8.37 The diatomic cations Br₂+ and 12+ are both known.a. On the basis of the molecular orbital model, what wouldyou predict for the bond orders of these ions? Wouldyou predict these cations to have longer or shorter bondsthan the corresponding neutral diatomic molecules?b. Br2 is red, and 12+ is bright blue. What electronic tran-sition is most likely responsible for absorption in theseions? Which ion has the more closely spaced HOMOand LUMO?c. 12 is violet, and I2+ is blue. On the basis of frontier orbitals(identify them), account for the difference in their colors.

In conclusion- The changing in color is based on the energy increasing between LUMO and HOMO. -…

Answered: 8.37 The diatomic cations Br₂+ and 12+…

Chemistry

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ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter9: Covalent Bonding: Orbitals

Section: Chapter Questions

Problem 8ALQ: What are the relationships among bond order, bond energy, and bond length? Which of these quantities...

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(20). Subject:- Chemistry
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