Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 83E
Use the mass spectrum of lead shown here to estimate the
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Chemistry: Structure and Properties
Ch. 1 - Which statement is true about matter? a) Matter is...Ch. 1 - A chemist mixes sodium with water and witnesses a...Ch. 1 - Two samples of a compound containing elements A...Ch. 1 - A compound containing only carbon and hydrogen has...Ch. 1 - Which concept was demostrated by Rutherford’s gold...Ch. 1 - A student re-creates Millikan’s oil drop...Ch. 1 - Prob. 7SAQCh. 1 - An isotope of an element contains 82 protons and...Ch. 1 - How many electrons are in the Cr3+ ion? 24...Ch. 1 - A naturally occurring sample of an element...
Ch. 1 - Copper has an atomic mass of 63.55 amu and two...Ch. 1 - Which sample contains the greatest number of...Ch. 1 - Explain this statement in your own words and give...Ch. 1 - Explain the main goal of chemistry.Ch. 1 - What are two different ways to classify matter?Ch. 1 - How do solids, liquids, and gases differ?Ch. 1 - Explain the difference between a pure substance...Ch. 1 - Explain the difference between an element and a...Ch. 1 - Explain the difference between a homogeneous and a...Ch. 1 - Describe the scientific approach to knowledge. How...Ch. 1 - Prob. 9ECh. 1 - What observations did Antoine Lavoisier make? What...Ch. 1 - What theory did John Dalton formulate?Ch. 1 - What is wrong with the expression, “That is just a...Ch. 1 - Summarize the history of the atomic idea. How was...Ch. 1 - Prob. 14ECh. 1 - State and explain the law of definite proportions.Ch. 1 - State and explain the law of multiple proportions....Ch. 1 - What are the main ideas in Dalton’s atomic theory?...Ch. 1 - How and by whom was the electron discovered? What...Ch. 1 - Explain Millikan’s oil drop experiment and how it...Ch. 1 - Prob. 20ECh. 1 - Describe Rutherford’s gold foil experiment. How...Ch. 1 - Describe Rutherford’s nuclear model of the atom....Ch. 1 - If matter is mostly empty space, as suggested by...Ch. 1 - List the three subatomic particles that compose...Ch. 1 - What defines an element?Ch. 1 - Explain the difference between Z (the atomic...Ch. 1 - Where do elements get their names?Ch. 1 - What are isotopes? What is percent natural...Ch. 1 - Describe the two different notations used to...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Explain how a mass spectrometer works. What kind...Ch. 1 - Each shape represents a type of particle (such as...Ch. 1 - Using triangles to represent one type of atom and...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Prob. 37ECh. 1 - Complete the table. Substance Pure or mixture Type...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - A chemist decomposes several samples of carbon...Ch. 1 - When astronomers observe distant galaxies, they...Ch. 1 - Prob. 45ECh. 1 - An automobile gasoline tank holds 21 kg of...Ch. 1 - Two samples of carbon tetrachloride are decomposed...Ch. 1 - Two samples of sodium chloride are decomposed into...Ch. 1 - The mass ratio of sodium to fluorine in sodium...Ch. 1 - Upon decomposition, one sample of magnesium...Ch. 1 - Two different compounds containing osmium and...Ch. 1 - Palladium forms three different compounds with...Ch. 1 - Prob. 53ECh. 1 - Sulfur and fluorine form several different...Ch. 1 - Which statements are consistent with Dalton’s...Ch. 1 - Which statements are inconsistent with Dalton’s...Ch. 1 - Which statements are consistent with Rutherford’s...Ch. 1 - Which statements are inconsistent with...Ch. 1 - A chemist in an imaginary universe, where...Ch. 1 - Imagine a unit of charge called the zorg. A...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Write isotopic symbols in the form XA (e g., C-13)...Ch. 1 - Write isotopic symbols in the form ZAX for each...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - The amount of carbon-14 in ancient artifacts and...Ch. 1 - Uranium-235 is used in nuclear fission. Determine...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Gallium has two naturally occurring isotopes with...Ch. 1 - Magnesium has three naturally occurring isotopes...Ch. 1 - The atomic mass of fluorine is 18.998 amu, and its...Ch. 1 - The atomic mass of copper is 63.546 amu. Do any...Ch. 1 - An element has two naturally occurring isotopes....Ch. 1 - An element has four naturally occuring isotopes...Ch. 1 - Bromine has two naturally occurring isotopes...Ch. 1 - Silicon has three naturally occurring isotopes...Ch. 1 - Use the mass spectrum of europium shown here to...Ch. 1 - Use the mass spectrum of rubidium shown here to...Ch. 1 - A 7.83-g sample of HCN contains 0.290 g of H and...Ch. 1 - The ratio of sulfur to oxygen by mass in SO2 is...Ch. 1 - Use the mass spectrum of lead shown here to...Ch. 1 - Use the mass spectrum of mercury shown here to...Ch. 1 - Nuclei with the same number of neutrons but...Ch. 1 - Fill in the blanks to complete the table. Symbol z...Ch. 1 - Silver is composed of two naturally occurring...Ch. 1 - To the right is a representation of 50 atoms of a...Ch. 1 - The ratio of oxygen to nitrogen by mass in NO2 is...Ch. 1 - Naturally occurring cobalt consists of only one...Ch. 1 - A 7.36-g sample of copper is contaminated with an...Ch. 1 - The ratio of the mass of O to the mass of N in...Ch. 1 - Naturally occurring magnesium has an atomic mass...Ch. 1 - A volatile liquid (one that readily evaporates) is...Ch. 1 - The diagram to the right represents solid carbon...Ch. 1 - Use triangles to represent atoms of element A and...Ch. 1 - Identify each statement as being most like an...
