EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
8th Edition
ISBN: 9780134554433
Author: CORWIN
Publisher: PEARSON CO
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Chapter 11, Problem 15E
Interpretation Introduction
(a)
Interpretation:
The compound having the higher viscosity is to be stated.
Concept introduction:
The viscosity is the property of liquid defined as the resistance to flow. The viscosity of the liquid is directly proportional to the force of attractions among the molecules of the liquid. It also depends upon the shape and size of the molecule.
Interpretation Introduction
(b)
Interpretation:
The compound having the higher viscosity is to be stated.
Concept introduction:
The viscosity is the property of liquid defined as the resistance to flow. The viscosity of the liquid is directly proportional to the force of attractions among the molecules of the liquid. It also depends upon the shape and size of the molecule.
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Below is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide (OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero
formal charges. In the third box, draw the two enantiomeric products that will be produced.
5th attempt
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1000
4th attempt
Feedback
Please draw all four bonds at chiral centers.
8.
R5
HO:
See Periodic Table
See Hint
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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Chapter 11 Solutions
EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
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