Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Textbook Question
Chapter 10, Problem 8RQ
What is meant by an ideal gas? Under what conditions does a real gas behave most like an ideal gas?
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A student proposes the following two-step synthesis of an ether from an alcohol A:
1. strong base
A
2. R
Is the student's proposed synthesis likely to work?
If you said the proposed synthesis would work, enter the chemical
formula or common abbreviation for an appropriate strong base to use
in Step 1:
If you said the synthesis would work, draw the structure of an alcohol
A, and the structure of the additional reagent R needed in Step 2, in
the drawing area below.
If there's more than one reasonable choice for a good reaction yield,
you can draw any of them.
☐
Click and drag to start drawing a structure.
Yes
No
ロ→ロ
0|0
G
Х
D
: ☐
ப
टे
Predict the major products of this organic reaction.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between different major products.
☐
☐
: ☐
+
NaOH
HO
2
Click and drag to start
drawing a structure.
Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Chapter 10 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 10 - Prob. 1PECh. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - Prob. 4PECh. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - Prob. 10PE
Ch. 10 - Practice Exercise 10.11 How many grams of argon...Ch. 10 - Prob. 12PECh. 10 - Practice Exercise 10.13
The label on a cylinder of...Ch. 10 - A glass bulb is found to have a volume of 544.23...Ch. 10 - Sulfur dioxide is a gas that has been used in...Ch. 10 - Radon, a radioactive gas, is formed in one step of...Ch. 10 - Practice Exercise 10.17
A gaseous compound of...Ch. 10 - A compound composed of only carbon and hydrogen...Ch. 10 - Carbon disulfide is an extremely flammable liquid....Ch. 10 - In one lab, thegas-collecting apparatus used a gas...Ch. 10 - The explosive PETN, pentaerythritoltetranitrate,...Ch. 10 - Prob. 22PECh. 10 - Suppose you prepared a sample of nitrogen and...Ch. 10 - A 2.50 L sample of methane was collected over...Ch. 10 - Suppose a mixture containing 2.15 g H2 and 34.0 g...Ch. 10 - Sulfur dioxide and oxygen react according to the...Ch. 10 - Bromine has two isotopes with masses of 78.9 and...Ch. 10 - The hydrogen halide gases all have the same...Ch. 10 - Prob. 1RQCh. 10 - Prob. 2RQCh. 10 - Prob. 3RQCh. 10 - Prob. 4RQCh. 10 - Prob. 5RQCh. 10 - Prob. 6RQCh. 10 - Prob. 7RQCh. 10 - What is meant by an ideal gas? Under what...Ch. 10 - Prob. 9RQCh. 10 - Prob. 10RQCh. 10 - Prob. 11RQCh. 10 - Prob. 12RQCh. 10 - Prob. 13RQCh. 10 - Prob. 14RQCh. 10 - Prob. 15RQCh. 10 - Prob. 16RQCh. 10 - Prob. 17RQCh. 10 - Prob. 18RQCh. 10 - Prob. 19RQCh. 10 - Prob. 20RQCh. 10 - Prob. 21RQCh. 10 - Prob. 22RQCh. 10 - Prob. 23RQCh. 10 - Prob. 24RQCh. 10 - Prob. 25RQCh. 10 - Prob. 26RQCh. 10 - Prob. 27RQCh. 10 - Prob. 28RQCh. 10 - Prob. 29RQCh. 10 - Prob. 30RQCh. 10 - What does a small value for the van der Waals...Ch. 10 - Which of the molecules below has the larger value...Ch. 10 - Under the same conditions of T and V, why is the...Ch. 10 - Prob. 34RQCh. 10 - Carry out the following unit conversions: (a) 1.26...Ch. 10 - Prob. 36RQCh. 10 - Prob. 37RQCh. 10 - 10.38 What is the pressure in atm of each of the...Ch. 10 - 10.39 An open-end manometer containing mercury was...Ch. 10 - Prob. 40RQCh. 10 - Prob. 41RQCh. 10 - An open-end mercury manometer was connected to a...Ch. 10 - Prob. 43RQCh. 10 - 10.44 Suppose a gas is