ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 10.5, Problem 12P
Interpretation Introduction

Interpretation:

The compounds A and B formed in the given electrophilic addition reaction are to be identified and the reason is to be explained.

Concept introduction:

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The alkene, on reaction with hydrogen bromide without peroxide, undergoes addition reaction in a way that the hydrogen is bonded to less substituted carbon of double bond and bromine is bonded to more substituted carbon of double bond.This is called Markovnikov's rule.

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The alkene, on reaction with hydrogen bromide in the presence of peroxide, undergoes addition reaction in a way that the hydrogen is bonded to more substituted carbon of double bond and bromine is bonded to less substituted carbon of double bond.Thisis called anti-Markovnikov's rule.

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