General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Question
Chapter 10.12, Problem 2QQ
Interpretation Introduction
Interpretation:
From the given pairs of substance could function as a buffer in aqueous solution or not has to be determined.
Concept Introduction:
A buffer is an aqueous solution containing substances that prevent major changes in
Solution
Buffer solutions contain either a weak acid and a salt of that weak acid or a weak base and a salt of that weak base.
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E) 10n adduct effect
Which of the following aqueous mixtures would be a buffer system?
A) HCI, NaCl
B) HNO3, NaNO3
C) H3PO4, NaH2PO4
D) H2SO4, CH3COOH
E) NH3, NaOH
Which solution is a buffer?
A) a solution that is 0.100 M in HNO2 and 0.100 M in HCI
B) a solution that is 0.100 M in HNO3 and 0.100 M in NANO3
C) a solution that is 0.100 M in HNO2 and 0.100 M in NaCl
D) a solution that is 0.100 M in HNO3 and 0.100 M in NAOH
E) a solution that is 0.100 M in HNO2 and 0.100 M in NaNO2
Which of the following best characterizes the solution you get after you
re to search
PROBLEM 2
Identify if the following system will form a buffer
or not. Write "BUFFER" or "NOT A BUFFER" as
your answer.
A. 5 M H2SO4 and 0.5 M Na2SO4
B. 3 M H2C204 and 0.3 M Na2C204
С. 75 М СН3СООН and 0.75 M NaCH3COO
D. 5 M NH3 and 0.5 M NH4CI
Е. 35 М НСI and 0.35 M NaCl
Answer both parts
Chapter 10 Solutions
General, Organic, and Biological Chemistry
Ch. 10.1 - In an Arrhenius acidbase theory context, the...Ch. 10.1 - In an Arrhenius acidbase theory context, the...Ch. 10.1 - Which of the following statements concerning...Ch. 10.2 - Prob. 1QQCh. 10.2 - For the chemical reaction N3 + H2O HN3 + OH, the...Ch. 10.2 - The chemical formula for the conjugate acid of ClO...Ch. 10.2 - Which of the following is a conjugate acidbase...Ch. 10.2 - Prob. 5QQCh. 10.3 - Which of the following is not a polyprotic acid?...Ch. 10.3 - For the triprotic acid H3PO4, the reactant in the...
Ch. 10.3 - Prob. 3QQCh. 10.4 - In which of the following pairs of acids are both...Ch. 10.4 - Prob. 2QQCh. 10.4 - Prob. 3QQCh. 10.5 - Acid ionization constants give information about...Ch. 10.5 - Prob. 2QQCh. 10.5 - Which of the following is the strongest acid? a....Ch. 10.5 - Prob. 4QQCh. 10.6 - Which of the following is an inappropriate...Ch. 10.6 - Prob. 2QQCh. 10.6 - In which of the following pairs of substances are...Ch. 10.7 - Prob. 1QQCh. 10.7 - Prob. 2QQCh. 10.7 - Prob. 3QQCh. 10.8 - Prob. 1QQCh. 10.8 - Prob. 2QQCh. 10.8 - What is the [OH] in an aqueous solution in which...Ch. 10.8 - Prob. 4QQCh. 10.8 - Prob. 5QQCh. 10.9 - Prob. 1QQCh. 10.9 - Prob. 2QQCh. 10.9 - Prob. 3QQCh. 10.9 - A solution with a pH of 12.0 is a. weakly acid b....Ch. 10.9 - Prob. 5QQCh. 10.9 - If the pH of a solution increases from 4.0 to 6.0...Ch. 10.9 - Prob. 7QQCh. 10.10 - Prob. 1QQCh. 10.10 - Prob. 2QQCh. 10.11 - Prob. 1QQCh. 10.11 - Prob. 2QQCh. 10.11 - Prob. 3QQCh. 10.12 - Which of the following combinations of substances...Ch. 10.12 - Prob. 2QQCh. 10.12 - Prob. 3QQCh. 10.12 - The chemical reaction that occurs when a HCN/CN...Ch. 10.13 - Prob. 1QQCh. 10.13 - For a buffer where the acid and conjugate base are...Ch. 10.14 - Which of the following statements concerning...Ch. 10.14 - In which of the following pairs of compounds are...Ch. 10.14 - Prob. 3QQCh. 10.15 - How many equivalents of Ca2+ ion are present in a...Ch. 10.15 - Prob. 2QQCh. 10.15 - Prob. 3QQCh. 10.15 - Prob. 4QQCh. 10.16 - Determining the concentration of an acid using an...Ch. 10.16 - Prob. 2QQCh. 10.16 - Prob. 3QQCh. 10 - In Arrhenius acidbase theory, what ion is...Ch. 10 - What term is used to describe the formation of...Ch. 10 - Classify each of the following as a property of an...Ch. 10 - Classify each of the