Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Textbook Question
Chapter 1, Problem 18CTQ
Explain how there can be two kinds of bent: “bent-109.5o” and bent-120o,” and give an exampleof each from the previous question. (Note that “bent-109.5°’ is more common than “bent-120°.”)
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 1 Solutions
Custom eBook for Organic Chemistry
Ch. 1 - (E) What does the number (+Z) at the center of...Ch. 1 - Prob. 2CTQCh. 1 - Prob. 3CTQCh. 1 - Prob. 4CTQCh. 1 - Prob. 5CTQCh. 1 - Prob. 6CTQCh. 1 - Prob. 7CTQCh. 1 - You hear a student from a nearby group say that...Ch. 1 - Use VSEPR to explain why the HBH bond angle of BH3...Ch. 1 - Both the HCH and HCO bond angles of H2CO...
Ch. 1 - Prob. 11CTQCh. 1 - Consider the following flat drawing of methane...Ch. 1 - Use VSEPR to assign a value of (close to) 109.5,...Ch. 1 - A student draws the picture of ammonia (NH3) in...Ch. 1 - Prob. 15CTQCh. 1 - How many central atoms does the molecule H2NCH3...Ch. 1 - Indicate the bond angle and shape about each...Ch. 1 - Explain how there can be two kinds of bent:...Ch. 1 - A student makes the following statement: “The...Ch. 1 - A student who missed this class needs to know how...Ch. 1 - Prob. 1ECh. 1 - Prob. 2ECh. 1 - Consider the incomplete valence shell...Ch. 1 - How many valence electrons does a neutral a. K...Ch. 1 - Consider the molecules AlCl3 (aluminum chloride)...Ch. 1 - Draw an example of a bent molecule with a bond...Ch. 1 - Label each atom marked with an arrow with the...Ch. 1 - a model of each of the following molecules: a....
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