Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 11, Problem 11.60PAE
(a)
Interpretation Introduction
To determine: The rate law for the given reaction.
(b)
Interpretation Introduction
To determine: The rate law for the given reaction.
(c)
Interpretation Introduction
To determine: The rate law for the given reaction.
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Chapter 11 Solutions
Chemistry for Engineering Students
Ch. 11 - Prob. 1COCh. 11 - . define the rate of a chemical reaction and...Ch. 11 - Prob. 3COCh. 11 - Prob. 4COCh. 11 - . explain the difference between elementary...Ch. 11 - . find the rate law predicted for a particular...Ch. 11 - . use a molecular perspective to explain the...Ch. 11 - Prob. 8COCh. 11 - . explain the role of a catalyst in the design of...Ch. 11 - Prob. 11.1PAE
Ch. 11 - List two types of chemical compounds that must be...Ch. 11 - Prob. 11.3PAECh. 11 - Prob. 11.4PAECh. 11 - Prob. 11.5PAECh. 11 - Prob. 11.6PAECh. 11 - Asphalt is composed of a mixture of organic...Ch. 11 - Prob. 11.8PAECh. 11 - Prob. 11.9PAECh. 11 - For each of the following, suggest appropriate...Ch. 11 - Prob. 11.11PAECh. 11 - Rank the following in order of increasing reaction...Ch. 11 - Prob. 11.13PAECh. 11 - Candle wax is a mixture of hydrocarbons. In the...Ch. 11 - Prob. 11.15PAECh. 11 - The reaction for the Haber process, the industrial...Ch. 11 - 11.17 Ammonia can react with oxygen to produce...Ch. 11 - The following data were obtained in the...Ch. 11 - Prob. 11.19PAECh. 11 - Experimental data are listed here for the reaction...Ch. 11 - Azomethane, CH3NNCH3, is not a stable compound,...Ch. 11 - Prob. 11.22PAECh. 11 - A reaction has the experimental rate equation Rate...Ch. 11 - Second-order rate constants used in modeling...Ch. 11 - For each of the rate laws below, what is the order...Ch. 11 - 11.26 The reaction of C(Xg) with NO2(g) is second...Ch. 11 - Prob. 11.27PAECh. 11 - Prob. 11.28PAECh. 11 - The hypothetical reaction, A + B —*C, has the rate...Ch. 11 - The rate of the decomposition of hydrogen...Ch. 11 - Prob. 11.31PAECh. 11 - 11.32 The following experimental data were...Ch. 11 - The following experimental data were obtained for...Ch. 11 - 11.34 Rate data were obtained at 25°C for the...Ch. 11 - 11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) +...Ch. 11 - The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a...Ch. 11 - Prob. 11.37PAECh. 11 - Prob. 11.38PAECh. 11 - The decomposition of N2O5 in solution in carbon...Ch. 11 - In Exercise 11.39, if the initial concentration of...Ch. 11 - 11.41 For a drug to be effective in treating an...Ch. 11 - Amoxicillin is an antibiotic packaged as a powder....Ch. 11 - As with any drug, aspirin (acetylsalicylic acid)...Ch. 11 - 11.44 A possible reaction for the degradation of...Ch. 11 - The initial concentration of the reactant in a...Ch. 11 - A substance undergoes first-order decomposition....Ch. 11 - Prob. 11.47PAECh. 11 - 11.48 The following data were collected for the...Ch. 11 - The rate of photodecomposition of the herbicide...Ch. 11 - Prob. 11.50PAECh. 11 - 11.51 Peroxyacetyl nitrate (PAN) has the chemical...Ch. 11 - Hydrogen peroxide (H20i) decomposes into water and...Ch. 11 - 11.53 The reaction in which CO, decomposes to CO...Ch. 11 - use the kineticmolecular theory to explain why an...Ch. 11 - The following rate constants were obtained in an...Ch. 11 - The table below presents measured rate constants...Ch. 11 - Prob. 11.57PAECh. 11 - Prob. 11.58PAECh. 11 - Can a reaction mechanism ever be proven correct?...Ch. 11 - Prob. 11.60PAECh. 11 - Describe how the Chapman cycle is a reaction...Ch. 11 - Prob. 11.62PAECh. 11 - The following mechanism is proposed for a...Ch. 11 - 11.64 HBr is oxidized in the following reaction: 4...Ch. 11 - Prob. 11.65PAECh. 11 - Prob. 11.66PAECh. 11 - What distinguishes homogeneous and heterogeneous...Ch. 11 - Prob. 11.68PAECh. 11 - In Chapter 3, we discussed the conversion of...Ch. 11 - The label on a bottle of 3% (by volume) hydrogen...Ch. 11 - Prob. 11.71PAECh. 11 - Prob. 11.72PAECh. 11 - Prob. 11.73PAECh. 11 - 11.74 The AQI includes six levels, including...Ch. 11 - Prob. 11.75PAECh. 11 - Prob. 11.76PAECh. 11 - Prob. 11.77PAECh. 11 - Prob. 11.78PAECh. 11 - Prob. 11.79PAECh. 11 - Prob. 11.80PAECh. 11 - Prob. 11.81PAECh. 11 - Prob. 11.82PAECh. 11 - Bacteria cause milk to go sour by generating...Ch. 11 - Prob. 11.84PAECh. 11 - Prob. 11.85PAECh. 11 - Prob. 11.86PAECh. 11 - Prob. 11.87PAECh. 