following as a property of an...Ch. 10 - Write equations depicting the behavior of the...Ch. 10 - Write equations depicting the behavior of the...Ch. 10 - Indicate whether the first listed reactant in each...Ch. 10 - Indicate whether the first listed reactant in each...Ch. 10 - Write chemical equations that show the indicated...Ch. 10 - Write chemical equations that show the indicated...Ch. 10 - Indicate whether or not the two members of each of...Ch. 10 - Indicate whether or not the two members of each of...Ch. 10 - Write the formula of each of the following. a....Ch. 10 - Write the formula of each of the following. a....Ch. 10 - Identify the conjugate acidbase pairs associated...Ch. 10 - Identify the conjugate acidbase pairs associated...Ch. 10 - The ion HCO3 is an amphiprotic ion. Write the...Ch. 10 - The ion HPO42 is an amphiprotic ion. Write the...Ch. 10 - Classify each of the following acids as...Ch. 10 - Classify each of the following acids as...Ch. 10 - Prob. 10.21EPCh. 10 - For each of the acids in Problem 10-19 indicate...Ch. 10 - Write chemical equations showing the individual...Ch. 10 - Write chemical equations showing the individual...Ch. 10 - Prob. 10.25EPCh. 10 - The formula for tartaric acid is preferably...Ch. 10 - Pyruvic acid, which is produced in metabolic...Ch. 10 - Oxaloacetic acid, which is produced in metabolic...Ch. 10 - Classify each of the acids in Problem 10-19 as a...Ch. 10 - Classify each of the acids in Problem 10-20 as a...Ch. 10 - For each of the following pairs of acids, indicate...Ch. 10 - For each of the following pairs of acids, indicate...Ch. 10 - For each of the following pairings of acid and...Ch. 10 - For each of the following pairings of acid and...Ch. 10 - The HCl in a 0.10 M HCl solution is 100%...Ch. 10 - The HNO3 in a 0.50 M HNO3 solution is 100%...Ch. 10 - The following four diagrams represent aqueous...Ch. 10 - Using the diagrams shown in Problem 10-37, which...Ch. 10 - Which of the terms weak, strong, monoprotic,...Ch. 10 - Which of the terms weak, strong, monoprotic,...Ch. 10 - Write the acid ionization constant expression for...Ch. 10 - Write the acid ionization constant expression for...Ch. 10 - Prob. 10.43EPCh. 10 - Write the base ionization constant expression for...Ch. 10 - Prob. 10.45EPCh. 10 - Using the acid ionization constant information...Ch. 10 - A 0.00300 M solution of an acid is 12% ionized....Ch. 10 - A 0.0500 M solution of a base is 7.5% ionized....Ch. 10 - Is the monoprotic acid Y or the monoprotic acid Z...Ch. 10 - Is the monoprotic acid Y or the monoprotic acid Z...Ch. 10 - Classify each of the following substances as an...Ch. 10 - Classify each of the following substances as an...Ch. 10 - Prob. 10.53EPCh. 10 - Indicate whether or not both members of each of...Ch. 10 - Prob. 10.55EPCh. 10 - Write a balanced equation for the dissociation...Ch. 10 - Indicate whether each of the following reactions...Ch. 10 - Indicate whether each of the following reactions...Ch. 10 - Without writing an equation, specify the molecular...Ch. 10 - Without writing an equation, specify the molecular...Ch. 10 - Write a balanced chemical equation to represent...Ch. 10 - Write a balanced chemical equation to represent...Ch. 10 - Prob. 10.63EPCh. 10 - Write a balanced molecular equation for the...Ch. 10 - Prob. 10.65EPCh. 10 - What is the molar hydronium ion concentration in...Ch. 10 - Indicate whether each of the solutions in Problem...Ch. 10 - Prob. 10.68EPCh. 10 - Prob. 10.69EPCh. 10 - Prob. 10.70EPCh. 10 - Prob. 10.71EPCh. 10 - Indicate whether each of the solutions in Problem...Ch. 10 - Selected information about five solutions, each at...Ch. 10 - Selected information about five solutions, each at...Ch. 10 - Calculate the pH of solutions with the following...Ch. 