Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 10.3, Problem 10.10YT
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SH
0
2.
Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the
two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction
energies in order to identify the lower energy conformer for each stereoisomer. Based on your
calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable.
[1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3
CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol)
all-cis-1,2,3-
1
all-cis-1,2,4-
2
None
Chapter 10 Solutions
Laboratory Manual Chemistry in Context
Ch. 10.2 - Skill Building Checking on Carbon a. Examine the...Ch. 10.2 - Prob. 10.7YTCh. 10.3 - Skill Building Ester Formation Draw structural...Ch. 10.3 - Prob. 10.10YTCh. 10.4 - Prob. 10.11CTCh. 10.4 - You Decide Supersize My Aspirin A friend who...Ch. 10.5 - Modern methods of drug discovery involve...Ch. 10.5 - Make two lists of drugs for each of the two...Ch. 10.5 - See for yourself the shapes of drug molecules by...Ch. 10.6 - Prob. 10.17YT
Ch. 10.6 - Prob. 10.18CTCh. 10.10 - Prob. 10.24CTCh. 10.10 - Prob. 10.25CTCh. 10.10 - Prob. 10.26YTCh. 10 - Prob. 10.1CTCh. 10 - Prob. 1QCh. 10 - Prob. 2QCh. 10 - Prob. 3QCh. 10 - Write the structural formula and line-angle...Ch. 10 - Prob. 5QCh. 10 - Prob. 6QCh. 10 - Prob. 7QCh. 10 - Prob. 8QCh. 10 - Prob. 9QCh. 10 - Prob. 10QCh. 10 - Prob. 11QCh. 10 - Prob. 12QCh. 10 - Prob. 13QCh. 10 - Prob. 14QCh. 10 - Prob. 15QCh. 10 - Prob. 16QCh. 10 - Prob. 17QCh. 10 - Prob. 18QCh. 10 - Prob. 19QCh. 10 - Prob. 20QCh. 10 - Prob. 21QCh. 10 - Sulfanilamide is the simplest sulfa drug, a type...Ch. 10 - Prob. 23QCh. 10 - Prob. 24QCh. 10 - Prob. 25QCh. 10 - Prob. 26QCh. 10 - Molecules as diverse as cholesterol, sex hormones,...Ch. 10 - The text states that some racemic mixtures contain...Ch. 10 - Draw structural formulas for each of these...Ch. 10 - Prob. 30QCh. 10 - In Your Turn 12.12, you were asked to draw...Ch. 10 - Prob. 32QCh. 10 - Prob. 33QCh. 10 - Prob. 34QCh. 10 - Prob. 35QCh. 10 - Prob. 36QCh. 10 - Prob. 37QCh. 10 - Prob. 38QCh. 10 - Prob. 39QCh. 10 - Prob. 40QCh. 10 - Prob. 41QCh. 10 - Prob. 42QCh. 10 - Dorothy Crowfoot Hodgkin first determined the...Ch. 10 - Prob. 46QCh. 10 - Prob. 47QCh. 10 - Prob. 49QCh. 10 - Prob. 51QCh. 10 - Prob. 52QCh. 10 - Prob. 54QCh. 10 - Prob. 55QCh. 10 - Prob. 56QCh. 10 - Prob. 57QCh. 10 - Prob. 58QCh. 10 - Prob. 59Q
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