Laboratory Manual Chemistry in Context
Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 10.2, Problem 10.7YT

(a)

Interpretation Introduction

Interpretation:

n-Butane and iso-butane is whether isomers have to be explained.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

  • • Structural isomers: They have same molecular formula but different bonding arrangements of atoms.
  • • Stereoisomers: They differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

n-Hexane and cyclohexane is whether isomers have to be explained.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

  • • Structural isomers: They have same molecular formula but different bonding arrangements of atoms.
  • • Stereoisomers: They differ in their spatial arrangement of atoms.

(c)

Interpretation Introduction

Interpretation:

The structural formula, condensed structural formula, and line-angle structure of three isomers with molecular formula C5H12 have to be drawn.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

  • • Structural isomers: They have same molecular formula but different bonding arrangements of atoms.
  • • Stereoisomers: They differ in their spatial arrangement of atoms.

In chemistry, structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

In condensed structure representation,

  • ✓  Some or all of the lines are omitted and atoms attached to carbon are written immediately after it.

In line-angle structure,

  • ✓  Only shows bonds.
  • ✓  C atoms assumed at each end and intersection of bonds and thus are not shown.
  • ✓  H atoms are not shown.
  • ✓  Assume 4 bonds to each C
  • ✓  Fulfill C’s 4 bonds by adding hydrogens.

In complete structural formula,

  • ✓  All of the atoms are shown at each end and intersection of bonds
  • ✓  H atoms are shown

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Laboratory Manual Chemistry in Context

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