ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 10, Problem 26P
Interpretation Introduction

Interpretation:

The monochloride products of photochemical chlorination of heptane other than 1-chloroheptane are to be listed, the percentages of all C7H15Cl isomers other than 1-chloroheptane are to be estimated given that the mixture contains 15% 1-chloroheptane and the percentage of 1-chlorododecane in the mixture of photochemical monochlorination products of dodecane is to be estimated.

Concept Introduction:

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The relative rates of replacement of different types of hydrogen atoms by a halogen in an alkane depends on the type of radical (methyl, primary, secondary or tertiary) produced.

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The product distribution depends on the relative rates and the number of equivalent sites of each type.

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