General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 11.2, Problem 11.1PP
Fill in all H's and lone pairs in each compound.
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Match each of the general molecular formulas below with its correct molecular geometry.
Note: The sorting box Tri. Bipyramidal stands for trigonal bipyramidal.
Items (6 items) (Drag and drop into the appropriate area below)
AB5 with no lone
pairs on A
AB4 with one
lone pair on A
AB4 with two
lone pairs on A
AB2 with one
lone pair on A
AB2 with two
AB2 with no lone
lone pairs on A
pairs on A
Categories
Bent 120° bond
Bent 109.5° bond
Tri. bipyramidal
Square planar
Seesaw
1. For each of the following compounds and ions, draw the complete Lewis structure. All formal charges should
be on the atoms that possess that formal charge.
CH4 H3CBr CH3CH₂OH H₂S H₂SO4 (sulfuric acid) H³0+ CH3*
2. Convert the following condensed formulas into bond-line structures, making sure to draw in zig-zag
formation.
CH3CH₂CH₂CH₂CH₂CH₂CH₂CH3
FCH₂CH₂I
H₂C=CHCH₂OH
(CH3)2CHCOOH
Draw VSEPR sketches for each compound below. Then, indicate whether the each of the following compounds is polar or nonpolar by drawing molecular dipole moments when appropriate.
CHCl3
CH2Cl2
CCl4
H2O
CH3CH2CH2CH2CH3
Chapter 11 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 11.1 - Prob. 11.1PCh. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.2PPCh. 11.3 - Prob. 11.2PCh. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.3PPCh. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...
Ch. 11.4 - Prob. 11.5PCh. 11.4 - How many H’s are bonded to each indicated carbon...Ch. 11.4 - Using the skeletal structure, determine the...Ch. 11.5 - Prob. 11.7PCh. 11.5 - Prob. 11.8PCh. 11.5 - For each compound. [1] Identify the functional...Ch. 11.5 - How do a carboxylic acid and an alcohol differ?...Ch. 11.5 - Label each of the following condensed structures...Ch. 11.5 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Identify all of the functional groups in atenolol,...Ch. 11.5 - Prob. 11.13PCh. 11.5 - Prob. 11.10PPCh. 11.5 - Prob. 11.14PCh. 11.6 - Indicate the polar bonds in each compound. Label...Ch. 11.6 - Prob. 11.11PPCh. 11.6 - Prob. 11.16PCh. 11.6 - Predict the water solubility of each compound.Ch. 11.6 - Prob. 11.17PCh. 11.7 - Prob. 11.18PCh. 11.7 - Prob. 11.19PCh. 11.7 - Prob. 11.20PCh. 11 - Prob. 21PCh. 11 - Prob. 22PCh. 11 - Complete each structure by filling in all H’s and...Ch. 11 - Complete the structure of mepivacaine by filling...Ch. 11 - Prob. 25PCh. 11 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - “Ecstasy” is a widely used illegal stimulant....Ch. 11 - Prob. 30PCh. 11 - Explain why each C—C—C bond angle in benzene...Ch. 11 - Prob. 32PCh. 11 - Convert each compound to a condensed structure.Ch. 11 - Convert each compound to a condensed structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each skeletal structure to a complete...Ch. 11 - Convert each skeletal structure to a complete...Ch. 11 - A and B are ball-and-stick models of two compounds...Ch. 11 - Prob. 42PCh. 11 - What is wrong in each of the following shorthand...Ch. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Albuterol (trade names Proventil and Ventolin) is...Ch. 11 - Prob. 47PCh. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - (a) Identify the functional groups in donepezil,...Ch. 11 - Prob. 51PCh. 11 - GHB is an addictive, illegal recreational drug...Ch. 11 - Prob. 53PCh. 11 - Prob. 54PCh. 11 - Prob. 55PCh. 11 - Prob. 56PCh. 11 - Prob. 57PCh. 11 - (a) Identify the functional groups in venlafaxine,...Ch. 11 - You are given two unlabeled bottles of solids, one...Ch. 11 - State how potassium iodide (KI) and pentane...Ch. 11 - The given beaker contains 100 mL of the organic...Ch. 11 - Prob. 62PCh. 11 - Why do we need to know the shape of a molecule...Ch. 11 - 1,1-Dichloroethylene (CH2=CCl2) is a starting...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Classify each molecule as polar or nonpolar.Ch. 11 - Classify each molecule as polar or nonpolar. a....Ch. 11 - Which molecule is more water soluble? Explain.Ch. 11 - Explain why pantothenic acid, vitamin B5, is water...Ch. 11 - Prob. 71PCh. 11 - Prob. 72PCh. 11 - Explain why regularly taking a large excess of a...Ch. 11 - You can obtain the minimum daily requirement of...Ch. 11 - Prob. 75PCh. 11 - Vitamin B6 is obtained by eating a diet that...Ch. 11 - Prob. 77PCh. 11 - Can an oxygen-containing organic compound, have...Ch. 11 - Prob. 79PCh. 11 - Prob. 80PCh. 11 - Benzocaine is the active ingredient in topical...Ch. 11 - Methyl salicylate is responsible for the...Ch. 11 - Answer the following questions about aldosterone,...Ch. 11 - Answer the following questions about...Ch. 11 - Prob. 85PCh. 11 - Skin moisturizers come in two types, (a) One type...Ch. 11 - THC is the active component in marijuana (Section...Ch. 11 - Cocaine is a widely abused, addicting drug....
