(a) Interpretation: The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic. Concept Introduction: Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles. The following table should be used while determining the shapes: Number of groups Number of atoms Number of lone pairs Shape Bond angle 2 2 0 Linear 180 ° 3 3 0 Trigonal planar 120 ° 4 4 0 Tetrahedral 109.5 ° 4 3 1 Trigonal pyramidal 109.5 ° 4 2 2 Bent 109.5 °

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Answer 1

Question

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

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Answer 2

Question

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

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Answer 3

Question

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

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Answer 4

Question

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Expert Solution & Answer

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Answer 5

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 6

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 7

Chapter 11.3, Problem 11.4P

Interpretation Introduction

(a)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Halothane' a general anesthetic.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 8

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 9

Interpretation Introduction

(b)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Propene' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 10

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 11

Interpretation Introduction

(c)

Interpretation:

The labelled bond angles needs to be determined in the given compound 'Phenol' a petroleum product.

Concept Introduction:

Bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts. Valence shell electron pair repulsion theory or VSEPR theory used in chemistry as a model for the prediction of shape of various molecules by knowing the electron pairs on the central atom. There will be repulsion between the electron pairs present on central atom, so to minimize the repulsion they adopt an arrangement with minimum repulsion, thus determining molecule's shape. And by knowing the shape we can easily determine the bond angles.

The following table should be used while determining the shapes:

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear 180°
3 3 0 Trigonal planar 120°
4 4 0 Tetrahedral 109.5°
4 3 1 Trigonal pyramidal 109.5°
4 2 2 Bent 109.5°

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11.1 - Prob. 11.1P Ch. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.3P Ch. 11.3 - Prob. 11.4P Ch. 11.3 - Prob. 11.5P Ch. 11.3 - Prob. 11.6P Ch. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...

Solution Summary: The author explains that bond angles can be determined by VSEPR theory based on hybridization but not accurately for certain oxides, metallic compounds and gaseous salts.

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Chapter 11 Solutions

Number of groups	Number of atoms	Number of lone pairs	Shape	Bond angle
2	2	0	Linear	180°
3	3	0	Trigonal planar	120°
4	4	0	Tetrahedral	109.5°
4	3	1	Trigonal pyramidal	109.5°
4	2	2	Bent	109.5°