Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 10.4, Problem 9P
Interpretation Introduction
Interpretation:
The mass spectra of 1-chloropropane has to be drawn.
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What molecular ions will be present in a mass spectrum of 2-chloropropane,(CH3)2CHCl ?
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Define Mass spectrum of 2-chloropropane [(CH3)2CHCl]
Chapter 10 Solutions
Essential Organic Chemistry, Global Edition
Ch. 10.1 - Prob. 1PCh. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3PCh. 10.3 - Prob. 5PCh. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7PCh. 10.4 - Prob. 8PCh. 10.4 - Prob. 9PCh. 10.5 - Prob. 10PCh. 10.5 - Prob. 11P
Ch. 10.6 - Identify the ketone responsible for the mass...Ch. 10.6 - Prob. 13PCh. 10.8 - Prob. 14PCh. 10.8 - Prob. 15PCh. 10.12 - Which will occur at a larger wavenumber: a. a C :...Ch. 10.13 - Which will occur at a larger wavenumber: a. the C...Ch. 10.13 - Prob. 18PCh. 10.13 - Prob. 19PCh. 10.13 - Which will show an O 8 H stretch at a larger...Ch. 10.14 - Prob. 21PCh. 10.14 - Prob. 22PCh. 10.15 - Prob. 23PCh. 10.15 - Prob. 24PCh. 10.17 - Prob. 25PCh. 10.18 - Prob. 26PCh. 10.18 - Prob. 27PCh. 10.19 - Prob. 28PCh. 10.19 - Prob. 29PCh. 10.22 - How many signals would you expect to see in the 1H...Ch. 10.22 - Prob. 31PCh. 10.22 - Prob. 32PCh. 10.23 - Where would you expect to find the 1H NMR signal...Ch. 10.24 - Prob. 34PCh. 10.25 - Prob. 35PCh. 10.25 - Prob. 36PCh. 10.25 - Prob. 37PCh. 10.26 - Prob. 38PCh. 10.26 - Which of the following compounds is responsible...Ch. 10.27 - Prob. 40PCh. 10.27 - Prob. 41PCh. 10.27 - The 1H NMR spectra of two carboxylic acids with...Ch. 10.28 - Prob. 43PCh. 10.28 - Prob. 44PCh. 10.28 - Prob. 45PCh. 10.28 - Describe the 1H NMR spectrum you would expect for...Ch. 10.28 - Identify the compound with molecular formula...Ch. 10.29 - Prob. 48PCh. 10.29 - Prob. 49PCh. 10.29 - Identify the compound with a molecular formula of...Ch. 10 - In the mass spectrum of the following compounds,...Ch. 10 - For each of the following pairs of compounds,...Ch. 10 - Draw the structure of a saturated hydrocarbon that...Ch. 10 - Prob. 54PCh. 10 - Prob. 55PCh. 10 - How could you use UV spectroscopy to distinguish...Ch. 10 - Prob. 57PCh. 10 - Predict the relative intensities of the molecular...Ch. 10 - Prob. 59PCh. 10 - List the following compounds in order from highest...Ch. 10 - How can 1H NMR be used to prove that the addition...Ch. 10 - There are four esters with molecular formula...Ch. 10 - Prob. 63PCh. 10 - Prob. 64PCh. 10 - Each of the IR spectra presented here is...Ch. 10 - Prob. 66PCh. 10 - Five compounds are shown for each of the following...Ch. 10 - Prob. 68PCh. 10 - Prob. 69PCh. 10 - Phenolphthalein is an acidbase indicator. In...Ch. 10 - Which one of the following five compounds produced...Ch. 10 - Prob. 72PCh. 10 - Prob. 73PCh. 10 - Prob. 74PCh. 10 - How could 1H NMR distinguish between the compounds...Ch. 10 - Prob. 76PCh. 10 - Prob. 77PCh. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - Identify the following compounds. (Relative...Ch. 10 - An alkyl halide reacts with an alkoxide ion to...Ch. 10 - Determine the structure of a compound with...
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- Is the compound giving rise to the mass spectrum shown here more likely to contain sulfur, bromine, or chlorine? Explain. 100 80 - 60- 40 20 40 80 120 160 m/z Relative abundance -유arrow_forwardc) The mass spectrum of 2,3-dibromopentane (CH; CHBr CHBr CH₂ CH3) includes the following peaks. Mass number (m/z) Relative abundance 15 29 107 109 199 201 203 i. What is the mass number of molecular ion, [CH; CHBr CHBr CH₂ CH₂]? Show your working. ii. Identify the molecular formula (including isotopic composition where relevant) of the 6 peaks. a b d 22 e f Mass number (m/z) 15 29 107 109 199 100 39 44 45 0.3 0.6 0.3 201 203 Molecule formula [CH₂]arrow_forwardIn a mass spectrum, what m/z value would correspond to the fragment shown below?arrow_forward
- The molecular weight of compound D is calculated to be 359.22 g/mol., However, the mass spectrum contains two peakS, with m/z 358.02 and m/z @360.02, in a approximately a 1:1 ratio. Explain this observation. HTML Editorgarrow_forwardMass spectrometry is often used to both identify and quantify compounds. What is different between mass spectra with changing concentrations of a compound? How would you design a method (i.e. what would you need) to both identify and quantify a compound using mass spectrometry?arrow_forward4. Halogenated compounds are particularly easy to identify by their mass spectra because chlorine and bromine occur naturally as mixtures of two abundant isotopes. Chlorine occurs as "CI (75.8%) and "CI (24.2%). Ignore the presence of "C isotopes. For the compound, C,H,Cl;: a) At what masses do the molecular ions occur? b)What are the percentages of cach molecular ion?arrow_forward
- 3. Both methylcycloheptane and ethylcyclohexane have the same molecular mass. Explain how is it possible to distinguish between the two compounds by studying and comparing both their mass spectra.arrow_forwardGive handwritten answer of questions no. 4arrow_forwardQ.1. Explain why, even though the average atomic mass of silver is 107.9amu, no peak at 108 amu is observed in the mass spectrum of pure silver. What effect does this absence have on form of mass spectra of silver compounds? a)arrow_forward
- b) Can these two molecules shown below be distinguished by mass spectrometry? Give reasons for your answer.arrow_forward5arrow_forwardFollowing is the mass spectrum of bromocyclopentane. The molecular ion m/z 148 is of such low intensity that it does not appear in this spectrum. Assign structural formulas for the cations of m/z 69 and 41.arrow_forward
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