![General, Organic, and Biological Chemistry - 4th edition](https://www.bartleby.com/isbn_cover_images/9781259883989/9781259883989_largeCoverImage.gif)
Concept explainers
(a)
Interpretation:
The indicated bond angle in the following compound should be predicted:
Concept Introduction:
The following table should be used while determining the bond around an atom.
Number of groups | Number of atoms | Number of lone pairs | Shape | Bond angle |
2 | 2 | 0 | Linear |
|
3 | 3 | 0 | Trigonal planar |
|
4 | 4 | 0 | Tetrahedral |
|
4 | 3 | 1 | Trigonal pyramidal |
|
4 | 2 | 2 | Bent |
|
![Check Mark](/static/check-mark.png)
Answer to Problem 27P
Angle (1) and angle (2) both measures
Explanation of Solution
The given structure is as follows:
In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is
(b)
Interpretation:
The indicated bond angle in the following compound should be predicted:
Concept Introduction:
The following table should be used while determining the bond angle around an atom.
Number of groups | Number of atoms | Number of lone pairs | Shape | Bond angle |
2 | 2 | 0 | Linear |
|
3 | 3 | 0 | Trigonal planar |
|
4 | 4 | 0 | Tetrahedral |
|
4 | 3 | 1 | Trigonal pyramidal |
|
4 | 2 | 2 | Bent |
|
![Check Mark](/static/check-mark.png)
Answer to Problem 27P
Angle (1) and (2) both measures
Explanation of Solution
The compound is as follows:
In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be
(c)
Interpretation:
The indicated bond angle in the following compound should be predicted:
Concept Introduction:
The following table should be used while determining the bond angle around an atom.
Number of groups | Number of atoms | Number of lone pairs | Shape | Bond angle |
2 | 2 | 0 | Linear |
|
3 | 3 | 0 | Trigonal planar |
|
4 | 4 | 0 | Tetrahedral |
|
4 | 3 | 1 | Trigonal pyramidal |
|
4 | 2 | 2 | Bent |
|
![Check Mark](/static/check-mark.png)
Answer to Problem 27P
Angle (1) and angle (2) both measures
Explanation of Solution
Given compound is as follows:
The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is
Want to see more full solutions like this?
Chapter 11 Solutions
General, Organic, and Biological Chemistry - 4th edition
- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305580350/9781305580350_smallCoverImage.gif)