Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Textbook Question
Chapter 10, Problem 31RQ
What does a small value for the van der Waals constant a suggest about the molecules of the gas?
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Chapter 10 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 10 - Prob. 1PECh. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - Prob. 4PECh. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - Prob. 10PE
Ch. 10 - Practice Exercise 10.11 How many grams of argon...Ch. 10 - Prob. 12PECh. 10 - Practice Exercise 10.13
The label on a cylinder of...Ch. 10 - A glass bulb is found to have a volume of 544.23...Ch. 10 - Sulfur dioxide is a gas that has been used in...Ch. 10 - Radon, a radioactive gas, is formed in one step of...Ch. 10 - Practice Exercise 10.17
A gaseous compound of...Ch. 10 - A compound composed of only carbon and hydrogen...Ch. 10 - Carbon disulfide is an extremely flammable liquid....Ch. 10 - In one lab, thegas-collecting apparatus used a gas...Ch. 10 - The explosive PETN, pentaerythritoltetranitrate,...Ch. 10 - Prob. 22PECh. 10 - Suppose you prepared a sample of nitrogen and...Ch. 10 - A 2.50 L sample of methane was collected over...Ch. 10 - Suppose a mixture containing 2.15 g H2 and 34.0 g...Ch. 10 - Sulfur dioxide and oxygen react according to the...Ch. 10 - Bromine has two isotopes with masses of 78.9 and...Ch. 10 - The hydrogen halide gases all have the same...Ch. 10 - Prob. 1RQCh. 10 - Prob. 2RQCh. 10 - Prob. 3RQCh. 10 - Prob. 4RQCh. 10 - Prob. 5RQCh. 10 - Prob. 6RQCh. 10 - Prob. 7RQCh. 10 - What is meant by an ideal gas? Under what...Ch. 10 - Prob. 9RQCh. 10 - Prob. 10RQCh. 10 - Prob. 11RQCh. 10 - Prob. 12RQCh. 10 - Prob. 13RQCh. 10 - Prob. 14RQCh. 10 - Prob. 15RQCh. 10 - Prob. 16RQCh. 10 - Prob. 17RQCh. 10 - Prob. 18RQCh. 10 - Prob. 19RQCh. 10 - Prob. 20RQCh. 10 - Prob. 21RQCh. 10 - Prob. 22RQCh. 10 - Prob. 23RQCh. 10 - Prob. 24RQCh. 10 - Prob. 25RQCh. 10 - Prob. 26RQCh. 10 - Prob. 27RQCh. 10 - Prob. 28RQCh. 10 - Prob. 29RQCh. 10 - Prob. 30RQCh. 10 - What does a small value for the van der Waals...Ch. 10 - Which of the molecules below has the larger value...Ch. 10 - Under the same conditions of T and V, why is the...Ch. 10 - Prob. 34RQCh. 10 - Carry out the following unit conversions: (a) 1.26...Ch. 10 - Prob. 36RQCh. 10 - Prob. 37RQCh. 10 - 10.38 What is the pressure in atm of each of the...Ch. 10 - 10.39 An open-end manometer containing mercury was...Ch. 10 - Prob. 40RQCh. 10 - Prob. 41RQCh. 10 - An open-end mercury manometer was connected to a...Ch. 10 - Prob. 43RQCh. 10 - 10.44 Suppose a gas is in a vessel connected to...Ch. 10 - Prob. 45RQCh. 10 - Prob. 46RQCh. 10 - Prob. 47RQCh. 10 - Prob. 48RQCh. 10 - Prob. 49RQCh. 10 - Prob. 50RQCh. 10 - A sample of helium at a pressure of 74$ torr and...Ch. 10 - When a sample of neon with a volume of 648 mL and...Ch. 10 - What must be the new volume of a sample of...Ch. 10 - When 286 mL of oxygen at 741 torr and 18.0C was...Ch. 10 - A sample of argon with a volume of 6.18 L, a...Ch. 10 - Prob. 56RQCh. 10 - How many milliliters of O2 are consumed in the...Ch. 10 - How many milliliters of oxygen are required to...Ch. 10 - *10.59 How many milliliters of measured at and...Ch. 10 - How many milliliters of H2O vapor, measured at...Ch. 10 - Prob. 61RQCh. 10 - Prob. 62RQCh. 10 - Prob. 63RQCh. 10 - Prob. 64RQCh. 10 - Prob. 65RQCh. 10 - Prob. 66RQCh. 10 - Prob. 67RQCh. 10 - Prob. 68RQCh. 10 - Prob. 69RQCh. 10 - 10.70 Methane is formed in landfills by the action...Ch. 10 - A chemist isolated a gas in a glass bulb with a...Ch. 10 - Prob. 72RQCh. 10 - 10.73 To three significant figures, calculate the...Ch. 10 - To three significant figures, calculate the...Ch. 10 - 10.75 What density does oxygen have at and 742...Ch. 10 - At 748.0 torr and 20.65C, what is the density of...Ch. 10 - The explosive PETN, pentaerythritol tetranitrate,...Ch. 10 - TNT, trinitrotoluene, is an explosive that can...Ch. 10 - Propylene, C3H6, reacts with hydrogen under...Ch. 10 - Nitric acid is formed when NO2 is dissolved in...Ch. 10 - A mixture of gases contains 315 torr N2, 275 torr...Ch. 10 - Prob. 82RQCh. 10 - A 1.00 L container was filled by pumping into it...Ch. 10 - A special gas mixture, BAR 97 High without NO, is...Ch. 10 - Prob. 85RQCh. 10 - Prob. 86RQCh. 10 - A 22.4 L container at 0C contains 0.300 mol N2,...Ch. 10 - A mixture of N2,O2,andCO2 Has a total pressure of...Ch. 10 - A 0.200 mol sample of a mixture of N2 