14. Draw all of the products expected for the following reaction. Circle the products expected to predominate when the reaction is heated to 40 °C. EXPLAIN your choice. (12 points) HBr ? Br -11
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- 1. Propose a mechanism for the following reaction. (10 points) Br₂ OH Br 29. on HBrPlease draw the arrow mechanism for the reaction below5. Using curved arrows show the mechanism for the hydrohalogenation for the following reaction. Show how the two possible intermediate products are formed and explain why only one product proceeds to form the product. Clearly indicate attack of electrons and full and partial (8) charges. H-Br Br H-Br Product Intermediate Products
- 5. For the following two-step reaction sequence, use curved arrows to clearly indicate electron movement in each step. (5 points) CH30 +] OCH3 ÓCH33. (10 points) Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. (C6H5)3P= C- o-C2H510. Draw a line structure for each organic product of the reaction shown below, including relevant stereochemistry. Do not draw multiple structures of the same compound. (6 pts) SN2 + HBr ???? OH
- th ante 3. Draw and name the product (s) of each incomplete reaction below and identify the type of reaction that is occurring (if possible). [10T] Reaction CH2 CH3 + HF H3C ΤΥPE: H,SO, + H20 H3C CH2 CH3 ΤΥΡE: CH2 H3C. CH2 .C + [H] > CH2 CH3 ΤΥΡΕ: OH H,SO, CH H3C CH3 TYPE:Propose a reasonable mechanism for the following reaction using curved arrows to indicate the flow of electrons or formation and breaking of bonds. Identify the pericyclic reactions involved in the mechanism. (7 points) 10.02.00. N N 45 °CFor the reaction shown below, draw the structure(s) of the major product(s) expected. Do not draw duplicate structures of the same molecule as different products. (Do this on a piece of paper, then scan into PDF file and upload.) H,SO,/SO3 5 deg C CH3