ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 10, Problem 35DSP
Interpretation Introduction

Interpretation:

The product of the reaction given is to be determined.

Concept Introduction:

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NaBH4 is a reducing agent.In presence of the catalyst InCl3, it serves as a source of hydrogen atoms.

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The reaction of NaBH4 and InCl3 produces HInCl2 which is the actual reducing agent.

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The reaction continues through the formation of the more stable alkyl free radical.

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI OH woཡི།༠w Br H مه D CI ပ။ Br H, Br Br H₂N OMe R IN Ill N S H CI Br CI CI D OH H 1/111
Draw the two products of the reaction. H₂C. CH₂ H :0: CH3 CH₂ +1
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