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- Predict the indicated bond angles in each compound drawn as a Lewis structure with no implied geometry. CH₂-CEC CI: b. CH₂ C CI: c. CH3 CI: Harrow_forward1) Draw the best Lewis structures for the molecules below in bond line notation with the correct bond geometry. Make sure to include formal charges if needed. If you can draw more than one resonance structure of the compound provide the best structure. a. CH3CH2CCCOOH b. CH3CH2C(NH)CH(CH3)2 c. CH2CHCH2NCO Geometry at terminal Carbon highlighted in bold Bond angle of indicated Carbon Geometry at Carbon highlighted in bold attached to N Bond angle of indicated Geometry at terminal Carbon highlighted in bold Bond angle at Carrow_forward2. To the right of each compound, redraw each of the line drawings, explicitly showing all of the atoms and lone pairs * OHarrow_forward
- D a Given that the spatial requirement of a lone pair is greater than that of a bond pair, explain why XeF2 has a linear molecular structure and not a bent one. The four lone pairs of XeF2 occupy the equatorial positions. The angles between lone pairs are 60°, so there is less lone pair/lone pair repulsion with this arrangement. O The two lone pairs of XeF2 occupy the equatorial positions. The angle between lone pairs is 180°, so there is less lone pair/lone pair repulsion with this arrangement. O The two lone pairs of XeF2 occupy the equatorial positions. The angle between lone pairs is 60°, so there is less lone pair/lone pair repulsion with this arrangement. O The three lone pairs of XeF2 occupy the equatorial positions. The angles between lone pairs are 120°, so there is less lone pair/lone pair repulsion with this arrangement. Submitarrow_forwardDraw the curved arrows and the resulting resonance structure for the following structure. Include lone pairs and charges in your structure. Also, at one end of the the bond line structure is H3C and the other end is CH3arrow_forwardDraw a resonance structure that shifts a lone pair from the oxygen to form a new pi bond. Include all hydrogen atoms and lone pairs in your structure.arrow_forward
- Provide all reasonable resonance structures for each molecular structure below. Use curved arrows to show how electrons are moved and dont forget lone pairs. E 1. CH3 CNO E2. CHỌN -1 NCO E3. CHOCN E +1 4. O C S E5. N = N = O E1. CH CNO E2. CH3NCO E3. CH₂OCN E4. O-C-S E5. N-1=N+1=0 E6. CH H₂Oarrow_forwardPredict all bond angles about each highlighted carbon atom. b Blue atom bond angles = Red atom bond angles = H3C -CH₂OH H3C Blue atom bond angles ⒸH₂CC=CC=CH₂ Blue atom bond angles = Red atom bond angles = dH3C. CH3 CH3 Blue atom bond angles =arrow_forwardWhich drawing best represents the resonance hybrid for the given molecule? S* Ď 8*arrow_forward
- Draw a skeletal structure for the molecules in parts (a) and (b), and a condensed structure for the molecules in parts (c) and (d).arrow_forwardChoose the condensed structure for the following line structure. CH3C(CH3)2CH₂O(CH2)4CH3 CH3CH₂C(CH3)2CHO(CH₂)4CH3 CH3CH₂C(CH3)2CH₂O(CH₂)4CH3 CH,CH CH(CH,)CH,O(CH,),CH; CH3CH₂C(CH3)2CH₂OCH(CH2)3CH3arrow_forwardDescribe the orbitals used by each carbon atom in bonding and indicate the approximate bond angles. Drag the appropriate items to their respective bins.arrow_forward
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