General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 1, Problem 1.61SP
If 6.02 × 1023 atoms of element Y have a mass of 83.80 g, what is the identity of Y?
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Question 5: Name the following compound in two ways
using side chain and using prefix amine (Common name
and IUPAC name both)
CH3NH2
CH3CH2NHCH3
CH₂CH₂N(CH3)2
Draw the structure of diethyl methyl amine
Question 6. Write the balanced combustion reaction
for:
a. Hexane
b. Propyne
c. 2-pentene
Question 7: Write the following electrophilic
substitution reactions of benzene:
Hint: Use notes if you get confused
a. Halogenation reaction:
b. Nitration reaction :
c. Sulphonation reaction:
d. Alkylation reaction:
e. Aceylation reaction:
Question 4. Name the following structures
○
CH3-C-N-H
H
CH3CH2-C-N-H
H
CH3CH2-C-N-CH3
H
A. Add Water to below compound which 2-methyl 2-butene (addition Reaction)
H₂C
CH₂
CH,
+ H₂O-> ?
Major product?
Minor product?
B. Add Bromine to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ Br₂→ ?
Major product and Minor product both are same in this?
C. Add Hydrogen Bromide to the compound which 2-methyl 2-butene (addition
Reaction)
H,C
CH₂
CH₂
+ HBr
Major product?
Minor product?
D. Add Hydrogen to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ H₂
Major product and Minor product both are same in this?
Chapter 1 Solutions
General Chemistry: Atoms First
Ch. 1.1 - Look at the alphabetical list of elements inside...Ch. 1.1 - Prob. 1.2PCh. 1.3 - Identify the following elements as metals,...Ch. 1.3 - Prob. 1.4CPCh. 1.5 - Compounds A and B are colorless gases obtained by...Ch. 1.7 - The gold foil Rutherford used in his scattering...Ch. 1.7 - A small speck of carbon the size of a pinhead...Ch. 1.8 - The isotope S3475e is used medically for the...Ch. 1.8 - Chlorine, one of the elements in common table salt...Ch. 1.8 - An atom of element X contains 47 protons and 62...
Ch. 1.9 - Copper metal has two naturally occurring isotopes:...Ch. 1.9 - Based on your answer to Problem 1.11, how many...Ch. 1.9 - What is the mass in grams of each of the following...Ch. 1.9 - How many moles are in each of the following...Ch. 1.11 - Prob. 1.15PCh. 1.11 - Prob. 1.16PCh. 1.11 - Prob. 1.17CPCh. 1.11 - Prob. 1.18PCh. 1.11 - Prob. 1.19PCh. 1 - Prob. 1.20CPCh. 1 - Where on the following outline of a periodic table...Ch. 1 - Prob. 1.22CPCh. 1 - Prob. 1.23CPCh. 1 - If yellow spheres represent sulfur atoms and red...Ch. 1 - Prob. 1.25CPCh. 1 - Prob. 1.26CPCh. 1 - Prob. 1.27CPCh. 1 - In the following drawings, red spheres represent...Ch. 1 - Isotope A decays to isotope E through the...Ch. 1 - Prob. 1.30SPCh. 1 - Prob. 1.31SPCh. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Prob. 1.34SPCh. 1 - Prob. 1.35SPCh. 1 - Prob. 1.36SPCh. 1 - Prob. 1.37SPCh. 1 - Prob. 1.38SPCh. 1 - Prob. 1.39SPCh. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - Prob. 1.45SPCh. 1 - Prob. 1.46SPCh. 1 - Prob. 1.47SPCh. 1 - Prob. 1.48SPCh. 1 - Prob. 1.49SPCh. 1 - Prob. 1.50SPCh. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - Prob. 1.53SPCh. 1 - Prob. 1.54SPCh. 1 - Prob. 1.55SPCh. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Prob. 1.58SPCh. 1 - Prob. 1.59SPCh. 1 - Prob. 1.60SPCh. 1 - If 6.02 1023 atoms of element Y have a mass of...Ch. 1 - Prob. 1.62SPCh. 1 - Prob. 1.63SPCh. 1 - Prob. 1.64SPCh. 1 - Prob. 1.65SPCh. 1 - Prob. 1.66SPCh. 1 - Prob. 1.67SPCh. 1 - Prob. 1.68SPCh. 1 - Prob. 1.69SPCh. 1 - Prob. 1.70SPCh. 1 - Prob. 1.71SPCh. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - Prob. 1.74SPCh. 1 - Prob. 1.75SPCh. 1 - Prob. 1.76SPCh. 1 - Prob. 1.77SPCh. 1 - Prob. 1.78SPCh. 1 - Prob. 1.79SPCh. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Which of the following isotope symbols cant be...Ch. 1 - Prob. 1.84SPCh. 1 - Naturally occurring silver consists of two...Ch. 1 - Magnesium has three naturally occurring isotopes:...Ch. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - Prob. 1.89SPCh. 1 - Prob. 1.90SPCh. 1 - Prob. 1.91SPCh. 1 - Prob. 1.92SPCh. 1 - Prob. 1.93SPCh. 1 - Prob. 1.94SPCh. 1 - Prob. 1.95SPCh. 1 - Prob. 1.96SPCh. 1 - Prob. 1.97SPCh. 1 - Prob. 1.98SPCh. 1 - Prob. 1.99SPCh. 1 - Prob. 1.100SPCh. 1 - Prob. 1.101SPCh. 1 - Prob. 1.102CHPCh. 1 - Prob. 1.103CHPCh. 1 - Prob. 1.104CHPCh. 1 - Prob. 1.105CHPCh. 1 - Prob. 1.106CHPCh. 1 - Prob. 1.107CHPCh. 1 - Prob. 1.108CHPCh. 1 - Prob. 1.109CHPCh. 1 - Prob. 1.110CHPCh. 1 - The mass percent of an element in a compound is...Ch. 1 - Prob. 1.112CHPCh. 1 - Prob. 1.113CHPCh. 1 - In an alternate universe, the smallest negatively...
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- 36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones, esters, malonic ester, and keto ester, etc. (30 pts) (1) A NaOH, H₂O+ heat A NaOEt EtO OEt (11) EOH, H+ H. B LDA, H₂O+ -78°C B (i) NaOMe, Et-Br (ii) H₂O+, heat EtOOC (III) COOEt B A (i) NaOEt LiAlH 4-bromo-2-butene H₂O+ (ii) H3O+, heat Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).arrow_forward31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D. (25 pts) O OH 0 K2Cr2O7 Ph-CH2-Br, Mg, H2SO4 THF, H3O* (A) (D) Racemic mixture TsCl, Py (B) KCN, DMSO Ph-CH2-Br, Mg, THF, H3O+ (C) Mechanism for reactions B and C:arrow_forwardManoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL 33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from benzene. Illustrate the mechanism for reaction A. 1) NU (25 pts) A FeCl B (i) HNO3, H2SO4 (II) Sn, HCl(aq) NH₂ NO₂-D NH₂ (i) MeCO2Me, heat C (ii) K2Cr2O7/H2SO4 D (ii) SOCl2 (iii) 2 Et-NH2 Mechanism for reaction for the nitration of alkyl benzene (B-i): Characterize the product compound arising from the reaction D by IR and IH NMR spectral data: IR data (cm): 'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.arrow_forward
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