ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 10.1, Problem 2P
Interpretation Introduction

Interpretation:

The reason behind‘'it would be incorrect to conclude that the nearly equal C-Cl bond dissociation enthalpies of propyl and isopropyl chloride indicate equal stabilities of propyl and isopropyl radicals' and ‘'bond dissociation enthalpies of propane are a better indicator of the free radical stabilities'are to be explained.

Concept Introduction:

>

Bond dissociation enthalpy is the amount of energy needed for homolytic dissociation of the bond.

>

Stabilities of two radicals can be estimated from reaction enthalpies if the only difference between the two reactions is the identity of the radical.

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