Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 1, Problem 2CTQ
Interpretation Introduction

Interpretation:

The total number of electrons present in an oxygen atom should be determined along with the way for finding answer with the help of periodic table.

Concept Introduction:

The distribution of electrons in atom into orbitals is said to be electronic configuration. The electronic configuration for every element present in the periodic table is unique or different. Atomic number is equal to the number of protons, which is further equal to the number of electrons for neutral atom.

Periodic Table contains periods and groups. There are 18 groups and 7 periods in the periodic table. The vertical columns are known as groups and horizontal rows are known as periods. The numbering of periods is done as 1 to 7 from top to bottom and groups are named as 1A, 2A, 3B to 8B, 1B, 2B, 3A to 8A from left to right where A represents representative elements and B represents transition elements.

In periodic table, different blocks within the periodic table correspond to the s, p, d and f sublevels. Thus, on the basis of increasing atomic number in the periodic table, electronic configuration of atoms can be written.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
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