You have to show the unit of rate is L m o l − 1 s − 1 Concept introduction: A + B → C + D R a t e = K [ A ] x [ B y ] This expression is known as equation of rate law. x : Order of reaction w.r.t A Y: order of reaction w.r.t B x + y : Overall order of reaction

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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2 pts) 1) HBr (no peroxides) 2) H- NaNH2 Br 3) NaNH, 4) CH3Br 5) H2, Pd (b) Starting with the molecule shown below and any other materials with two carbons or less, write out an alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major product in all the steps in your synthesis. (5 pts) 2024 Fall Term (1) Organic Chemistry 1 (Lec) CHEM 22204 02[6386] (Hunter College) (c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from your synthesis in part (b). (5 pts)

Answer 1

Question

Chapter 11, Problem 11.27PAE

Interpretation Introduction

Interpretation: You have to show the unit of rate is Lmol−1s−1

Concept introduction:

A+B→C+D

Rate=K[A]x[By] This expression is known as equation of rate law.

x: Order of reaction w.r.t A

Y: order of reaction w.r.t B

x+y: Overall order of reaction

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