General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 1, Problem 1.107CHP
Interpretation Introduction
Interpretation:
The isotopic kinds of
Concept introduction:
Isotope:
The same element that have equal number of protons but different numbers of neutrons in their nucleus.
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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 1 Solutions
General Chemistry: Atoms First
Ch. 1.1 - Look at the alphabetical list of elements inside...Ch. 1.1 - Prob. 1.2PCh. 1.3 - Identify the following elements as metals,...Ch. 1.3 - Prob. 1.4CPCh. 1.5 - Compounds A and B are colorless gases obtained by...Ch. 1.7 - The gold foil Rutherford used in his scattering...Ch. 1.7 - A small speck of carbon the size of a pinhead...Ch. 1.8 - The isotope S3475e is used medically for the...Ch. 1.8 - Chlorine, one of the elements in common table salt...Ch. 1.8 - An atom of element X contains 47 protons and 62...
Ch. 1.9 - Copper metal has two naturally occurring isotopes:...Ch. 1.9 - Based on your answer to Problem 1.11, how many...Ch. 1.9 - What is the mass in grams of each of the following...Ch. 1.9 - How many moles are in each of the following...Ch. 1.11 - Prob. 1.15PCh. 1.11 - Prob. 1.16PCh. 1.11 - Prob. 1.17CPCh. 1.11 - Prob. 1.18PCh. 1.11 - Prob. 1.19PCh. 1 - Prob. 1.20CPCh. 1 - Where on the following outline of a periodic table...Ch. 1 - Prob. 1.22CPCh. 1 - Prob. 1.23CPCh. 1 - If yellow spheres represent sulfur atoms and red...Ch. 1 - Prob. 1.25CPCh. 1 - Prob. 1.26CPCh. 1 - Prob. 1.27CPCh. 1 - In the following drawings, red spheres represent...Ch. 1 - Isotope A decays to isotope E through the...Ch. 1 - Prob. 1.30SPCh. 1 - Prob. 1.31SPCh. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Prob. 1.34SPCh. 1 - Prob. 1.35SPCh. 1 - Prob. 1.36SPCh. 1 - Prob. 1.37SPCh. 1 - Prob. 1.38SPCh. 1 - Prob. 1.39SPCh. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - Prob. 1.45SPCh. 1 - Prob. 1.46SPCh. 1 - Prob. 1.47SPCh. 1 - Prob. 1.48SPCh. 1 - Prob. 1.49SPCh. 1 - Prob. 1.50SPCh. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - Prob. 1.53SPCh. 1 - Prob. 1.54SPCh. 1 - Prob. 1.55SPCh. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Prob. 1.58SPCh. 1 - Prob. 1.59SPCh. 1 - Prob. 1.60SPCh. 1 - If 6.02 1023 atoms of element Y have a mass of...Ch. 1 - Prob. 1.62SPCh. 1 - Prob. 1.63SPCh. 1 - Prob. 1.64SPCh. 1 - Prob. 1.65SPCh. 1 - Prob. 1.66SPCh. 1 - Prob. 1.67SPCh. 1 - Prob. 1.68SPCh. 1 - Prob. 1.69SPCh. 1 - Prob. 1.70SPCh. 1 - Prob. 1.71SPCh. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - Prob. 1.74SPCh. 1 - Prob. 1.75SPCh. 1 - Prob. 1.76SPCh. 1 - Prob. 1.77SPCh. 1 - Prob. 1.78SPCh. 1 - Prob. 1.79SPCh. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Which of the following isotope symbols cant be...Ch. 1 - Prob. 1.84SPCh. 1 - Naturally occurring silver consists of two...Ch. 1 - Magnesium has three naturally occurring isotopes:...Ch. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - Prob. 1.89SPCh. 1 - Prob. 1.90SPCh. 1 - Prob. 1.91SPCh. 1 - Prob. 1.92SPCh. 1 - Prob. 1.93SPCh. 1 - Prob. 1.94SPCh. 1 - Prob. 1.95SPCh. 1 - Prob. 1.96SPCh. 1 - Prob. 1.97SPCh. 1 - Prob. 1.98SPCh. 1 - Prob. 1.99SPCh. 1 - Prob. 1.100SPCh. 1 - Prob. 1.101SPCh. 1 - Prob. 1.102CHPCh. 1 - Prob. 1.103CHPCh. 1 - Prob. 1.104CHPCh. 1 - Prob. 1.105CHPCh. 1 - Prob. 1.106CHPCh. 1 - Prob. 1.107CHPCh. 1 - Prob. 1.108CHPCh. 1 - Prob. 1.109CHPCh. 1 - Prob. 1.110CHPCh. 1 - The mass percent of an element in a compound is...Ch. 1 - Prob. 1.112CHPCh. 1 - Prob. 1.113CHPCh. 1 - In an alternate universe, the smallest negatively...
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