Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 11, Problem 11.67EP
Interpretation Introduction
Interpretation: The base that would get depleted first in the given replication process is to be stated.
Concept introduction: DNA stands for Deoxyribonucleic acid. A DNA molecule contains genetic information required for the maintenance, functioning and growth of an organism. DNA molecules are generated by a process known as
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 11 Solutions
Organic And Biological Chemistry
Ch. 11.1 - Which of the following statements concerning...Ch. 11.1 - Which of the following statements concerning...Ch. 11.2 - Any given nucleotide in a nucleic acid contains a....Ch. 11.2 - How many different sugars and how many different...Ch. 11.2 - How many different heterocyclic bases that are...Ch. 11.3 - Which of the following is present in nucleotides...Ch. 11.3 - Prob. 2QQCh. 11.3 - Prob. 3QQCh. 11.3 - Prob. 4QQCh. 11.4 - Prob. 1QQ
Ch. 11.4 - Prob. 2QQCh. 11.4 - Prob. 3QQCh. 11.4 - In a segment of a nucleic acid a terminal...Ch. 11.4 - Prob. 5QQCh. 11.5 - Which of the following statements concerning a DNA...Ch. 11.5 - Prob. 2QQCh. 11.5 - Prob. 3QQCh. 11.5 - Prob. 4QQCh. 11.6 - Prob. 1QQCh. 11.6 - In DNA replication the DNA double helix unwinds...Ch. 11.6 - Prob. 3QQCh. 11.6 - Prob. 4QQCh. 11.6 - Prob. 5QQCh. 11.7 - Prob. 1QQCh. 11.7 - The product of the first phase of protein...Ch. 11.8 - Prob. 1QQCh. 11.8 - Prob. 2QQCh. 11.8 - Prob. 3QQCh. 11.8 - Prob. 4QQCh. 11.9 - Which of the following statements concerning the...Ch. 11.9 - What is the complementary hnRNA base sequence...Ch. 11.9 - The location in a DNA strand carrying the...Ch. 11.9 - Prob. 4QQCh. 11.9 - Which of the following types of RNA is not part of...Ch. 11.10 - Prob. 1QQCh. 11.10 - The genetic code is a listing that gives...Ch. 11.10 - Prob. 3QQCh. 11.10 - Without reference to the genetic code, which of...Ch. 11.11 - Which of the following is an incorrect pairing of...Ch. 11.11 - Prob. 2QQCh. 11.11 - A tRNA molecule with the anticodon 5 AAG 3 will...Ch. 11.12 - Which of the following statements about ribosomes...Ch. 11.12 - Prob. 2QQCh. 11.12 - Prob. 3QQCh. 11.12 - Prob. 4QQCh. 11.12 - Prob. 5QQCh. 11.13 - Which of the following describes the effect of a...Ch. 11.13 - Prob. 2QQCh. 11.13 - Which of the following statements applies to both...Ch. 11.14 - Prob. 1QQCh. 11.14 - Prob. 2QQCh. 11.15 - Prob. 1QQCh. 11.15 - Prob. 2QQCh. 11.15 - The role of E. coli plasmids in obtaining rDNA is...Ch. 11.15 - Prob. 4QQCh. 11.15 - Prob. 5QQCh. 11.16 - Prob. 1QQCh. 11.16 - Prob. 2QQCh. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following pentoses is...Ch. 11 - Indicate whether each of the pentoses in Problem...Ch. 11 - With the help of Figure 22-2, identify each of the...Ch. 11 - With the help of Figure 22-2, identify each of the...Ch. 11 - With the help of Figure 22-2, what is the...Ch. 11 - With the help of Figure 22-2, what is the...Ch. 11 - With the help of Figure 22-2, indicate whether...Ch. 11 - With the help of Figure 22-2, indicate whether...Ch. 11 - Prob. 11.11EPCh. 11 - How many different choices are there for each of...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.14EPCh. 11 - What is the name of the nucleoside that contains...Ch. 11 - What is the name of the nucleoside that contains...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following is a DNA...Ch. 11 - Indicate whether each of the following is a DNA...Ch. 11 - Prob. 11.21EPCh. 11 - Prob. 11.22EPCh. 11 - What nitrogen-containing base and what sugar are...Ch. 11 - What nitrogen-containing base and what sugar are...Ch. 11 - Prob. 11.25EPCh. 11 - Prob. 11.26EPCh. 11 - Consider the following nucleotide. a. What is the...Ch. 11 - Consider the following nucleotide. a. What is the...Ch. 11 - Prob. 11.29EPCh. 11 - Prob. 11.30EPCh. 11 - For the trinucleotide 5 GCA 3 a. How many...Ch. 11 - For the trinucleotide 5 UCG 3 a. How many...Ch. 11 - Is the trinucleotide in Problem 22-31 found only...Ch. 11 - Is the trinucleotide in Problem 22-32 found only...Ch. 11 - In the lengthening of a polynucleotide chain,...Ch. 11 - Prob. 11.36EPCh. 11 - Draw the structure of the RNA dinucleotide 5 UG 3.Ch. 11 - Draw the structure of the DNA dinucleotide 5 TA 3.Ch. 11 - For the trinucleotide 5 T-G-A 3 a. How