Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 10.5, Problem 12CC
Interpretation Introduction

Interpretation:

The target molecule should be drawn and identified for the given string molecule by using its molecular formula.

Concept Introduction:

Birch reduction: The conjugated alkynes and benzenes in the presence of sodium metal in liquid ammonia and alkyne produced a non-conjugated diene system. The alkyne involves sodium (Na)/NH3 . Further alkyne triple bond end parts reducing to give the trans (E) alkene.

Metal reduction: The alkyne molecules can also be reduced to trans alkenes via an entirely different reaction called dissolving metal (Na/NH3) .

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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