Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 71QAP
For a certain reaction, Ea is 135 kJ and
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Part 3: AHm,system
Mass of 1.00 M HCI
Vol. of 1.00 M HCI
Mass of NaOH(s)
Total Mass in Calorimeter
Mole product if
HCI limiting reactant
Trial 1
62.4009
1.511g
Mole product if
NaOH limiting reactant
Limiting reactant
Initial Temperature
Final Temperature
23.8°C
37.6°C
Change in Temperature
AHm,system (calculated)
Average AHm,system
(calculated)
(calculated)
(calculated)
Trial 2
64.006g
1.9599
(calculated)
(calculated)
(calculated)
(calculated)
(calculated)
(calculated)
24.7°C
41.9°C
(calculated)
(calculated)
(2 pts. each)
Don't used Ai solution
What is the numerical value of the slope
using the equation y=-1.823x -0.0162
please show calculations
Chapter 11 Solutions
Chemistry: Principles and Reactions
Ch. 11 - Express the rate of the reaction...Ch. 11 - Express the rate of the reaction...Ch. 11 - Consider the following hypothetical reaction: X( g...Ch. 11 - Consider the following hypothetical reaction:...Ch. 11 - Consider the combustion of ethane:...Ch. 11 - For the reaction 5Br(aq)+BrO3(aq)+6...Ch. 11 - Nitrosyl chloride (NOCI) decomposes to nitrogen...Ch. 11 - Ammonia is produced by the reaction between...Ch. 11 - Experimental data are listed for the following...Ch. 11 - Experimental data are listed for the hypothetical...
Ch. 11 - A reaction has two reactants X and Y. What is the...Ch. 11 - A reaction has two reactants Q and P. What is the...Ch. 11 - What will the units of the rate constants in...Ch. 11 - What will the units of the rate constants in...Ch. 11 - Consider the reaction ZproductsThe data below give...Ch. 11 - Consider the reaction YproductsThe graph below...Ch. 11 - Complete the following table for the reaction...Ch. 11 - Complete the following table for the reaction...Ch. 11 - The decomposition of nitrogen dioxide is a...Ch. 11 - The decomposition of ammonia on tungsten at 1100C...Ch. 11 - The reaction ICl(g)+12 H2(g)12 I2(g)+HCl(g)is...Ch. 11 - The hypothetical reaction X(g)+12Y(g)productsis...Ch. 11 - For a reaction involving the decomposition of Z at...Ch. 11 - For a reaction involving the decomposition of Y,...Ch. 11 - When boron trifluoride reacts with ammonia, the...Ch. 11 - When nitrogen dioxide reacts with carbon monoxide,...Ch. 11 - Hydrogen bromide is a highly reactive and...Ch. 11 - Diethylhydrazine reacts with iodine according to...Ch. 11 - The equation for the reaction between iodide and...Ch. 11 - Prob. 30QAPCh. 11 - In a solution at a constant H+ concentration,...Ch. 11 - Consider the reaction Â...Ch. 11 - Nitrosyl bromide decomposes to nitrogen oxide and...Ch. 11 - Prob. 34QAPCh. 11 - Azomethane decomposes into nitrogen and ethane at...Ch. 11 - The decomposition of sulfuryl chloride, SO2Cl2, to...Ch. 11 - The first-order rate constant for the...Ch. 11 - Consider the first-order decomposition of phosgene...Ch. 11 - The decomposition of azomethane, (CH3)2N2, to...Ch. 11 - The first-order rate constant for the...Ch. 11 - In the first-order decomposition of acetone at...Ch. 11 - The decomposition of sulfuryl chlorideSO2Cl2fur...Ch. 11 - Dinitrogen pentoxide gas decomposes to form...Ch. 11 - Sucrose (C12H22O11) hydrolyzes into glucose and...Ch. 11 - Iodine-131 is used to treat tumors in the thyroid....Ch. 11 - Cesium-131 is the latest tool of nuclear medicine....Ch. 11 - Prob. 47QAPCh. 11 - A sample of sodium-24 chloride contains 0.050 mg...Ch. 11 - The decomposition of A at 850C is a zero-order...Ch. 11 - The decomposition of R at 33C is a zero-order...Ch. 11 - For the zero-order decomposition of HI on a gold...Ch. 11 - For the zero-order decomposition of ammonia on...Ch. 11 - Ammonium cyanate, NH4NCO, in water rearranges to...Ch. 11 - Butadiene, C4H6, dimerizes according to the...Ch. 11 - The rate constant for the second-order reaction...Ch. 11 - The decomposition of nitrosyl chloride...Ch. 11 - An increase in temperature from 23C to 36C...Ch. 11 - If the activation energy of a reaction is 9.13 kJ,...Ch. 11 - The following data are obtained for the gas-phase...Ch. 11 - The following data are obtained for the...Ch. 11 - Consider the following hypothetical reaction:...Ch. 11 - For the reaction: Q+RY+ZH=128kJ Draw a...Ch. 11 - The uncoiling of deoxyribonucleic acid (DNA) is a...Ch. 11 - The precipitation of egg albumin in water at 100C...Ch. 11 - Prob. 65QAPCh. 