many...Ch. 11 - For the trinucleotide 5 U-C-G 3 a. How many...Ch. 11 - Prob. 11.41EPCh. 11 - Prob. 11.42EPCh. 11 - Prob. 11.43EPCh. 11 - Prob. 11.44EPCh. 11 - The base content of a particular DNA molecule is...Ch. 11 - The base content of a particular DNA molecule is...Ch. 11 - What structural consideration prevents the bases A...Ch. 11 - What structural consideration prevents the bases C...Ch. 11 - The base composition for one of the strands of a...Ch. 11 - The base composition for one of the strands of a...Ch. 11 - Convert each of the following 3-to-5 DNA base...Ch. 11 - Convert each of the following 3-to-5 DNA base...Ch. 11 - Using the concept of complementary base pairing,...Ch. 11 - Using the concept of complementary base pairing,...Ch. 11 - For the DNA segment 5 TTGCAC 3 how many of each of...Ch. 11 - For the DNA segment 5 TAGATG 3 how many of each of...Ch. 11 - What is the base sequence, specified in the 5-to-3...Ch. 11 - What is the base sequence, specified in the 5-to-3...Ch. 11 - In the replication of a DNA molecule, two daughter...Ch. 11 - In the replication of a DNA molecule, two daughter...Ch. 11 - How does the synthesis of a daughter DNA strand...Ch. 11 - In the context of DNA replication, what is the...Ch. 11 - Prob. 11.63EPCh. 11 - Prob. 11.64EPCh. 11 - Prob. 11.65EPCh. 11 - Prob. 11.66EPCh. 11 - Prob. 11.67EPCh. 11 - Prob. 11.68EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.70EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.72EPCh. 11 - Prob. 11.73EPCh. 11 - Prob. 11.74EPCh. 11 - Indicate whether the predominant cellular location...Ch. 11 - Indicate whether the predominant cellular location...Ch. 11 - Indicate whether each of the following situations...Ch. 11 - Indicate whether each of the following processes...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.81EPCh. 11 - What is the base sequence, given in the 5-to-3...Ch. 11 - For each of the following DNA template strands,...Ch. 11 - For each of the following DNA template strands,...Ch. 11 - Prob. 11.85EPCh. 11 - Prob. 11.86EPCh. 11 - Prob. 11.87EPCh. 11 - Prob. 11.88EPCh. 11 - What mRNA base sequence, specified in the 5-to-3...Ch. 11 - Prob. 11.90EPCh. 11 - Prob. 11.91EPCh. 11 - What mRNA base sequence, specified in the 5-to-3...Ch. 11 - Prob. 11.93EPCh. 11 - Prob. 11.94EPCh. 11 - Prob. 11.95EPCh. 11 - Prob. 11.96EPCh. 11 - Prob. 11.97EPCh. 11 - Prob. 11.98EPCh. 11 - Prob. 11.99EPCh. 11 - Prob. 11.100EPCh. 11 - Prob. 11.101EPCh. 11 - Using the information in Table 22-2, determine...Ch. 11 - Using the information in Table 22-2, determine the...Ch. 11 - Prob. 11.104EPCh. 11 - Explain why the base sequence ATC could not be a...Ch. 11 - Explain why the base sequence AGAC could not be a...Ch. 11 - Prob. 11.107EPCh. 11 - Predict the sequence of amino acids coded by the...Ch. 11 - Prob. 11.109EPCh. 11 - Prob. 11.110EPCh. 11 - Determine each of the following items using the...Ch. 11 - Prob. 11.112EPCh. 11 - Prob. 11.113EPCh. 11 - Prob. 11.114EPCh. 11 - Prob. 11.115EPCh. 11 - Prob. 11.116EPCh. 11 - Prob. 11.117EPCh. 11 - Prob. 11.118EPCh. 11 - Which amino acid will a tRNA molecule be carrying...Ch. 11 - Prob. 11.120EPCh. 11 - Prob. 11.121EPCh. 11 - Identify the amino acid associated with each of...Ch. 11 - Prob. 11.123EPCh. 11 - Prob. 11.124EPCh. 11 - Indicate whether each of the following statements...Ch. 11 - Prob. 11.126EPCh. 11 - Prob. 11.127EPCh. 11 - Prob. 11.128EPCh. 11 - Prob. 11.129EPCh. 11 - Prob. 11.130EPCh. 11 - Prob. 11.131EPCh. 11 - Prob. 11.132EPCh. 11 - Which of these RNA types(1) mRNA, (2) hnRNA, (3)...Ch. 11 - Prob. 11.134EPCh. 11 - Consider the following mRNA base sequence 5CUUCAG3...Ch. 11 - Consider the following mRNA base sequence 5ACCCAC3...Ch. 11 - Consider the following DNA base sequence 3TTAATA5...Ch. 11 - Prob. 11.138EPCh. 11 - The DNA template strand segment 3TTCAAACCGTAC5...Ch. 11 - The DNA template strand segment 3TTCAAACCGTAC5...Ch. 11 - Prob. 11.141EPCh. 11 - Prob. 11.142EPCh. 11 - Prob. 11.143EPCh. 11 - Prob. 11.144EPCh. 11 - Prob. 11.145EPCh. 11 - Prob. 11.146EPCh. 11 - Prob. 11.147EPCh. 11 - Prob. 11.148EPCh. 11 - Prob. 11.149EPCh. 11 - Prob. 11.150EPCh. 11 - Prob. 11.151EPCh. 11 - Which of the following processes(1) transcription...Ch. 11 - Prob. 11.153EPCh. 11 - Prob. 11.154EP
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