Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 10, Problem 38PP
Interpretation Introduction

Interpretation:

The different alkene, alkane products formed for each given alkyne substrates when treated with a different reducing reagents are needed to be find out.

Concept Introduction:

Platinum reduction reaction: The alkenes can be reduced to alkanes with H2 in the presence of metal catalyst (Pt). The two new C-H σ bonds are formed simultaneously from H atoms absorbed into the metal surface. Further this reaction stereospecific giving only the cis (syn) addition product.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

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(9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception tothe general ionization energy (IE) trend. For the two elements involved, answer the followingquestions. Be sure to cite sources for all physical data that you use.a. (2 pts) Identify the two elements and write their electronic configurations.b. (2 pts) Based on their configurations, propose a reason for the IE trend exception.c. (5 pts) Calculate effective nuclear charges for the last electron in each element and theAllred-Rochow electronegativity values for the two elements. Can any of these valuesexplain the IE trend exception? Explain how (not) – include a description of how IErelates to electronegativity.
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