10 - Calculate the pH of solutions with the following...Ch. 10 - Calculate the pH of solutions with the following...Ch. 10 - Calculate the pH of solutions with the following...Ch. 10 - What is the [H3O+] value in solutions with each of...Ch. 10 - What is the [H3O+] value in solutions with each of...Ch. 10 - Prob. 10.81EPCh. 10 - What is the molar hydronium ion concentration in...Ch. 10 - Prob. 10.83EPCh. 10 - Indicate whether each of the following samples is...Ch. 10 - Selected information about five solutions, each at...Ch. 10 - Prob. 10.86EPCh. 10 - Consider the following four solutions: (1) apple...Ch. 10 - Consider the following four biological solutions:...Ch. 10 - For each of the following pairs of solutions,...Ch. 10 - Prob. 10.90EPCh. 10 - Calculate the pKa value for each of the following...Ch. 10 - Calculate the pKa value for each of the following...Ch. 10 - Acid A has a pKa value of 4.23, and acid B has a...Ch. 10 - Acid A has a pKa value of 5.71, and acid B has a...Ch. 10 - If a weak acid has a pKa value of 8.73, what is...Ch. 10 - If a weak acid has a pKa value of 7.21, what is...Ch. 10 - Classify each of the following salts as a strong...Ch. 10 - Classify each of the following salts as a strong...Ch. 10 - Prob. 10.99EPCh. 10 - Identify the ion (or ions) present in each of the...Ch. 10 - Prob. 10.101EPCh. 10 - Prob. 10.102EPCh. 10 - Both ions in the salt ammonium cyanide (NH4CN)...Ch. 10 - Both ions in the salt ammonium acetate (NH4C2H3O2)...Ch. 10 - Arrange the following 0.10 M aqueous solutions in...Ch. 10 - Arrange the following 0.10 M aqueous solutions in...Ch. 10 - Predict whether each of the following pairs of...Ch. 10 - Predict whether each of the following pairs of...Ch. 10 - Identify the two active species in each of the...Ch. 10 - Identify the two active species in each of the...Ch. 10 - Prob. 10.111EPCh. 10 - Write an equation for each of the following...Ch. 10 - Prob. 10.113EPCh. 10 - Prob. 10.114EPCh. 10 - Prob. 10.115EPCh. 10 - A buffer solution has a pH value of 9.8. Which...Ch. 10 - The following four diagrams represent aqueous...Ch. 10 - Using the diagrams shown in Problem 10-117, which...Ch. 10 - Identify the buffer system(s)the conjugate...Ch. 10 - Identify the buffer system(s)the conjugate...Ch. 10 - Prob. 10.121EPCh. 10 - Prob. 10.122EPCh. 10 - What is the pH of a buffer that is 0.230 M in a...Ch. 10 - What is the pH of a buffer that is 0.250 M in a...Ch. 10 - What is the pH of a buffer that is 0.150 M in a...Ch. 10 - What is the pH of a buffer that is 0.175 M in a...Ch. 10 - Classify each of the following compounds as a...Ch. 10 - Classify each of the following compounds as a...Ch. 10 - Indicate whether solutions of each of the...Ch. 10 - Indicate whether solutions of each of the...Ch. 10 - How many ions, per formula unit, are produced when...Ch. 10 - How many ions, per formula unit, are produced when...Ch. 10 - Write a balanced chemical equation for the...Ch. 10 - Prob. 10.134EPCh. 10 - Four different substances of the generalized...Ch. 10 - Which of the diagrams in Problem 10-135 represents...Ch. 10 - Indicate the number of equivalents in each of the...Ch. 10 - Indicate the number of equivalents in each of the...Ch. 10 - Indicate the number of equivalents in each of the...Ch. 10 - Indicate the number of equivalents in each of the...Ch. 10 - A solution contains 48 mEq of Ca2+ ion. Based on...Ch. 10 - Prob. 10.142EPCh. 10 - Prob. 10.143EPCh. 10 - A solution is 0.0030 M in H2PO4 ion. What is this...Ch. 10 - Prob. 10.145EPCh. 10 - Prob. 10.146EPCh. 10 - How many mEq of HCO3 are present in a solution...Ch. 10 - How many mEq of Ca2+ are present in a solution...Ch. 10 - Determine the molarity of a NaOH solution when...Ch. 10 - Determine the molarity of a KOH solution when each...
