Please solve the following practice chemical thermodynamics problem in detail. 6.12* (a) Given that the Helmholtz energy can be written asA = -Nsystem KBT In 2Obtain simplified expressions for both A and S of an Einstein solid.(b) Show that the entropy approaches 0 as the temperature approaches 0 in sucha solid.

(a)- (i) Hemholtz Free Energy (A) :- Given that :- A = -NsystemKBT lnZHere, Z is partition…

Answered: 6.12* (a) Given that the Helmholtz…

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

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Chapter17: Statistical Thermodynamics: Introduction

Section: Chapter Questions

Problem 17.17E

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6.12* (a) Given that the Helmholtz energy can be written as A = -Nsystem KBT In 2 Obtain simplified expressions for both A and S of an Einstein solid. (b) Show that the entropy approaches 0 as the temperature approaches 0 in such a solid.