Problem 11-57Order each of the following sets of compounds concerning SN2 reactivity. Most reactive=1; Least reactive=3.CH3H3C-C-ClCH3CH2CH2Cl(a)CH3CS Scanned with CamScannerClCH3CH2CHCH3

Step 1: Step 2: Step 3: Step 4:

Answered: Problem 11-57 Order each of the…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

Section5.8: Racemic Mixtures And The Resolution Of Enantiomers

Problem 19P

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Problem 11-56 Order each of the following sets of compounds concerning SN1 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3 (a) CS Scanned with CamScanner H3C CH3 Cl NH 2 1 CH3CH2CHCH3
PROBLEM 4-30 Rank the following radicals in decreasing order of stability. Classify each as primary, second- ary, or tertiary. (a) The isopentyl radical, (CH3)2CHCH₂-CH₂ (d) (b) The 3-methyl-2-butyl radical, CH3-CH-CH(CH3)2 (c) The 2-methyl-2-butyl radical, CH3-C(CH3)CH₂CH3
PROBLEM 5-21 Which of the following compounds are chiral? Draw each compound in its most symmetric con- formation, star (*) any asymmetric carbon atoms, and draw any mirror planes. Label any meso compounds. You may use Fischer projections if you prefer. (a) meso-2,3-dibromo-2,3-dichlorobutane (b) (±)-2,3-dibromo-2,3-dichlorobutane (c) (2R,3S)-2-bromo-3-chlorobutane (d) (2R,3S)-2,3-dibromobutane (e) (R, R)-2,3-dibromobutane (f) H- HO CHO -OH -H CH₂OH H Br H. CH₂ H CH₂ H Br (h) H Br CH₂ H H CH₂ H Br
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Problem 11-57 Order each of the following sets of compounds concerning SN2 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3CH2CH2Cl (a) CH3 CS Scanned with CamScanner Cl CH3CH2CHCH3