11 - Prob. 11.88PAECh. 11 - Prob. 11.89PAECh. 11 - 11.90 Draw a hypothetical activation energy...Ch. 11 - Prob. 11.91PAECh. 11 - Prob. 11.92PAECh. 11 - 11.93 On a particular day, the ozone level in...Ch. 11 - Prob. 11.94PAECh. 11 - The following is a thought experiment. Imagine...Ch. 11 - The following statements relate to the reaction...Ch. 11 - Prob. 11.97PAECh. 11 - Experiments show that the reaction of nitrogen...Ch. 11 - Substances that poison a catalyst pose a major...Ch. 11 - Prob. 11.100PAECh. 11 - Prob. 11.101PAECh. 11 - 11.102 Suppose that you are studying a reaction...Ch. 11 - Prob. 11.103PAECh. 11 - Prob. 11.104PAECh. 11 - Prob. 11.105PAECh. 11 - Prob. 11.106PAECh. 11 - 11.1047 Fluorine often reacts explosively. What...Ch. 11 - Prob. 11.108PAECh. 11 - Prob. 11.109PAECh. 11 - When formic acid is heated, it decomposes to...
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- The Raschig reaction produces the industrially important reducing agent hydrazine, N2H4, from ammonia, NH3, and hypochlorite ion, OCl−, in basic aqueous solution. A proposed mechanism is Step 1: Step 2: Step 3: What is the overall stoichiometric equation? Which step is rate-limiting? What reaction intermediates are involved? What rate law is predicted by this mechanism?arrow_forwardFor the reaction A+BC, explain at least two ways in which the rate law could be zero order in chemical A.arrow_forward. find the rate law predicted for a particular reaction mechanism.arrow_forward
- One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall reaction? What rate law would be derived from this mechanism? What effect does increasing the concentration of the product NO2 have on the reaction rate?arrow_forwardExplain how a species might be part of a rate law but not part of a balanced chemical reaction.arrow_forwardDefine stability from both a kinetic and thermodynamic perspective. Give examples to show the differences in these concepts.arrow_forward
- Why does a catalyst increase the rate of a reaction? What is the difference between a homogeneous catalyst and a heterogeneous catalyst? Would a given reaction necessarily have the same rate law for both a catalyzed and an uncatalyzed pathway? Explain.arrow_forwardNitryl fluoride is an explosive compound that can be made by oxidizing nitrogen dioxide with fluorine: 2 NO2(g) + F2(g) → 2 NO2F(g) Several kinetics experiments, all done at the same temperature and involving formation of nitryl fluoride, are summarized in this table: Write the rate law for the reaction. Determine what the order of the reaction is with respect to each reactant and each product. Calculate the rate constant k and express it in appropriate units.arrow_forwardA reaction is believed to occur by the following mechanism: Stepl: 2AI (Fast equilibrium) Step 2: I + B C (Slow) Overall: 2 A + B C What experimentally determined rate law would lead to this mechanism? (a) Rate = k[A][B] (b) Rate = k[A]2[B] (c) Rate = k[A]2 (d) Rate = k[I][B]arrow_forward
- Isomerization of CH3NC occurs slowly when CH3NC is heated. CH3NC(g) CH3CN(g) To study the rate of this reaction at 488 K, data on [CH3NC] were collected at various times. Analysis led to the following graph. (a) What is the rate law for this reaction? (b) What is the equation for the straight line in this graph? (c) Calculate the rate constant for this reaction. (d) How long does it take for half of the sample to isomerize? (e) What is the concentration of CH3NC after 1.0 104 s?arrow_forwardOne experimental procedure that can be used to determine the rate law of a reaction is the method of initial rates. What data are gathered in the method of initial rates, and how are these data manipulated to determine k and the orders of the species in the rate law? Are the units for k. the rate constant, the same for all rate laws? Explain. If a reaction is first order in A, what happens to the rate if [A] is tripled? If the initial rate for a reaction increases by a factor of 16 when [A] is quadrupled, what is the order of n? If a reaction is third order in A and [A] is doubled, what happens to the initial rate? If a reaction is zero order, what effect does [A] have on the initial rate of a reaction?arrow_forwardThe type of rate law for a reaction, either the differential rate law or the integrated rate law, is usually determined by which data is easiest to collect. Explain.arrow_forward
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