous 0.237mLiCl...Ch. 12 - Determine the freezing point of aqueous solutions...Ch. 12 - Prob. 31PECh. 12 - Prob. 32PECh. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Prob. 7RQCh. 12 - Intermolecular Forces and the Formation of...Ch. 12 - Heats of Solution
12.9 The value of for a soluble...Ch. 12 - Heats of Solution Referring to Question 12.9,...Ch. 12 - Heats of Solution Which would be expected to have...Ch. 12 - Heats of Solution
12.12. Suggest a reason why the...Ch. 12 - Prob. 13RQCh. 12 - Prob. 14RQCh. 12 - Heat of solution When a certain solid dissolves in...Ch. 12 - Heat of solution
12.16 If the value of for the...Ch. 12 - Prob. 17RQCh. 12 - Solubility as a Function of Temperature
12.18 If a...Ch. 12 - Solubility as a Function of Temperature Anglers...Ch. 12 - Henry's Law
12.20 What is Henry’s law?
Ch. 12 - Henry's Law
12.21 Mountain streams often contain...Ch. 12 - Henry's Law Why is ammonia so much more soluble in...Ch. 12 - Prob. 23RQCh. 12 - Prob. 24RQCh. 12 - Prob. 25RQCh. 12 - Prob. 26RQCh. 12 - Concentration Units Suppose a 1.0 m solution of a...Ch. 12 - Colligative Properties What specific fact about a...Ch. 12 - Colligative Properties
12.29. What is Raoult’s...Ch. 12 - Colligative Properties Why does a nonvolatile...Ch. 12 - Prob. 31RQCh. 12 - Prob. 32RQCh. 12 - Prob. 33RQCh. 12 - Prob. 34RQCh. 12 - Prob. 35RQCh. 12 - Prob. 36RQCh. 12 - Prob. 37RQCh. 12 - Prob. 38RQCh. 12 - Colligative Properties
12.39 When a solid is...Ch. 12 - Colligative Properties
12.40 What is the...Ch. 12 - Prob. 41RQCh. 12 - Colligative Properties What is the vant Hoff...Ch. 12 - Prob. 43RQCh. 12 - Prob. 44RQCh. 12 - Prob. 45RQCh. 12 - Prob. 46RQCh. 12 - Heterogeneous Mixtures What is the Tyndall effect?Ch. 12 - Heterogeneous Mixtures
12.48 What is a micelle,...Ch. 12 - Heat of Solution For an ionic compound dissolving...Ch. 12 - Heat of solution
12.50 Consider the formation of a...Ch. 12 - Henry's Law The solubility of methane, the chief...Ch. 12 - Henry's Law If the solubility of a gas in water is...Ch. 12 - At 740 torr and 20.0C, nitrogen has a solubility...Ch. 12 - Hydrogen gas has a solubility in water of...Ch. 12 - 12.55. If 100.0 mL of water is shaken with oxygen...Ch. 12 - 12.56 Helium gas can be used to displace other...Ch. 12 - Concentration Units Muriatic acid is the...Ch. 12 - Prob. 58RQCh. 12 - What mass of a 0.853 molal solution of iron(III)...Ch. 12 - In order to conduct three experiments that...Ch. 12 - Prob. 61RQCh. 12 - A solution of acetic acid, CH3COOH, has a...Ch. 12 - Prob. 63RQCh. 12 - Botulinum toxin is one of the most acutely toxic...Ch. 12 - A solution of fructose, C6H12O6, a sugar found in...Ch. 12 - Prob. 66RQCh. 12 - Prob. 67RQCh. 12 - Prob. 68RQCh. 12 - Prob. 69RQCh. 12 - An aqueous solution of isopropyl alcohol, C3H8O,...Ch. 12 - Sodium nitrate, NaNO3, is sometimes added to...Ch. 12 - In an aqueous solution of sulfuric acid, the...Ch. 12 - Colligative Properties At 25C, the vapor pressure...Ch. 12 - Colligative Properties The vapor pressure of water...Ch. 12 - 12.75 At the vapor pressures of benzene and...Ch. 12 - Pentane (C5HI2)andheptane(C7HI6) are two...Ch. 12 - *12.77 Benzene and toluene help achieve good...Ch. 12 - The vapor pressure of pure methanol, CH3OH, at 33C...Ch. 12 - A solution containing 8.3 g of a nonvolatile,...Ch. 12 - At 21.0C, a solution of 18.26 g of a nonvolatile,...Ch. 12 - 12.81 How many grams of sucrose are needed to...Ch. 12 - Prob. 82RQCh. 12 - A solution of 12.00 g of an unknown...Ch. 12 - 12.84 A solution of 14 g of a nonvolatile,...Ch. 12 - What are the molecular mass and molecular formula...Ch. 12 - Benzene reacts with hot concentrated nitric acid...Ch. 12 - 12.87 (a) Show that the following equation is...Ch. 12 - A saturated solution is made by dissolving 0.400 g...Ch. 12 - Prob. 89RQCh. 12 - How many grams of A1C13 would have to be dissolved...Ch. 12 - 12.91 What is the osmotic pressure, in torr, of a ...Ch. 12 - Below are the concentrations of the most abundant...Ch. 12 - 12.93 What is the expected freezing point of a...Ch. 12 - Prob. 94RQCh. 12 - 12.95 The van’t Hoff factor