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- For a buffer where the acid and conjugate base are present in a 1-to-1 molar ratio, the HendersonHasselbalch equation simplifies to a. pH = pKa b. pH = Ka c. pH = log(pKa) d. no correct responsearrow_forward9 PRACTICE QUESTION A titration was performed using a 25.00 mL sample of 0.15 M weak acid and 0.092 M strong base. What was the pH 5.00 mL after the equivalence point was reached? REPORT YOUR ANSWER TO 2 DECIMAL PLACES. DO NOT INCLUDE UNITS. X 12.40arrow_forwardHow many milliliters of 0.0897 M NaOH are required to titrate 10.00 mL of 0.1150M weak diprotic acid to the second equivalence point? no correct answer 6.4 25.6 51.2 12.8arrow_forward
- Titration Problemarrow_forwardIncorrect Question 5 Consider the titration graph below, select all statements that are TRUE. 14 12 10 4. 20.0 0 0 100.0 t. of10 M Na ed Trace 2 represents a strong base titration to a strong acid. Trace #1 represents a strong acid titration to a weak base O Trace #1 represents a strong base titration to a weak acid 2 Trace #2 represents a strong acid titration to a strong base Both a and b points are within the buffer regianarrow_forwardExperiment 2: Investigating the Properties of Buffer Solutions Test Data: pH of Cola Solution 2.5 pH of Borax Solution:9.7 Table 3: Observing the Effects of Acid (Cola) on Buffer A and Water Solution pH with 0 mL Cola pH with 5.0 mL Cola pH with 10.0 mL Cola pH with 20.0 mL Cola Buffer Beaker A 4.2 4.7 4.2 4.2 Water Beaker C 7 3.3 n/a n/a Table 4: Observing the Effects of Base (Borax) on Buffer B and Water Solution pH with 0 mL Borax Solution pH with 5.0 mL Borax Solution pH with 10.0 mL Borax Solution pH with 20.0 mL Borax Solution Buffer Beaker B 4.2 4.2 4.3 4.6 Water Beaker D 6.9 8.7 n/a n/a questions - .What happened when the cola and borax solutions were added to the buffers in Beakers A and B? Did either of these buffers reach their buffer capacity? How do you know - What happened when the cola and borax solutions were added to the distilled water? Is distilled…arrow_forward
- Experiment 2: Investigating the Properties of Buffer Solutions Test Data: pH of Cola Solution 2.5 pH of Borax Solution:9.7 Table 3: Observing the Effects of Acid (Cola) on Buffer A and Water Solution pH with 0 mL Cola pH with 5.0 mL Cola pH with 10.0 mL Cola pH with 20.0 mL Cola Buffer Beaker A 4.2 4.7 4.2 4.2 Water Beaker C 7 3.3 n/a n/a Table 4: Observing the Effects of Base (Borax) on Buffer B and Water Solution pH with 0 mL Borax Solution pH with 5.0 mL Borax Solution pH with 10.0 mL Borax Solution pH with 20.0 mL Borax Solution Buffer Beaker B 4.2 4.2 4.3 4.6 Water Beaker D 6.9 8.7 n/a n/a Compare the calculated pH of buffers A, B, C, D, and E to the measured pH of each of these buffers in Experiment What did you notice? Describe what may have accounted for any variations in pH if you saw any variations.arrow_forwardExperiment 2: Investigating the Properties of Buffer Solutions Test Data: pH of Cola Solution 2.5 pH of Borax Solution:9.7 Table 3: Observing the Effects of Acid (Cola) on Buffer A and Water Solution pH with 0 mL Cola pH with 5.0 mL Cola pH with 10.0 mL Cola pH with 20.0 mL Cola Buffer Beaker A 4.2 4.7 4.2 4.2 Water Beaker C 7 3.3 n/a n/a Table 4: Observing the Effects of Base (Borax) on Buffer B and Water Solution pH with 0 mL Borax Solution pH with 5.0 mL Borax Solution pH with 10.0 mL Borax Solution pH with 20.0 mL Borax Solution Buffer Beaker B 4.2 4.2 4.3 4.6 Water Beaker D 6.9 8.7 n/a n/a question What happened when the cola and borax solutions were added to the buffers in Beakers A and B? Did either of these buffers reach their buffer capacity? How do you know?arrow_forwardIncorrect Question 5 Which of the following mixtures would result in a buffered solution? Mixing 100.0 mL of 0.100 MHC1 with 100.0 mL of 0.100 M NaOH. Ⓒ Mixing 100.0 mL of 0.100 MNH3 (K=1.8 x 105) with 100.0 mL of 0.100 M NaOH. Mixing 100.0 mL of 0.100 MHCI with 100.0 mL of 0.100 MNH3; (K=1.8×10) Mixing 50.0 mL of 0.100 MHCI with 100.0 mL of 0.100 MNH3 (K₂=1.8 × 10-). O At least two of the above mixtures would result in a buffered solution.arrow_forward
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