General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 11, Problem 11.43EP

(a)

Interpretation Introduction

Interpretation:

Equation for berylllum-9 bombarded with an alpha particle giving neutron as product has to be written.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  This is a natural transmutation reaction where the nuclide of one element is converted into nuclide of another element.  Radioactive decay happens naturally.  This can also be done artificially in the laboratory by means of bombardment reaction.  Bombardment reaction is the one where the target nuclei is hit by a small fast moving high-energy particle to give a daughter nuclide and a small particle such as proton or neutron.  This can be represented in form of a nuclear equation.  A balanced nuclear equation is the one in which the sum of subscripts on both sides are equal and sum of superscripts on both sides are equal.

(b)

Interpretation Introduction

Interpretation:

Equation for sodium-23 bombarded with a hydrogen-2 giving neon-21 as product has to be written.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  This is a natural transmutation reaction where the nuclide of one element is converted into nuclide of another element.  Radioactive decay happens naturally.  This can also be done artificially in the laboratory by means of bombardment reaction.  Bombardment reaction is the one where the target nuclei is hit by a small fast moving high-energy particle to give a daughter nuclide and a small particle such as proton or neutron.  This can be represented in form of a nuclear equation.  A balanced nuclear equation is the one in which the sum of subscripts on both sides are equal and sum of superscripts on both sides are equal.

(c)

Interpretation Introduction

Interpretation:

Equation for cadmium-113 giving cadmium-114 and gamma ray on bombardment with a small particle has to be written.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  This is a natural transmutation reaction where the nuclide of one element is converted into nuclide of another element.  Radioactive decay happens naturally.  This can also be done artificially in the laboratory by means of bombardment reaction.  Bombardment reaction is the one where the target nuclei is hit by a small fast moving high-energy particle to give a daughter nuclide and a small particle such as proton or neutron.  This can be represented in form of a nuclear equation.  A balanced nuclear equation is the one in which the sum of subscripts on both sides are equal and sum of superscripts on both sides are equal.

(d)

Interpretation Introduction

Interpretation:

Equation for bombarding a nuclide with alpha particle that gives phosphorus-30 and neutron has to be written.

Concept Introduction:

Radioactive nuclides undergo disintegration by emission of radiation.  This is a natural transmutation reaction where the nuclide of one element is converted into nuclide of another element.  Radioactive decay happens naturally.  This can also be done artificially in the laboratory by means of bombardment reaction.  Bombardment reaction is the one where the target nuclei is hit by a small fast moving high-energy particle to give a daughter nuclide and a small particle such as proton or neutron.  This can be represented in form of a nuclear equation.  A balanced nuclear equation is the one in which the sum of subscripts on both sides are equal and sum of superscripts on both sides are equal.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 11 Solutions

