General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
Question
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Chapter 11, Problem 11.27EP

(a)

Interpretation Introduction

Interpretation:

Half-life of the radionuclide has to be determined if after 5.4 days, 1/16 fraction of undecayed nuclide is present.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  All the radioactive nuclide do not undergo the decay at a same rate.  Some decay rapidly and others decay very slowly.  The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life.  It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amountofradionuclideundecayedafternhalflives) =  (Originalamountofradionuclide)  x  (12n)

(a)

Expert Solution
Check Mark

Answer to Problem 11.27EP

Half-life of the radionuclide is 1.4 days.

Explanation of Solution

Number of half-lives can be determined as shown below,

(12n) = 116(12n) = 1242n = 24

As the bases are equal, the power can be equated.  This gives the number of half-lives that have elapsed as 4 half-lives.

In the problem statement it is given that the time is 5.4 days.  From the number of half-lives elapsed and the total time given, the length of one half-life can be calculated as shown below,

5.4 days   x  (1 half-lifet1/2) = 4 half-lives t1/2 = 5.4 days4 = 1.4days

Therefore, the half-life of the given sample is determined as 1.4 days.

Conclusion

Half-life of the given sample is determined.

(b)

Interpretation Introduction

Interpretation:

Half-life of the radionuclide has to be determined if after 5.4 days, 1/64 fraction of undecayed nuclide is present.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  All the radioactive nuclide do not undergo the decay at a same rate.  Some decay rapidly and others decay very slowly.  The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life.  It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amountofradionuclideundecayedafternhalflives) =  (Originalamountofradionuclide)  x  (12n)

(b)

Expert Solution
Check Mark

Answer to Problem 11.27EP

Half-life of the radionuclide is 0.90 day.

Explanation of Solution

Number of half-lives can be determined as shown below,

(12n) = 164(12n) = 1262n = 26

As the bases are equal, the power can be equated.  This gives the number of half-lives that have elapsed as 6 half-lives.

In the problem statement it is given that the time is 5.4 days.  From the number of half-lives elapsed and the total time given, the length of one half-life can be calculated as shown below,

5.4 days   x  (1 half-lifet1/2) = 6 half-lives t1/2 = 5.4 days6 = 0.90day

Therefore, the half-life of the given sample is determined as 0.90 day.

Conclusion

Half-life of the given sample is determined.

(c)

Interpretation Introduction

Interpretation:

Half-life of the radionuclide has to be determined if after 5.4 days, 1/256 fraction of undecayed nuclide is present.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  All the radioactive nuclide do not undergo the decay at a same rate.  Some decay rapidly and others decay very slowly.  The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life.  It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amountofradionuclideundecayedafternhalflives) =  (Originalamountofradionuclide)  x  (12n)

(c)

Expert Solution
Check Mark

Answer to Problem 11.27EP

Half-life of the radionuclide is 0.68 day.

Explanation of Solution

Number of half-lives can be determined as shown below,

(12n) = 1256(12n) = 1282n = 28

As the bases are equal, the power can be equated.  This gives the number of half-lives that have elapsed as 8 half-lives.

In the problem statement it is given that the time is 5.4 days.  From the number of half-lives elapsed and the total time given, the length of one half-life can be calculated as shown below,

5.4 days   x  (1 half-lifet1/2) = 8 half-lives t1/2 = 5.4 days8 = 0.68day

Therefore, the half-life of the given sample is determined as 0.68 day.

Conclusion

Half-life of the given sample is determined.

(d)

Interpretation Introduction

Interpretation:

Half-life of the radionuclide has to be determined if after 5.4 days, 1/1024 fraction of undecayed nuclide is present.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  All the radioactive nuclide do not undergo the decay at a same rate.  Some decay rapidly and others decay very slowly.  The nuclear stability can be quantitatively expressed by using the half-life.

The time required for half quantity of the radioactive substance to undergo decay is known as half-life.  It is represented as t1/2.

The equation that relates amount of decayed radioactive material, amount of undecayed radioactive material and the time elapsed can be given as,

(Amountofradionuclideundecayedafternhalflives) =  (Originalamountofradionuclide)  x  (12n)

(d)

Expert Solution
Check Mark

Answer to Problem 11.27EP

Half-life of the radionuclide is 0.54 day.

Explanation of Solution

Number of half-lives can be determined as shown below,

(12n) = 11024(12n) = 12102n = 210

As the bases are equal, the power can be equated.  This gives the number of half-lives that have elapsed as 10 half-lives.

In the problem statement it is given that the time is 5.4 days.  From the number of half-lives elapsed and the total time given, the length of one half-life can be calculated as shown below,

5.4 days   x  (1 half-lifet1/2) = 10 half-lives t1/2 = 5.4 days10 = 0.54day

Therefore, the half-life of the given sample is determined as 0.54 day.

Conclusion

Half-life of the given sample is determined.

