Problem 11-56Order each of the following sets of compounds concerning SN1 reactivity. Most reactive=1; Least reactive=3.CH3H3C-C-ClCH3(a)CS Scanned with CamScannerH3C CH3ClNH 21CH3CH2CHCH3

Step 1: Step 2: Step 3: Step 4:

Answered: Problem 11-56 Order each of the…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter7: Alkenes: Structure And Reactivity

Section7.3: Naming Alkenes

Problem 5P

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Problem 11-57 Order each of the following sets of compounds concerning SN2 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3CH2CH2Cl (a) CH3 CS Scanned with CamScanner Cl CH3CH2CHCH3
PROBLEM 5-21 Which of the following compounds are chiral? Draw each compound in its most symmetric con- formation, star (*) any asymmetric carbon atoms, and draw any mirror planes. Label any meso compounds. You may use Fischer projections if you prefer. (a) meso-2,3-dibromo-2,3-dichlorobutane (b) (±)-2,3-dibromo-2,3-dichlorobutane (c) (2R,3S)-2-bromo-3-chlorobutane (d) (2R,3S)-2,3-dibromobutane (e) (R, R)-2,3-dibromobutane (f) H- HO CHO -OH -H CH₂OH H Br H. CH₂ H CH₂ H Br (h) H Br CH₂ H H CH₂ H Br
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PROBLEM 3-24 Draw the most stable conformation of: (a) ethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane (b) 3-isopropyl-1, 1-dimethylcyclohexane
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Problem 3-42 Consider 2-methylbutane (isopentane). Sighting along the C2-C3 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. Problem 3-44 Construct a qualitative potential-energy diagram for rotation about the C-C bond of 1,2-dibromoethane. Which conformation would you expect to be most stable? Label the anti and gauche conformations of 1,2- dibromoethane. Problem 3-45 Which conformation of 1,2-dibromoethane (Problem 3-44) would you expect to have the largest dipole moment? The observed dipole moment of 1,2-dibromoethane is µ = 1.0 D. What does this tell you about the actual conformation of the molecule?
3-33 Which of the following structures represent the same compound? Which ones represent different compounds? CH3 CH3 CH3 H H H H H 1 1 H-C-C-C-C H H 1 (a) H-C-C-C-H H H CH₂ (b) (d) (e) (f) CH3 CH3 H. H H ..H Η CH3 H CH3 H CH3 CH3 CH3 CH3 CH3 H H H CH3 CH3 H3C. H₂C H CH₂ H HHH H H H H ad at CH,_ _H CH3 CH3 | -H H-C-C-H_H-C-C-H H-C-C-H CH₂ H a H CH3 H CH3 H CH3 H CH3 H₂C CH3 H CH3 H H CH3 H₂CH, H CH3 CH3 CH 3 CH₂ H H H3C. H H | | HH CH₂ H CH3 H H CH₂ H H H CH₂ -CH3 -CH(CH3)2 H3C. H H CH3 1 H CH3 CH₂CH3 H
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CHEM2323 E Tt PS CH03 Draw and name all monobromo derivatives of pentane, C5H11Br. Problem 3-33 Name: Draw structures for the following: (a) 2-Methylheptane (d) 2,4,4-Trimethylheptane Problem 3-35 (b) 4-Ethyl-2,2-dimethylhexane (e) 3,3-Diethyl-2,5-dimethylnonane (c) 4-Ethyl-3,4-dimethyloctane 2 (f) 4-Isopropyl-3-methylheptane KNIE>

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Problem 11-56 Order each of the following sets of compounds concerning SN1 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3 (a) CS Scanned with CamScanner H3C CH3 Cl NH 2 1 CH3CH2CHCH3