General, Organic, and Biological Chemistry

Ch. 11.4 - The half-life of cobalt-60 is 5.2 years. This...Ch. 11.4 - Prob. 2QQCh. 11.4 - Prob. 3QQCh. 11.4 - Prob. 4QQCh. 11.4 - Prob. 5QQCh. 11.5 - Prob. 1QQCh. 11.5 - The bombardment reaction involving 1123Na and 12H...Ch. 11.5 - Prob. 3QQCh. 11.5 - Prob. 4QQCh. 11.6 - Prob. 1QQCh. 11.6 - In the 14-step uranium-238 decay series a. all...Ch. 11.7 - Prob. 1QQCh. 11.7 - Prob. 2QQCh. 11.8 - Which of the following is not a form of ionizing...Ch. 11.8 - Prob. 2QQCh. 11.8 - Prob. 3QQCh. 11.8 - Prob. 4QQCh. 11.9 - Prob. 1QQCh. 11.9 - Which of the following correctly orders the three...Ch. 11.10 - Prob. 1QQCh. 11.10 - Prob. 2QQCh. 11.10 - Prob. 3QQCh. 11.11 - Prob. 1QQCh. 11.11 - Prob. 2QQCh. 11.11 - Prob. 3QQCh. 11.12 - Prob. 1QQCh. 11.12 - Prob. 2QQCh. 11.12 - Prob. 3QQCh. 11.12 - Prob. 4QQCh. 11.13 - Prob. 1QQCh. 11.13 - Prob. 2QQCh. 11 - Prob. 11.1EPCh. 11 - Prob. 11.2EPCh. 11 - Prob. 11.3EPCh. 11 - Prob. 11.4EPCh. 11 - Prob. 11.5EPCh. 11 - Prob. 11.6EPCh. 11 - Prob. 11.7EPCh. 11 - Prob. 11.8EPCh. 11 - Prob. 11.9EPCh. 11 - Prob. 11.10EPCh. 11 - Prob. 11.11EPCh. 11 - Prob. 11.12EPCh. 11 - Prob. 11.13EPCh. 11 - Prob. 11.14EPCh. 11 - Prob. 11.15EPCh. 11 - Prob. 11.16EPCh. 11 - Prob. 11.17EPCh. 11 - Prob. 11.18EPCh. 11 - Prob. 11.19EPCh. 11 - Prob. 11.20EPCh. 11 - Prob. 11.21EPCh. 11 - Prob. 11.22EPCh. 11 - Prob. 11.23EPCh. 11 - Prob. 11.24EPCh. 11 - Prob. 11.25EPCh. 11 - Prob. 11.26EPCh. 11 - Prob. 11.27EPCh. 11 - Prob. 11.28EPCh. 11 - Prob. 11.29EPCh. 11 - Fill in the blanks in each line of the following...Ch. 11 - Prob. 11.31EPCh. 11 - Prob. 11.32EPCh. 11 - Prob. 11.33EPCh. 11 - Prob. 11.34EPCh. 11 - Prob. 11.35EPCh. 11 - Prob. 11.36EPCh. 11 - Prob. 11.37EPCh. 11 - Prob. 11.38EPCh. 11 - Prob. 11.39EPCh. 11 - Prob. 11.40EPCh. 11 - Prob. 11.41EPCh. 11 - Prob. 11.42EPCh. 11 - Prob. 11.43EPCh. 11 - Prob. 11.44EPCh. 11 - Prob. 11.45EPCh. 11 - Prob. 11.46EPCh. 11 - Prob. 11.47EPCh. 11 - Prob. 11.48EPCh. 11 - Prob. 11.49EPCh. 11 - Prob. 11.50EPCh. 11 - Prob. 11.51EPCh. 11 - Prob. 11.52EPCh. 11 - Prob. 11.53EPCh. 11 - Prob. 11.54EPCh. 11 - Prob. 11.55EPCh. 11 - Prob. 11.56EPCh. 11 - Prob. 11.57EPCh. 11 - Write a chemical equation that involves water as a...Ch. 11 - Prob. 11.59EPCh. 11 - Prob. 11.60EPCh. 11 - Prob. 11.61EPCh. 11 - Prob. 11.62EPCh. 11 - Prob. 11.63EPCh. 11 - Prob. 11.64EPCh. 11 - Prob. 11.65EPCh. 11 - Prob. 11.66EPCh. 11 - Prob. 11.67EPCh. 11 - Prob. 11.68EPCh. 11 - Prob. 11.69EPCh. 11 - Prob. 11.70EPCh. 11 - Prob. 11.71EPCh. 11 - Prob. 11.72EPCh. 11 - Prob. 11.73EPCh. 11 - Prob. 11.74EPCh. 11 - Prob. 11.75EPCh. 11 - Prob. 11.76EPCh. 11 - Prob. 11.77EPCh. 11 - Prob. 11.78EPCh. 11 - Prob. 11.79EPCh. 11 - Prob. 11.80EPCh. 11 - Prob. 11.81EPCh. 11 - Prob. 11.82EPCh. 11 - Prob. 11.83EPCh. 11 - Prob. 11.84EPCh. 11 - Prob. 11.85EPCh. 11 - Prob. 11.86EPCh. 11 - Prob. 11.87EPCh. 11 - Prob. 11.88EPCh. 11 - Prob. 11.89EPCh. 11 - Prob. 11.90EP
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