ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 12, Problem 29P , additional homework tip  1

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methyl propane.

(b)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 12, Problem 29P , additional homework tip  2

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL, Chapter 12, Problem 29P , additional homework tip  3

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

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Chapter 12 Solutions

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