Answered: A Fe (111). 02, 2e 2H -H20 cys. Fe cys…

A Fe (111). 02, 2e 2H -H20 cys. Fe cys t. HN 0 HO. 0 Sill. Fe(v) Cys HN 0 он OH O он но OH O. 成 ...Fe. I 1. Cys HN он но OH. O он

Curren'S Math For Meds: Dosages & Sol

11th Edition

ISBN:9781305143531

Author:CURREN

Publisher:CURREN

Chapter10: Reconstitution Of Powdered Drugs

Section: Chapter Questions

Problem 3.6P

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Question

Can you check if I did it correctly

what us a step-by-step mechanism of the formation of the epoxy intermediate, starting with the Cytochrome P450 high valent iron-oxo intermediate as your oxidant

The drug Atorvastatin (brand name is Lipitor, used to lower cholesterol levels) is shown below. This molecule is rapidly metabolized (+ = 14 hours) by Cytochrome P450 to a para-hydroxy derivative of the benzene ring attached to the amide group (this is followed by reaction of the acid group with glucose and excretion via bile). The Cytochrome P450-catalyzed metabolic process occurs via an epoxide intermediate.

A
Fe (111).
02, 2e 2H
-H20
cys.
Fe
cys
t.
HN
0
HO.
0
Sill.
Fe(v)
Cys
HN
0
он
OH O
он
но
OH O.
成
...Fe. I
1.
Cys
HN
он
но
OH. O
он

Chemical pathways by which living things function, especially those that provide cellular energy, such as the transformation of energy from food into the energy of ATP. Metabolism also focuses on chemical pathways involving the synthesis of new biomolecules and the elimination of waste.

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