11 - Prob. 66QAPCh. 11 - For the reaction 2N2O(g)2N2(g)+O2(g) the rate...Ch. 11 - For the decomposition of a peroxide, the...Ch. 11 - Consider a 5.000 M solution of the hypothetical...Ch. 11 - The decomposition of N2O5 to NO2 and NO3 is a...Ch. 11 - For a certain reaction, Ea is 135 kJ and H=45 kJ....Ch. 11 - Consider a reaction in which E a=129 kJ and H=29...Ch. 11 - A catalyst lowers the activation energy of a...Ch. 11 - A reaction has an activation energy of 363 kJ at...Ch. 11 - Write the rate expression for each of the...Ch. 11 - Write the rate expression for each of the...Ch. 11 - For the reaction between hydrogen and iodine,...Ch. 11 - For the reaction 2H2(g)+2NO(g)N2(g)+2H2O(g) the...Ch. 11 - At low temperatures, the rate law for the reaction...Ch. 11 - Two mechanisms are proposed for the reaction...Ch. 11 - The hypothetical reaction QR+Xproductswas...Ch. 11 - When a base is added to an aqueous solution of...Ch. 11 - The decomposition of sulfuryl chloride, SO2Cl2, to...Ch. 11 - How much faster would a reaction proceed at 46C...Ch. 11 - Prob. 85QAPCh. 11 - Prob. 86QAPCh. 11 - A drug decomposes in the blood by a first-order...Ch. 11 - Prob. 88QAPCh. 11 - Prob. 89QAPCh. 11 - Prob. 90QAPCh. 11 - Consider the decomposition of A represented by...Ch. 11 - Consider the decomposition reaction 2X2Y+ZThe...Ch. 11 - Consider the following activation energy diagram....Ch. 11 - Three first-order reactions have the following...Ch. 11 - Consider the first-order decomposition reaction...Ch. 11 - Consider the following energy diagram (not to...Ch. 11 - Prob. 97QAPCh. 11 - Prob. 98QAPCh. 11 - The gas-phase reaction between hydrogen and iodine...Ch. 11 - Consider the coagulation of a protein at 100C. The...Ch. 11 - Prob. 101QAPCh. 11 - Prob. 102QAPCh. 11 - Prob. 103QAPCh. 11 - In a first-order reaction, suppose that a quantity...Ch. 11 - Consider the hypothetical first-order reaction...
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- Don't used hand raitingarrow_forward1.) Using the graph below (including the line equation of y = -1.823x - 0.0162) What is the numerical value for the slope shown? 2.) What are the Unit(s) associated with the slope of the line shown? for we all remember that numerical data always has units. 3.) What would be a good title for this graph and explain your choice. 0.00 0.0 02 0.4 10.6 08 10 12 -0.20 -0.40 -0.60 -0.80 Temp, freezing, in degrees Celcius 5-1.00 -1.20 -1.40 -1:60 y=-1.823x-0.0162 -180 -2.00 Concentration of Sucrose (m)arrow_forwardDon't used Ai solutionarrow_forward
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- 3. Devise a retrosynthesis for the problem given below and then provide the corresponding synthesis with all necessary reagents/reactants: RETROSYNTHESIS: SYNTHESIS: Brarrow_forwardSeveral square planar complexes are known for Gold (III) ions but not for Silver (III) why?arrow_forwardAiter running various experiments, you determine that the mechanism for the following reaction is bimolecular. CI Using this information, draw the correct mechanism in the space below. X Explanation Check C Cl OH + CI Add/Remove step Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Carrow_forward
- Complete the reaction in the fewest number of steps as possible, Draw all intermediates (In the same form as the picture provided) and provide all reagents.arrow_forwardPlease provide steps to work for complete understanding.arrow_forwardPlease provide steps to work for complete understanding.arrow_forward
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