GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 10, Problem 10.55QP
(a)
Interpretation Introduction
Interpretation:
Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.
Concept Introduction:
The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.
(b)
Interpretation Introduction
Interpretation:
Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.
Concept Introduction:
Refer part (a).
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2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
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Which of the following predicts the theoretical yield of SO2(g) from the reaction?
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1.2 g
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Answer B: 41 grams
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
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f1 (ppm)
30
220 210 200 190 180
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110
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-26
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46
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115
10
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0
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Chapter 10 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
Ch. 10.1 - Prob. 10.1QCh. 10.1 - Prob. 10.2QCh. 10.2 - Prob. 10.3QCh. 10.2 - Prob. 10.4QCh. 10.3 - Prob. 10.1PPCh. 10.3 - Prob. 10.5QCh. 10.3 - Prob. 10.6QCh. 10.3 - Prob. 10.2PPCh. 10.3 - Prob. 10.3PPCh. 10.3 - Heptane is a very poor fuel and is given a zero on...
Ch. 10.4 - Name each of the following cycloalkanes using...Ch. 10.4 - Prob. 10.6PPCh. 10.4 - Prob. 10.7PPCh. 10.6 - Write a balanced equation for the complete...Ch. 10.6 - Write a balanced equation for each of the...Ch. 10.6 - Prob. 10.8QCh. 10 - Prob. 10.9QPCh. 10 - Prob. 10.10QPCh. 10 - Prob. 10.12QPCh. 10 - Prob. 10.13QPCh. 10 - Prob. 10.14QPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Prob. 10.17QPCh. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.21QPCh. 10 - Describe the major differences between ionic and...Ch. 10 - For centuries, fishermen have used shark liver oil...Ch. 10 - Prob. 10.24QPCh. 10 - Prob. 10.25QPCh. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.29QPCh. 10 - Prob. 10.30QPCh. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - Prob. 10.33QPCh. 10 - Prob. 10.34QPCh. 10 - Prob. 10.35QPCh. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - Prob. 10.39QPCh. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - Prob. 10.51QPCh. 10 - Prob. 10.52QPCh. 10 - Prob. 10.53QPCh. 10 - Prob. 10.54QPCh. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Prob. 10.58QPCh. 10 - Prob. 10.59QPCh. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - Prob. 10.63QPCh. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Prob. 10.67QPCh. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - Are the following names correct or incorrect? If...Ch. 10 - In your own words, describe the steps used to name...Ch. 10 - Draw the structures of the following compounds....Ch. 10 - Prob. 10.80QPCh. 10 - Prob. 10.81QPCh. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Draw each of the following...Ch. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Which of the following names are correct and which...Ch. 10 - Which of the following names are correct and which...Ch. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - Prob. 10.95QPCh. 10 - Prob. 10.96QPCh. 10 - What are conformational isomers?
Ch. 10 - Prob. 10.98QPCh. 10 - Make a model of cyclohexane and compare the boat...Ch. 10 - Prob. 10.100QPCh. 10 - Prob. 10.101QPCh. 10 - Prob. 10.102QPCh. 10 - Prob. 10.103QPCh. 10 - Prob. 10.104QPCh. 10 - Prob. 10.105QPCh. 10 - Prob. 10.106QPCh. 10 - Prob. 10.107QPCh. 10 - Prob. 10.108QPCh. 10 - Prob. 10.109QPCh. 10 - Prob. 10.110QPCh. 10 - Prob. 10.111QPCh. 10 - Prob. 10.112QPCh. 10 - Prob. 1MCPCh. 10 - Prob. 2MCPCh. 10 - Prob. 3MCPCh. 10 - Indicate which of the following are true of...Ch. 10 - Prob. 7MCPCh. 10 - Prob. 8MCPCh. 10 - Prob. 9MCPCh. 10 - Prob. 10MCP
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