Whether cytosine is a nucleotide , nucleoside or neither a nucleotide nor a nucleoside has to be predicted. Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Question

Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

Answer 1

Question

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

Draw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He command

Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9

Answer 2

Question

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

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Answer 3

Question

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

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Answer 4

Question

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

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Answer 5

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 6

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 7

Chapter 11, Problem 11.30EP

(a)

Interpretation Introduction

Interpretation: Whether cytosine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 8

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 9

(b)

Interpretation Introduction

Interpretation: Whether cytidine is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 10

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 11

(c)

Interpretation Introduction

Interpretation: Whether CMP is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 12

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 13

(d)

Interpretation Introduction

Interpretation: Whether deoxycytidine 5’-monophosphate is a nucleotide, nucleoside or neither a nucleotide nor a nucleoside has to be predicted.

Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Answer 14

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Answer 25

Ch. 11.1 - Which of the following statements concerning...Ch. 11.1 - Which of the following statements concerning...Ch. 11.2 - Any given nucleotide in a nucleic acid contains a....Ch. 11.2 - How many different sugars and how many different...Ch. 11.2 - How many different heterocyclic bases that are...Ch. 11.3 - Which of the following is present in nucleotides...Ch. 11.3 - Prob. 2QQ Ch. 11.3 - Prob. 3QQ Ch. 11.3 - Prob. 4QQ Ch. 11.4 - Prob. 1QQ

Whether cytosine is a nucleotide , nucleoside or neither a nucleotide nor a nucleoside has to be predicted. Concept introduction: A nucleotide consists of a pentose sugar, a nitrogen-containing base, and a phosphate group while a nucleoside consists of a nitrogen-containing base and a pentose sugar.

Solution Summary: The author explains that cytosine is a nucleotide, while cytidine is not.

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