GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 10, Problem 10.31QP
(a)
Interpretation Introduction
Interpretation:
Line formula for 4-ethyl-2-methylhexane has to be drawn.
Concept Introduction:
Organic compounds can be drawn from its IUPAC name. Initially, the parent chain is identified from the IUPAC name. After that the carbon chain is drawn with carbon atoms alone. Next step is to add the substituents in the respective positions as indicated in the IUPAC name. Remaining valency of carbon atom is satisfied by adding correct number of hydrogen atoms.
Line formula is the simplest representation of molecule. Carbon atoms are not explicitly shown in line formula. Intersection of lines and the end point of line are considered as carbon atoms. At the end-point it is understood as methyl group. Heteroatoms and hydrogen bonded to the heteroatoms are shown explicitly.
(b)
Interpretation Introduction
Interpretation:
Line formula for 2,3-dimethylhexane has to be drawn.
Concept Introduction:
Refer part (a).
(c)
Interpretation Introduction
Interpretation:
Line formula for 3,3-dimethylhexane has to be drawn.
Concept Introduction:
Refer part (a).
(d)
Interpretation Introduction
Interpretation:
Line formula for 3-ethylpentane has to be drawn.
Concept Introduction:
Refer part (a).
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2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
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1.2 g
Answer A: 1.2 grams
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Answer B: 41 grams
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Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
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46
30
20
115
10
1.0 0.9 0.8
0
-10
Chapter 10 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
Ch. 10.1 - Prob. 10.1QCh. 10.1 - Prob. 10.2QCh. 10.2 - Prob. 10.3QCh. 10.2 - Prob. 10.4QCh. 10.3 - Prob. 10.1PPCh. 10.3 - Prob. 10.5QCh. 10.3 - Prob. 10.6QCh. 10.3 - Prob. 10.2PPCh. 10.3 - Prob. 10.3PPCh. 10.3 - Heptane is a very poor fuel and is given a zero on...
Ch. 10.4 - Name each of the following cycloalkanes using...Ch. 10.4 - Prob. 10.6PPCh. 10.4 - Prob. 10.7PPCh. 10.6 - Write a balanced equation for the complete...Ch. 10.6 - Write a balanced equation for each of the...Ch. 10.6 - Prob. 10.8QCh. 10 - Prob. 10.9QPCh. 10 - Prob. 10.10QPCh. 10 - Prob. 10.12QPCh. 10 - Prob. 10.13QPCh. 10 - Prob. 10.14QPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Prob. 10.17QPCh. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.21QPCh. 10 - Describe the major differences between ionic and...Ch. 10 - For centuries, fishermen have used shark liver oil...Ch. 10 - Prob. 10.24QPCh. 10 - Prob. 10.25QPCh. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.29QPCh. 10 - Prob. 10.30QPCh. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - Prob. 10.33QPCh. 10 - Prob. 10.34QPCh. 10 - Prob. 10.35QPCh. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - Prob. 10.39QPCh. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - Prob. 10.51QPCh. 10 - Prob. 10.52QPCh. 10 - Prob. 10.53QPCh. 10 - Prob. 10.54QPCh. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Prob. 10.58QPCh. 10 - Prob. 10.59QPCh. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - Prob. 10.63QPCh. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Prob. 10.67QPCh. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - Are the following names correct or incorrect? If...Ch. 10 - In your own words, describe the steps used to name...Ch. 10 - Draw the structures of the following compounds....Ch. 10 - Prob. 10.80QPCh. 10 - Prob. 10.81QPCh. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Draw each of the following...Ch. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Which of the following names are correct and which...Ch. 10 - Which of the following names are correct and which...Ch. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - Prob. 10.95QPCh. 10 - Prob. 10.96QPCh. 10 - What are conformational isomers?
Ch. 10 - Prob. 10.98QPCh. 10 - Make a model of cyclohexane and compare the boat...Ch. 10 - Prob. 10.100QPCh. 10 - Prob. 10.101QPCh. 10 - Prob. 10.102QPCh. 10 - Prob. 10.103QPCh. 10 - Prob. 10.104QPCh. 10 - Prob. 10.105QPCh. 10 - Prob. 10.106QPCh. 10 - Prob. 10.107QPCh. 10 - Prob. 10.108QPCh. 10 - Prob. 10.109QPCh. 10 - Prob. 10.110QPCh. 10 - Prob. 10.111QPCh. 10 - Prob. 10.112QPCh. 10 - Prob. 1MCPCh. 10 - Prob. 2MCPCh. 10 - Prob. 3MCPCh. 10 - Indicate which of the following are true of...Ch. 10 - Prob. 7MCPCh. 10 - Prob. 8MCPCh. 10 - Prob. 9MCPCh. 10 - Prob. 10MCP
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