
EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
8th Edition
ISBN: 9780134554433
Author: CORWIN
Publisher: PEARSON CO
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Chapter 11, Problem 2E
Interpretation Introduction
Interpretation:
The general properties of the liquids are to be predicted.
Concept introduction:
The liquids take the shape of their container. The liquid state is an intermediate state between the solid and gaseous state. The liquid particles have more intermolecular space than the solid state but less than that of the gaseous state.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 11 Solutions
EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
Ch. 11 - Prob. 1CECh. 11 - Prob. 2CECh. 11 - Prob. 3CECh. 11 - Prob. 4CECh. 11 - Prob. 5CECh. 11 - Prob. 6CECh. 11 - Prob. 7CECh. 11 - Prob. 8CECh. 11 - Prob. 1KTCh. 11 - Prob. 2KT
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