in a vessel connected to...Ch. 10 - Prob. 45RQCh. 10 - Prob. 46RQCh. 10 - Prob. 47RQCh. 10 - Prob. 48RQCh. 10 - Prob. 49RQCh. 10 - Prob. 50RQCh. 10 - A sample of helium at a pressure of 74$ torr and...Ch. 10 - When a sample of neon with a volume of 648 mL and...Ch. 10 - What must be the new volume of a sample of...Ch. 10 - When 286 mL of oxygen at 741 torr and 18.0C was...Ch. 10 - A sample of argon with a volume of 6.18 L, a...Ch. 10 - Prob. 56RQCh. 10 - How many milliliters of O2 are consumed in the...Ch. 10 - How many milliliters of oxygen are required to...Ch. 10 - *10.59 How many milliliters of measured at and...Ch. 10 - How many milliliters of H2O vapor, measured at...Ch. 10 - Prob. 61RQCh. 10 - Prob. 62RQCh. 10 - Prob. 63RQCh. 10 - Prob. 64RQCh. 10 - Prob. 65RQCh. 10 - Prob. 66RQCh. 10 - Prob. 67RQCh. 10 - Prob. 68RQCh. 10 - Prob. 69RQCh. 10 - 10.70 Methane is formed in landfills by the action...Ch. 10 - A chemist isolated a gas in a glass bulb with a...Ch. 10 - Prob. 72RQCh. 10 - 10.73 To three significant figures, calculate the...Ch. 10 - To three significant figures, calculate the...Ch. 10 - 10.75 What density does oxygen have at and 742...Ch. 10 - At 748.0 torr and 20.65C, what is the density of...Ch. 10 - The explosive PETN, pentaerythritol tetranitrate,...Ch. 10 - TNT, trinitrotoluene, is an explosive that can...Ch. 10 - Propylene, C3H6, reacts with hydrogen under...Ch. 10 - Nitric acid is formed when NO2 is dissolved in...Ch. 10 - A mixture of gases contains 315 torr N2, 275 torr...Ch. 10 - Prob. 82RQCh. 10 - A 1.00 L container was filled by pumping into it...Ch. 10 - A special gas mixture, BAR 97 High without NO, is...Ch. 10 - Prob. 85RQCh. 10 - Prob. 86RQCh. 10 - A 22.4 L container at 0C contains 0.300 mol N2,...Ch. 10 - A mixture of N2,O2,andCO2 Has a total pressure of...Ch. 10 - A 0.200 mol sample of a mixture of N2 and CO2 with...Ch. 10 - A sample of carbon monoxide was prepared and...Ch. 10 - Prob. 91RQCh. 10 - What volume of wet oxygen would you have to...Ch. 10 - Prob. 93RQCh. 10 - Prob. 94RQCh. 10 - Prob. 95RQCh. 10 - 10.96 For the gases which gas will effuse the...Ch. 10 - Prob. 97RQCh. 10 - Prob. 98RQCh. 10 - Uranium hexafluoride is a white solid that readily...Ch. 10 - Prob. 100RQCh. 10 - Prob. 101RQCh. 10 - A typical automobile has a weight of approximately...Ch. 10 - *10.103 Suppose you were planning to move a house...Ch. 10 - Prob. 104RQCh. 10 - Two flasks (which we will refer to as flask 1 and...Ch. 10 - *10.106 A bubble of air escaping from a divers...Ch. 10 - *10.107 In a diesel engine, the fuel is ignited...Ch. 10 - *10.108 Early one cool (60.0F) morning you start...Ch. 10 - Prob. 109RQCh. 10 - *10.110 A mixture was prepared in a 0.500 L...Ch. 10 - *10.111 A student collected 18.45 mL of H2 over...Ch. 10 - *10.112 A mixture of gases is prepared from 87.5 g...Ch. 10 - 10.113 A gas was found to have a density of...Ch. 10 - *10.114 In one analytical procedure for...Ch. 10 - Prob. 115RQCh. 10 - Prob. 116RQCh. 10 - Prob. 117RQCh. 10 - The odor of a rotten egg is caused by hydrogen...Ch. 10 - Chlorine reacts with sulfite ion to give sulfate...Ch. 10 - *10.120 In an experiment designed to prepare a...Ch. 10 - Carbon dioxide can be made in the lab by the...Ch. 10 - 10.122 Boron forms a variety of unusual compounds...Ch. 10 - Prob. 123RQCh. 10 - Carbon dioxide is implicated in global warming....Ch. 10 - Prob. 125RQCh. 10 - One of the that is implicated in decreasing the...
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