
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 1.11, Problem 1.16P
Interpretation Introduction
Interpretation:
Which particle is produced by decay of
determined.
Concept introduction:
Balancing
The key to balancing nuclear equations is to make sure that the number of nucleons is the
same on both sides of the equation and that the number of nuclear charges plus electron or positron charges is the same.
Alpha radiation be made up of helium nuclei, small particles containing two protons and two neutrons
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 1 Solutions
General Chemistry: Atoms First
Ch. 1.1 - Look at the alphabetical list of elements inside...Ch. 1.1 - Prob. 1.2PCh. 1.3 - Identify the following elements as metals,...Ch. 1.3 - Prob. 1.4CPCh. 1.5 - Compounds A and B are colorless gases obtained by...Ch. 1.7 - The gold foil Rutherford used in his scattering...Ch. 1.7 - A small speck of carbon the size of a pinhead...Ch. 1.8 - The isotope S3475e is used medically for the...Ch. 1.8 - Chlorine, one of the elements in common table salt...Ch. 1.8 - An atom of element X contains 47 protons and 62...
Ch. 1.9 - Copper metal has two naturally occurring isotopes:...Ch. 1.9 - Based on your answer to Problem 1.11, how many...Ch. 1.9 - What is the mass in grams of each of the following...Ch. 1.9 - How many moles are in each of the following...Ch. 1.11 - Prob. 1.15PCh. 1.11 - Prob. 1.16PCh. 1.11 - Prob. 1.17CPCh. 1.11 - Prob. 1.18PCh. 1.11 - Prob. 1.19PCh. 1 - Prob. 1.20CPCh. 1 - Where on the following outline of a periodic table...Ch. 1 - Prob. 1.22CPCh. 1 - Prob. 1.23CPCh. 1 - If yellow spheres represent sulfur atoms and red...Ch. 1 - Prob. 1.25CPCh. 1 - Prob. 1.26CPCh. 1 - Prob. 1.27CPCh. 1 - In the following drawings, red spheres represent...Ch. 1 - Isotope A decays to isotope E through the...Ch. 1 - Prob. 1.30SPCh. 1 - Prob. 1.31SPCh. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Prob. 1.34SPCh. 1 - Prob. 1.35SPCh. 1 - Prob. 1.36SPCh. 1 - Prob. 1.37SPCh. 1 - Prob. 1.38SPCh. 1 - Prob. 1.39SPCh. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - Prob. 1.45SPCh. 1 - Prob. 1.46SPCh. 1 - Prob. 1.47SPCh. 1 - Prob. 1.48SPCh. 1 - Prob. 1.49SPCh. 1 - Prob. 1.50SPCh. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - Prob. 1.53SPCh. 1 - Prob. 1.54SPCh. 1 - Prob. 1.55SPCh. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Prob. 1.58SPCh. 1 - Prob. 1.59SPCh. 1 - Prob. 1.60SPCh. 1 - If 6.02 1023 atoms of element Y have a mass of...Ch. 1 - Prob. 1.62SPCh. 1 - Prob. 1.63SPCh. 1 - Prob. 1.64SPCh. 1 - Prob. 1.65SPCh. 1 - Prob. 1.66SPCh. 1 - Prob. 1.67SPCh. 1 - Prob. 1.68SPCh. 1 - Prob. 1.69SPCh. 1 - Prob. 1.70SPCh. 1 - Prob. 1.71SPCh. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - Prob. 1.74SPCh. 1 - Prob. 1.75SPCh. 1 - Prob. 1.76SPCh. 1 - Prob. 1.77SPCh. 1 - Prob. 1.78SPCh. 1 - Prob. 1.79SPCh. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Which of the following isotope symbols cant be...Ch. 1 - Prob. 1.84SPCh. 1 - Naturally occurring silver consists of two...Ch. 1 - Magnesium has three naturally occurring isotopes:...Ch. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - Prob. 1.89SPCh. 1 - Prob. 1.90SPCh. 1 - Prob. 1.91SPCh. 1 - Prob. 1.92SPCh. 1 - Prob. 1.93SPCh. 1 - Prob. 1.94SPCh. 1 - Prob. 1.95SPCh. 1 - Prob. 1.96SPCh. 1 - Prob. 1.97SPCh. 1 - Prob. 1.98SPCh. 1 - Prob. 1.99SPCh. 1 - Prob. 1.100SPCh. 1 - Prob. 1.101SPCh. 1 - Prob. 1.102CHPCh. 1 - Prob. 1.103CHPCh. 1 - Prob. 1.104CHPCh. 1 - Prob. 1.105CHPCh. 1 - Prob. 1.106CHPCh. 1 - Prob. 1.107CHPCh. 1 - Prob. 1.108CHPCh. 1 - Prob. 1.109CHPCh. 1 - Prob. 1.110CHPCh. 1 - The mass percent of an element in a compound is...Ch. 1 - Prob. 1.112CHPCh. 1 - Prob. 1.113CHPCh. 1 - In an alternate universe, the smallest negatively...
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