ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 12, Problem 12.42P
Interpretation Introduction
Interpretation: The structure of two different
Concept introduction: The metal hydride reagents are good reducing agents such as
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19. Complete the following chart for the incorrect electron configurations shown in the left column.
When drawing the correct electron configuration, assume the same number of electrons that were
shown in the incorrect configuration.
Incorrect Electron
Configuration
2p
↑↓ ↑
2s
↑↓
1s
↑↓↓
ਵੇ ਵੇ ਵੇ
3p
↑
↑
↑
-
38
↑
2p
2s
↑↓
1s
2p
2s
1s
**
↑↓ ↑↓ ↑↑
리리리
Which principle or
rule is violated?
Explain the violated principle
or rule in your own words
Draw the correct
electron configuration
14.36 Draw all reasonable resonance structures for each compound.
a.
+
b.
C.
:O:
d.
:O:
NH2
NH2
:O:
Chapter 12 Solutions
ORGANIC CHEMISTRY
Ch. 12 - Prob. 12.1PCh. 12 - Problem 12.2 What alkane is formed when each...Ch. 12 - Prob. 12.3PCh. 12 - Prob. 12.4PCh. 12 - Prob. 12.5PCh. 12 - Prob. 12.6PCh. 12 - Compound Molecular formula before...Ch. 12 - Problem 12.8 Draw the products formed when...Ch. 12 - Prob. 12.9PCh. 12 - Prob. 12.10P
Ch. 12 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Problem 12.14 Draw the products of each...Ch. 12 - Prob. 12.15PCh. 12 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12 - Prob. 12.17PCh. 12 - Problem 12.18 Draw the products formed when both...Ch. 12 - Problem 12.19 Draw the products formed when each...Ch. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - Problem 12.22 Draw the products formed when each...Ch. 12 - Prob. 12.23PCh. 12 - Problem 12.24 Draw the organic products in each of...Ch. 12 - Prob. 12.25PCh. 12 - Prob. 12.26PCh. 12 - Problem 12.27 Draw the products of each Sharpless...Ch. 12 - Prob. 12.28PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 12.30PCh. 12 - 12.31 Devise a synthesis of the following compound...Ch. 12 - Prob. 12.32PCh. 12 - Prob. 12.33PCh. 12 - Prob. 12.34PCh. 12 - Prob. 12.35PCh. 12 - Prob. 12.36PCh. 12 - 12.37 Stearidonic acid (C18H28O2) is an...Ch. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Draw the organic products formed in each reaction....Ch. 12 - Prob. 12.41PCh. 12 - Prob. 12.42PCh. 12 - Prob. 12.43PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - Prob. 12.45PCh. 12 - 12.46 (a)What product is formed in Step [1] of the...Ch. 12 - Draw the products formed after Steps 1 and 2 in...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 12.50PCh. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Prob. 12.53PCh. 12 - 12.54 An unknown compound A of molecular formula ...Ch. 12 - 12.55 DHA is a fatty acid derived from fish oil...Ch. 12 - Prob. 12.56PCh. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.58 Epoxidation of the following allylic alcohol...Ch. 12 - Prob. 12.59PCh. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 12.61PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 12.64PCh. 12 - Prob. 12.65PCh. 12 - 12.66 Devise a synthesis of each compound from the...Ch. 12 - Prob. 12.67PCh. 12 - Prob. 12.68PCh. 12 - 12.69 Devise a synthesis of each compound from as...Ch. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - 12.72 Draw a stepwise mechanism for the following...Ch. 12 - Prob. 12.73PCh. 12 - Prob. 12.74PCh. 12 - 12.75 Sharpless epoxidation of allylic alcohol X...
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- 14.32 What diene and dienophile are needed to prepare each compound by a Diels-Alder reaction? a. b.arrow_forward14.34 Draw all reasonable resonance structures for each species. a. b. Ö :0: C. :0: :0: d. OH e. f. :O:arrow_forward7. The standard reduction potentials for two half-reactions are shown above. Which of the statements listed below will be true for the following reaction taking place under standard conditions? a. E° b. E° c. E° = d. E° e. E° = Al (s) + Cr³+ → Al³+ + Cr (s) 0.93 V, and the reaction is not spontaneous 0.93 V, and the reaction is spontaneous 2.39 V, and the reaction is not spontaneous 2.39 V, and the reaction is not spontaneous 0.93 V, and the reaction is spontaneous Cu2+ + 2e → Cu E° = +0.34 V Zn2+ + 2e → Zn E° = -0.76 V E° = -1.18 V Mn2+ + 2e → Mn 8. Based on the above reduction potential, which of the following reactions will occur spontaneously? a. Mn²+ + Cu → Mn + Cu2+ b. Mn²+ + Zn → Mn + Zn²+ c. Zn2+ + Cu → Zn + Cu²+ d. Zn²+ + Mn → Zn + Mn2+ e. Cu²+ + Zn²+ → Cu + Znarrow_forward
- 14.35 For which compounds can a second resonance structure be drawn? Draw an additional resonance structure and the hybrid for each resonance-stabilized compound. a. OCH3 OCH 3 b. C. d. CH3 NHCH3arrow_forwardpls help on all, inlcude all steps.arrow_forwardpls help on all, inlcude all steps.arrow_forward
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