and CO2 with...Ch. 10 - A sample of carbon monoxide was prepared and...Ch. 10 - Prob. 91RQCh. 10 - What volume of wet oxygen would you have to...Ch. 10 - Prob. 93RQCh. 10 - Prob. 94RQCh. 10 - Prob. 95RQCh. 10 - 10.96 For the gases which gas will effuse the...Ch. 10 - Prob. 97RQCh. 10 - Prob. 98RQCh. 10 - Uranium hexafluoride is a white solid that readily...Ch. 10 - Prob. 100RQCh. 10 - Prob. 101RQCh. 10 - A typical automobile has a weight of approximately...Ch. 10 - *10.103 Suppose you were planning to move a house...Ch. 10 - Prob. 104RQCh. 10 - Two flasks (which we will refer to as flask 1 and...Ch. 10 - *10.106 A bubble of air escaping from a divers...Ch. 10 - *10.107 In a diesel engine, the fuel is ignited...Ch. 10 - *10.108 Early one cool (60.0F) morning you start...Ch. 10 - Prob. 109RQCh. 10 - *10.110 A mixture was prepared in a 0.500 L...Ch. 10 - *10.111 A student collected 18.45 mL of H2 over...Ch. 10 - *10.112 A mixture of gases is prepared from 87.5 g...Ch. 10 - 10.113 A gas was found to have a density of...Ch. 10 - *10.114 In one analytical procedure for...Ch. 10 - Prob. 115RQCh. 10 - Prob. 116RQCh. 10 - Prob. 117RQCh. 10 - The odor of a rotten egg is caused by hydrogen...Ch. 10 - Chlorine reacts with sulfite ion to give sulfate...Ch. 10 - *10.120 In an experiment designed to prepare a...Ch. 10 - Carbon dioxide can be made in the lab by the...Ch. 10 - 10.122 Boron forms a variety of unusual compounds...Ch. 10 - Prob. 123RQCh. 10 - Carbon dioxide is implicated in global warming....Ch. 10 - Prob. 125RQCh. 10 - One of the that is implicated in decreasing the...
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- perform stoichiometric ca1cu1uions for reactions involving gases as reactants or products.arrow_forwardUnder what conditions does the behavior of a real gas begin to differ significantly from the ideal gas law?arrow_forwardGiven that 1.00 mol of neon and 1.00 mol of hydrogen chloride gas are in separate containers at the same temperature and pressure, calculate each of the following ratios. (a) volume Ne/volume HCI (b) density Ne/density HCI (c) average translational energy Ne/average translational energy HCI (d) number of Ne atoms/number of HCl moleculesarrow_forward
- What is the value of the ideal gas constant R if the volume is specified in milliliters rather than liters?arrow_forwardWhat properties of a nonideal gas do the Vander Waals constants represent?arrow_forwardAt high temperatures, one of the van der Waals constants can be ignored. Which one? Justify your choice and write a high temperature version of the van der Waals equation of state.arrow_forward
- A 1.000-g sample of an unknown gas at 0C gives the following data: P(atm) V (L) 0.2500 3.1908 0.5000 1.5928 0.7500 1.0601 1.0000 0.7930 Use these data to calculate the value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). Plot the apparent molar masses against pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?arrow_forwardUnder what conditions would the van der Waals constant b be negative? Do you think there are any gases for which this occurs?arrow_forwardA 0.245-L flask contains 0.467 mol CO2 at 159 C. Calculate the pressure: (a) using the ideal gas law (b) using the van der Waals equation (c) Explain the reason for the difference. (d) Identify which correction (that for P or V) is dominant and why.arrow_forward
- Referring to exercises 1.6 and 1.7, does it matter if the pressure difference is caused by an ideal gas or a non-ideal gas? Explain your answer.arrow_forwardThe compression ratio in an automobile engine is the ratio of the gas pressure at the end of the compression stroke to the pressure in the beginning. Assume that compression occurs at constant temperature. The total volume of the cylinder in an automobile is 350 cm3, and the displacement the reduction in volume during the compression stroke is 309 cm3. What is the compression ratio in that engine?arrow_forwardCalculate the molar volume of ethane at 1.00 atm and 0C and at 10.0 atm and 0C, using the van der Waals equation. The van der Waals constants are given in Table 5.7. To simplify, note that the term n2a/V2 is small compared with P. Hence, it may be approximated with negligible error by substituting nRT/P from the ideal gas law for V in this term. Then the van der Waals equation can be solved for the volume. Compare the results with the values predicted by the ideal gas law.arrow_forward
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