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- The mass spectrum of bromine (Br2) consists of three peaks with the following characteristics: Mass (u) Relative Size 157.84 0.2534 159.84 0.5000 161.84 0.2466 How do you interpret these data?arrow_forwardThe mass spectrum of phosphoryl chloride. POF3, is illustrated here. (a) Identify the cation fragment at a m/Z ratio of 85. (b) Identify the cation fragment at a m/Z ratio of 69. (c) Which two peaks in the mass spectrum provide evidence that the oxygen atom is connected to the phosphorus atom and is not connected to any of the three fluorine atoms?arrow_forwardThe element bromine is Br2, so the mass of a Br2 molecule is the sum of the mass of its two atoms. Bromine has two isotopes. The mass spectrum of Br2 produces three peaks with relative masses of 157.836, 159.834, and 161.832, and relative heights of 6.337, 12.499. and 6.164, respectively. (a) What isotopes of bromine are present in each of the three peaks? (b) What is the mass of each bromine isotope? (c) What is the average atomic mass of bromine? (d) What is the abundance of each of the two bromine isotopes?arrow_forward
- Boron consists of two isotopes, 10B and 11B. Chlorine also has two isotopes, 35Cl and 37Cl. Consider the mass spectrum of BC13. How many peaks would be present, and what approximate mass would each peak correspond to in the BCl3 mass spectrum?arrow_forwardThe mass spectrum of nitrogen dioxide is illustrated here. (a) Identify the cations present for each of the four peaks in the mass spectrum. (b) Does the mass spectrum provide evidence that the two oxygen atoms are attached to a central nitrogen atom (ONO), or that an oxygen atom is at the center (NOO)? Explain.arrow_forwardGallium arsenide, GaAs, has gained widespread use in semiconductor devices that convert light and electrical signals in fiber-optic communications systems. Gallium consists of 60.% 69Ga and 40.% 71Ga. Arsenic has only one naturally occurring isotope, 75As. Gallium arsenide is a polymeric material, but its mass spectrum shows fragments with the formulas GaAs and Ga2As2. What would the distribution of peaks look like for these two fragments?arrow_forward
- The mass spectrum of CH3Cl is illustrated here. You know that carbon has two stable isotopes, and 13C with relative abundances of 98.9% and 1.1%, respectively, and chlorine has two isotopes, 35a and 37CI with abundances of 75.77% and 24.23%, respectively. (a) What molecular species gives rise to the lines at m/Z of 50 and 52? Why is the line at 52 about 1/3 the height of the line at 50? (b) What species might be responsible for the line at m/Z = 51?arrow_forwardConsider the following data for three binary compounds of hydrogen and nitrogen: %H (by Mass) %N (by Mass) I 17.75 82.25 II 12.58 87.42 III 2.34 97.66 When 1.00 L of each gaseous compound is decomposed to its elements, the following volumes of H2(g) and N2(g) are obtained: H2(L) N2(L) I 1.50 0.50 II 2.00 1.00 III 0.50 1.50 Use these data to determine the molecular formulas of compounds I, II, and III and to determine the relative values for the atomic masses of hydrogen and nitrogen.arrow_forwardA cube of sodium has length 1.25 in. How many atoms are in that cube? (Note: dNa=0.968 g/cm3.)arrow_forward
- he chemical formula for aspirin is C9H8O4 . What is the mass percent for each element in 1 mole of aspirin? (Give your answer to four significant figures.) l type="a"> carbon > % l type="a"> hydrogen > % l type="a"> oxygen > %arrow_forwardReference Section 5-2 to find the atomic masses of 12C and 13C, the relative abundance of 12C and 13C in natural carbon, and the average mass (in u) of a carbon atom. If you had a sample of natural carbon containing exactly 10,000 atoms, determine the number of 12C and 13C atoms present. What would be the average mass (in u) and the total mass (in u) of the carbon atoms in this 10,000-atom sample? If you had a sample of natural carbon containing 6.0221 1023 atoms, determine the number of 12C and 13C atoms present What would be the average mass (in u) and the total mass (in u) of this 6.0221 1023 atom sample? Given that 1 g = 6.0221 1023 u, what is the total mass of I mole of natural carbon in units of grams?arrow_forwardThe density of gold, Au, is 19.32 g/cm3. What is the volume (in cubic centimeters) of a piece of gold that contains 2.6 × 1024 atoms?arrow_forward
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Mass Spectrometry; Author: Professor Dave Explains;https://www.youtube.com/watch?v=hSirWciIvSg;License: Standard YouTube License, CC-BY