Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 1, Problem 7CTQ

(a)

Interpretation Introduction

Interpretation:

The type of bonding electron domain should be identified for each molecule in given figure.

Concept Introduction:

The bonding electron domain is defined as the shared valence electrons (2, 4, or 6 electrons) which are localized between two core atoms.

This is classified as follows:

Single bond: two electrons or 1 pair;

Double bond: four electrons or 2 pairs;

Triple bond: six electrons or 3 pairs.

The non-bonding electron domain is defined as the pair of valence electrons which are not involved in bonding.

(b)

Interpretation Introduction

Interpretation:

The number of electrons present in each bonding electron domain should be reported.

Concept Introduction:

The bonding electron domain is defined as the shared valence electrons (2, 4, or 6 electrons) which are localized between two core atoms.

This is classified as:

Single bond: two electrons or 1 pair;

Double bond: four electrons or 2 pairs;

Triple bond: six electrons or 3 pairs.

The non-bonding electron domain is defined as the pair of valence electrons that are not involved in bonding.

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1) For each condensed or skeletal structure below: A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs. B. Indicate the hybridization of all C, O, and N atoms in each of the molecules. C. Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember, e.g. that a double bond is made up of both a o and a π bond). Also indicate which orbitals overlap to form the bond (e.g., Ols-2sp3). D. For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located. E. Which of the bonds indicated by arrows is shorter? a) c) H CH3 C=CHC=C-CH g) (CH3)3CCN CH3 CH₂CH=CHCECH b) d) CH3 Lo LOH f) CH₂CH(CH3)SH h) (CH3)2CH(CH₂)3Br
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