Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 12, Problem 12.23P
Interpretation Introduction

(a)

Interpretation: The alkyne which yields the given oxidative cleavage products is to be predicted.

Concept introduction: In presence of ozone and H2O, oxidative cleavage occurs in alkynes. In oxidative cleavage both the sigma and pi bonds of the alkyne is broken. In case of terminal alkynes, carboxylic acid and carbon dioxide is formed while in case of internal alkynes, only carboxylic acids are formed.

Interpretation Introduction

(b)

Interpretation: The alkyne which yields the given oxidative cleavage products is to be predicted.

Concept introduction: In presence of ozone and H2O, oxidative cleavage occurs in alkynes. In oxidative cleavage both the sigma and pi bonds of the alkyne is broken. In case of terminal alkynes, carboxylic acid and carbon dioxide is formed while in case of internal alkynes, only carboxylic acids are formed.

Interpretation Introduction

(c)

Interpretation: The alkyne which yields the given oxidative cleavage products is to be predicted.

Concept introduction: In presence of ozone and H2O, oxidative cleavage occurs in alkynes. In oxidative cleavage both the sigma and pi bonds of the alkyne is broken. In case of terminal alkynes, carboxylic acid and carbon dioxide is formed while in case of internal alkynes, only carboxylic acids are formed.

Interpretation Introduction

(d)

Interpretation: The alkyne which yields the given oxidative cleavage products is to be predicted.

Concept introduction: In presence of ozone and H2O, oxidative cleavage occurs in alkynes. In oxidative cleavage both the sigma and pi bonds of the alkyne is broken. In case of terminal alkynes, carboxylic acid and carbon dioxide is formed while in case of internal alkynes, only carboxylic acids are formed.

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Chapter 12 Solutions

Organic Chemistry

Ch. 12 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Problem 12.18 Draw the products formed when both...Ch. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - Prob. 12.22PCh. 12 - Prob. 12.23PCh. 12 - Problem 12.24 Draw the organic products in each of...Ch. 12 - Prob. 12.25PCh. 12 - Prob. 12.26PCh. 12 - Problem 12.27 Draw the products of each Sharpless...Ch. 12 - Prob. 12.28PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 12.30PCh. 12 - 12.31 Devise a synthesis of the following compound...Ch. 12 - Label each reaction as oxidation, reduction, or...Ch. 12 - Prob. 12.33PCh. 12 - Prob. 12.34PCh. 12 - Prob. 12.35PCh. 12 - Prob. 12.36PCh. 12 - 12.37 Stearidonic acid (C18H28O2) is an...Ch. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Prob. 12.39PCh. 12 - Draw the organic products formed when allylic...Ch. 12 - Draw the organic products formed in each reaction...Ch. 12 - Draw the organic products formed in each reaction....Ch. 12 - Prob. 12.43PCh. 12 - Prob. 12.44PCh. 12 - Prob. 12.45PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - Prob. 12.47PCh. 12 - Draw the products formed after Steps 1 and 2 in...Ch. 12 - Prob. 12.49PCh. 12 - Prob. 12.50PCh. 12 - Prob. 12.51PCh. 12 - What alkyne gives each set of products after...Ch. 12 - Prob. 12.53PCh. 12 - Prob. 12.54PCh. 12 - Prob. 12.55PCh. 12 - 12.54 An unknown compound A of molecular formula ...Ch. 12 - 12.55 DHA is a fatty acid derived from fish oil...Ch. 12 - Prob. 12.58PCh. 12 - Prob. 12.59PCh. 12 - 12.58 Epoxidation of the following allylic alcohol...Ch. 12 - What allylic alcohol and DET isomer are needed to...Ch. 12 - Devise a synthesis of each hydrocarbon from...Ch. 12 - Prob. 12.63PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - Prob. 12.65PCh. 12 - Prob. 12.66PCh. 12 - Prob. 12.67PCh. 12 - Prob. 12.68PCh. 12 - Devise a synthesis of each compound from the...Ch. 12 - Devise a synthesis of each compound from acetylene...Ch. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Prob. 12.74PCh. 12 - Prob. 12.75PCh. 12 - Prob. 12.76PCh. 12 - 12.72 Draw a stepwise mechanism for the following...Ch. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - Prob. 12.80PCh. 12 - 12.75 Sharpless epoxidation of allylic alcohol X...
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