Problem 11-57 Order each of the following sets of compounds concerning SN2 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3CH2CH2Cl (a) CH3 CS Scanned with CamScanner Cl CH3CH2CHCH3
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- Problem 11-56 Order each of the following sets of compounds concerning SN1 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3 (a) CS Scanned with CamScanner H3C CH3 Cl NH 2 1 CH3CH2CHCH3PROBLEM 4-30 Rank the following radicals in decreasing order of stability. Classify each as primary, second- ary, or tertiary. (a) The isopentyl radical, (CH3)2CHCH₂-CH₂ (d) (b) The 3-methyl-2-butyl radical, CH3-CH-CH(CH3)2 (c) The 2-methyl-2-butyl radical, CH3-C(CH3)CH₂CH3PROBLEM 5-21 Which of the following compounds are chiral? Draw each compound in its most symmetric con- formation, star (*) any asymmetric carbon atoms, and draw any mirror planes. Label any meso compounds. You may use Fischer projections if you prefer. (a) meso-2,3-dibromo-2,3-dichlorobutane (b) (±)-2,3-dibromo-2,3-dichlorobutane (c) (2R,3S)-2-bromo-3-chlorobutane (d) (2R,3S)-2,3-dibromobutane (e) (R, R)-2,3-dibromobutane (f) H- HO CHO -OH -H CH₂OH H Br H. CH₂ H CH₂ H Br (h) H Br CH₂ H H CH₂ H Br
- A set of three nucleophilic displacement reactions is shown below: NaN3 CH;OH CH3CH2CHCH3 SN2 reaction A, X = | В, Х%3D Br C, X = OH Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest? Submit Answer Try Another Version 2 item attempts remaining[Relerences H;C H3C CH3 CH3 CH3 CH3 CH3 H,C CH, HO CH3 Violaxanthin How many double bonds in this terpenoid compound are capable of cis,trans isomerism? Of these, how many are in the cis configuration? Submit Answer Try Another Version 10 item attempts remainingIt is not neces Cl NO2 What is the name of the following? 1-chloro-2-nitrobenzene Submit Answer Retry Entire Group 9 more group attempts
- What are the missing reagent(s) for the reaction below? (Select all that apply? OH PBr3 A ☐ A C B D 1) ??? 2) NaCN SOCI₂ NEt3 B TSCI NEt3 с с CN HCN DPROBLEM 11-38 Develop syntheses for the following compounds. As starting materials, you may use cyclopentanol, alcohols containing no more than four carbon atoms, and any common reagents and solvents. (a) trans-cyclopentane-1,2-diol (b) 1-chloro-1-ethyleyclopentane f (c) OCH, CH₂ (e) OCH₂CH₂ C-CH₂CH₂ (1) OCH,Problem 9-42 CH=CH How would you synthesize the following compounds from acetylene and any alkyl halides with four or fewer carbons? More than one step may be needed. (a) CH3CH2CH2C=CH (b) CH3CH2C=CCH2CH3 (c) CH3 CH3CHCH2CH=CH2 л CS Scanned with CamScanner
- CH16 PE5 Please help Organic Chemistry problemPROBLEM 4-25 In the presence of a small amount of bromine, cyclohexene undergoes the following light- promoted reaction: + trace Br₂ hv cyclohexene (a) Propose a mechanism for this reaction. (b) Draw the structure of the rate-limiting transition state. Br 3-bromocyclohexene + HBrConsidering cis-trans isomers, how many compounds are possible for 3-methyl-2,4-hexadiene ? CH3-CH=Ċ-CH=CH-CH3 Submit Answer Retry Entire Group 9 more group attempts remaining