for the solute in is...Ch. 12 - 12.96 What is the expected van’t Hoff factor for ...Ch. 12 - Prob. 97RQCh. 12 - *12.98 The “bends” is a medical emergency caused...Ch. 12 - In order for mosquitos to survive the cold winter,...Ch. 12 - The vapor pressure of a mixture of 0.400 kg of...Ch. 12 - Ethylene glycol, C2H6O2, is used in many...Ch. 12 - What is the osmotic pressure in torr of a 0.010 M...Ch. 12 - The osmotic pressure of a dilute solution of a...Ch. 12 - Prob. 104RQCh. 12 - Consider an aqueous 1.00 m solution of Na3PO4,a...Ch. 12 - A 2.50 g sample of aluminum chloride and sodium...Ch. 12 - Prob. 107RQCh. 12 - A sample containing only iron(II) nitrate and...Ch. 12 - Prob. 109RQCh. 12 - Prob. 110RQCh. 12 - How many mL of 0.223MK2Cr2O7 are needed to...Ch. 12 - Prob. 112RQCh. 12 - A certain organic substance is soluble in solvent...Ch. 12 - Prob. 114RQCh. 12 - Prob. 115RQCh. 12 - Having had some laboratory experience by now,...Ch. 12 - 12.117 This chapter focused on the physical...Ch. 12 - 12.118 Using the principles developed in this...Ch. 12 - Prob. 119RQCh. 12 - Prob. 120RQCh. 12 - Prob. 121RQCh. 12 - Consider a solution that has the maximum amount of...Ch. 12 - 12.123 When a 10.0 molar solution of sodium...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Temperature influences solubility. Does temperature have the same effect on all substances? Justify your answer. (Hint: Consider Le Chateliers principle.)arrow_forwardThe freezing point of 0.109 m aqueous formic acid is 0.210C. Formic acid, HCHO2, is partially dissociated according to the equation HCHO2(aq)H+(aq)+CHO2(aq) Calculate the percentage of HCHO2 molecules that are dissociated, assuming the equation for the freezing-point depression holds for the total concentration of molecules and ions in the solution.arrow_forwardA 0.109 mol/kg aqueous solution of formic acid, HCOOH, freezes at −0.210 °C. Calculate the percent dissociation of formic acid.arrow_forward
- Vapor-pressure lowering is a colligative property, as are freezing-point depression and boiling-point elevation. What is a colligative property? Why is the freezing point depressed for a solution as compared to the pure solvent? Why is the boiling point elevated for a solution as compared to the pure solvent? Explain how to calculate T for a freezing-point depression problem or a boiling-point elevation problem. Of the solvents listed in Table 10-5, which would have the largest freezing-point depression for a 0.50 molal solution? Which would have the smallest boiling-point elevation for a 0.50 molal solution? A common application of freezing-point depression and boiling-point elevation experiments is to provide a means to calculate the molar mass of a nonvolatile solute. What data are needed to calculate the molar mass of a nonvolatile solute? Explain how you would manipulate these data to calculate the molar mass of the nonvolatile solute.arrow_forwardFreezing point depression is one means of determining the molar mass of a compound. The freezing point depression constant of benzene is 5.12 C/m. a. When a 0.503 g sample of the white crystalline dimer is dissolved in 10.0 g benzene, the freezing point of benzene is decreased by 0542 C. Verify that the molar mass of the dimer is 475 g/mol when determined by freezing point depression. Assume no dissociation of the dimer occurs. b. The correct molar mass of the dimer is 487 g/mol. Explain why the dissociation equilibrium causes the freezing point depression calculation to yield a lower molar mass for the dimer.arrow_forwardA patient has a “cholesterol count” of 214. Like manyblood-chemistry measurements,this result is measured inunits of milligrams per deciliter (mgdL1). Determine the molar concentration of cholesterol inthis patient’s blood, taking the molar mass of cholesterolto be 386.64gmol1. Estimate the molality of cholesterol in the patient’sblood. If 214 is a typical cholesterol reading among men inthe United States, determine the volume of such bloodrequired to furnish 8.10 g of cholesterol.arrow_forward
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