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Chapter 11 Solutions

General, Organic, and Biological Chemistry

Ch. 11.4 - The half-life of cobalt-60 is 5.2 years. This...Ch. 11.4 - Prob. 2QQCh. 11.4 - Prob. 3QQCh. 11.4 - Prob. 4QQCh. 11.4 - Prob. 5QQCh. 11.5 - Prob. 1QQCh. 11.5 - The bombardment reaction involving 1123Na and 12H...Ch. 11.5 - Prob. 3QQCh. 11.5 - Prob. 4QQCh. 11.6 - Prob. 1QQCh. 11.6 - In the 14-step uranium-238 decay series a. all...Ch. 11.7 - Prob. 1QQCh. 11.7 - Prob. 2QQCh. 11.8 - Which of the following is not a form of ionizing...Ch. 11.8 - Prob. 2QQCh. 11.8 - Prob. 3QQCh. 11.8 - Prob. 4QQCh. 11.9 - Prob. 1QQCh. 11.9 - Which of the following correctly orders the three...Ch. 11.10 - Prob. 1QQCh. 11.10 - Prob. 2QQCh. 11.10 - Prob. 3QQCh. 11.11 - Prob. 1QQCh. 11.11 - Prob. 2QQCh. 11.11 - Prob. 3QQCh. 11.12 - Prob. 1QQCh. 11.12 - Prob. 2QQCh. 11.12 - Prob. 3QQCh. 11.12 - Prob. 4QQCh. 11.13 - Prob. 1QQCh. 11.13 - Prob. 2QQCh. 11 - Prob. 11.1EPCh. 11 - Prob. 11.2EPCh. 11 - Prob. 11.3EPCh. 11 - Prob. 11.4EPCh. 11 - Prob. 11.5EPCh. 11 - Prob. 11.6EPCh. 11 - Prob. 11.7EPCh. 11 - Prob. 11.8EPCh. 11 - Prob. 11.9EPCh. 11 - Prob. 11.10EPCh. 11 - Prob. 11.11EPCh. 11 - Prob. 11.12EPCh. 11 - Prob. 11.13EPCh. 11 - Prob. 11.14EPCh. 11 - Prob. 11.15EPCh. 11 - Prob. 11.16EPCh. 11 - Prob. 11.17EPCh. 11 - Prob. 11.18EPCh. 11 - Prob. 11.19EPCh. 11 - Prob. 11.20EPCh. 11 - Prob. 11.21EPCh. 11 - Prob. 11.22EPCh. 11 - Prob. 11.23EPCh. 11 - Prob. 11.24EPCh. 11 - Prob. 11.25EPCh. 11 - Prob. 11.26EPCh. 11 - Prob. 11.27EPCh. 11 - Prob. 11.28EPCh. 11 - Prob. 11.29EPCh. 11 - Fill in the blanks in each line of the following...Ch. 11 - Prob. 11.31EPCh. 11 - Prob. 11.32EPCh. 11 - Prob. 11.33EPCh. 11 - Prob. 11.34EPCh. 11 - Prob. 11.35EPCh. 11 - Prob. 11.36EPCh. 11 - Prob. 11.37EPCh. 11 - Prob. 11.38EPCh. 11 - Prob. 11.39EPCh. 11 - Prob. 11.40EPCh. 11 - Prob. 11.41EPCh. 11 - Prob. 11.42EPCh. 11 - Prob. 11.43EPCh. 11 - Prob. 11.44EPCh. 11 - Prob. 11.45EPCh. 11 - Prob. 11.46EPCh. 11 - Prob. 11.47EPCh. 11 - Prob. 11.48EPCh. 11 - Prob. 11.49EPCh. 11 - Prob. 11.50EPCh. 11 - Prob. 11.51EPCh. 11 - Prob. 11.52EPCh. 11 - Prob. 11.53EPCh. 11 - Prob. 11.54EPCh. 11 - Prob. 11.55EPCh. 11 - Prob. 11.56EPCh. 11 - Prob. 11.57EPCh. 11 - Write a chemical equation that involves water as a...Ch. 11 - Prob. 11.59EPCh. 11 - Prob. 11.60EPCh. 11 - Prob. 11.61EPCh. 11 - Prob. 11.62EPCh. 11 - Prob. 11.63EPCh. 11 - Prob. 11.64EPCh. 11 - Prob. 11.65EPCh. 11 - Prob. 11.66EPCh. 11 - Prob. 11.67EPCh. 11 - Prob. 11.68EPCh. 11 - Prob. 11.69EPCh. 11 - Prob. 11.70EPCh. 11 - Prob. 11.71EPCh. 11 - Prob. 11.72EPCh. 11 - Prob. 11.73EPCh. 11 - Prob. 11.74EPCh. 11 - Prob. 11.75EPCh. 11 - Prob. 11.76EPCh. 11 - Prob. 11.77EPCh. 11 - Prob. 11.78EPCh. 11 - Prob. 11.79EPCh. 11 - Prob. 11.80EPCh. 11 - Prob. 11.81EPCh. 11 - Prob. 11.82EPCh. 11 - Prob. 11.83EPCh. 11 - Prob. 11.84EPCh. 11 - Prob. 11.85EPCh. 11 - Prob. 11.86EPCh. 11 - Prob. 11.87EPCh. 11 - Prob. 11.88EPCh. 11 - Prob. 11.89EPCh. 11 - Prob. 11.90EP
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