CHEMISTRY THE CENTRAL SCIENCE >EBOOK<14th EditionBrown Publisher: PEARSONISBN: 9780136873891
CHEMISTRY THE CENTRAL SCIENCE >EBOOK<
Solutions for CHEMISTRY THE CENTRAL SCIENCE >EBOOK<
Problem 1E:
The reaction between reactant A (blue spheres) and reactant B (red spheres) is shown in the...Problem 2E:
The following diagram shows the combination reaction between hydrogen, H2,and carbon monoxide, CO,...Problem 3E:
3.3 The following diagram represents the collection of elements formed by a decomposition...Problem 4E:
3.4 The following diagram represents the collection of CO2 and H2O molecules formed by...Problem 5E:
Glycine, an amino acid used by organisms to make proteins, is represented by the following molecuar...Problem 6E:
The following diagram represents a high-temperature reaction between CH4 and H20. Based on this...Problem 7E:
3.7 Nitrogen (N2) and hydrogen (H2) react to form ammonia (NH3). Consider the mixture of N2 and H2...Problem 8E:
3.8 Nitrogen monoxide and oxygen react to form nitrogen dioxide. Consider the mixture of NO and O2...Problem 9E:
Write "true" or "false" for each statement. a. We balance chemical equations as we do because energy...Problem 10E:
A key step in balancing chemical equations is correctly identifying the formulas of the reactant...Problem 12E:
Balance the following equations 3. Li(s) + N2(g) -> Li3N(s) b. TiCL4,(l) + H2O(l) -(TiO2(g) +...Problem 13E:
3.13 Balance the following equations:
A14C3(s) + H2O(l) —> A1(OH)3 (s) + CH4 (g)
C5H10O2(l) + O2(g)...Problem 14E:
3.14 Balance the following equations:
a. Ca3P2(s) +H2O(1) → Ca(OH)2(aq) PH3(g)
b Al(OH)3(s) +...Problem 15E:
3.15 Write balanced chemical equations corresponding to each of the following descriptions
a....Problem 18E:
318
a. When a compound containing C, H, and O is completely combusted in air, what reactant besides...Problem 19E:
Write a balanced chemical equation for the reaction that occurs when a. Mg(s) reacts with C12(g) b....Problem 20E:
3.20 Write a balanced chemical equation for the reaction that occurs when
a. titanium metal reacts...Problem 21E:
Balance the following equations and indicate whether they are combination, decomposition, or...Problem 22E:
Balance the following equations and indicate whether they are combination, decomposition, or...Problem 23E:
Determine the formula weights of each of the following compounds: 3. nitric acid, HNO3; b. MO“ 0....Problem 24E:
3.24 Determine the formula weights of each of the following compounds:
a. nitrous oxide, N20, known...Problem 25E:
Calculate the percentage by mass of oxygen in the following compounds: 3. morphine, Cl7H19No3; b....Problem 26E:
Calculate the percentage by mass of the indicated element in the followung compounds: a. carbon in...Problem 27E:
Based on the following structural formulas, calculate the percentage of carbon by mass present in...Problem 28E:
Calculate the percentage of carbon by mass In each of the compounds represented by the following...Problem 29E:
Write "true' or 'Yalse' for each statement a- A mole of horses contain a mole of horse legs- b. A...Problem 30E:
a. What is the mass, in grams, of one mole of 12C? b. How many carbon atoms are present in one mole...Problem 31E:
Without doing any detailed calculations (but using a periodic table to give atomic weights), rank...Problem 32E:
Without doing any detailed calculations {but using a periodic table to give atomic weights), rank...Problem 33E:
What is the mass, m Iqlograms, of an Avogadro“s number of people, If the average mass of a person is...Problem 34E:
If Avogadro’s number of pennies is divided equally among the 321 million men, women, and children in...Problem 35E:
Calculate the following quantities: a. mass, in grams, of 0.105 mol sucrose (C12H22O11) b. moles of...Problem 36E:
Calculate the following quantities: a. mass, in grams, of 1.50 x 10- 2 mol CdS b. number of moles of...Problem 37E:
a. What is the mass, in grams, of 2.50 x 10-3 mol of ammonium phosphate? b. How many moles of...Problem 38E:
a. What is the mass, in grams, of 1.223 mol of iron(lll) sulfate? b. How many moles of ammonium ions...Problem 39E:
339 The molecular formula of allicin, the compound responsible for the characteristic smell of...Problem 40E:
3.40 The molecular formula of aspartame, the artificial sweetener marketed as NutraSweet®, is...Problem 41E:
3.41 A sample of glucose, C6H12O6, contains 1.250 x 1021 carbon atoms-
a. How many atoms of...Problem 42E:
A sample of the male sex hormone testosterone, C19H28O2, contains 3.88 x 1021 hydrogen atoms a. How...Problem 43E:
343 The allowable concentration level of vinyl chloride, C2H3Cl, in the atmosphere in a chemical...Problem 44E:
At least 25 g oftetrahydrocannabinol (THC), the active ingredient m marijuana, IS required to...Problem 45E:
Give the empirical formula of each of the following compounds if a sample contains a. 0-0130 mol (3,...Problem 46E:
Determine the empirical formula of each of the following compounds if a sample contains 3. 0-104 mol...Problem 47E:
Determine the empirical formulas of the compounds with the following compositions by mass 3. 10.4%...Problem 48E:
Determine the empirical formulas of the compounds with the following compositions by mass. 3. 55,395...Problem 49E:
3.49 A compound whose empirical formula is XF3 consists of 65% F by mass. What is the atomic mass...Problem 51E:
3.51 What is the molecular formula of each of the following compounds?
3. Empirical formula CH2,...Problem 52E:
What is the molecular formula of each of the following compounds? a. empirical formula HCO2, molar...Problem 53E:
Determine the empirical and molecular formulas of each of the following substances: a. Styrene, a...Problem 54E:
Determine the empirical and molecular formulas of each of the following substances: a. Ibuprofen, a...Problem 55E:
a. Combustion analysis of toluene, a common organic solvent, gives 5.86 mg of 002 and 1.37 mg of...Problem 56E:
a. The characteristic odor of pineapple is due to ethyl butyrate, a compound containing carbon,...Problem 57E:
3.57 Valproic acid, used to treat seizures and bipolar disorder; is composed of C, H, and Q A...Problem 58E:
Propenoic acid, C3H4O2, is a reactive organic liquid that is used in the manufacturing of plastics,...Problem 59E:
3.59 Washing soda, a compound used to prepare hard water for washing laundry, is a hydrate, which...Problem 60E:
3.60 Epsom salts, a strong laxative used in veterinary medicine, is a hydrate, which means that a...Problem 61E:
f 3461 Hydrofluoric acid, HF(aq), cannot be stored in glass bottles because compounds called...Problem 62E:
The reaction between potassium superoxide, KO2, and CO2, 4 KO2 + 2 CO2? 2K2CO3 + 3 02 is used as a...Problem 63E:
3,63 Several brands of antacids use Al(OH)3 to react with stomach acid, which contains primarily...Problem 64E:
3.64 An iron ore sample contains Fe2O3 together with other substances. Reaction of the ore with CO...Problem 65E:
Aluminum sulfides reacts with water to form aluminum hydroxide and hydrogen sulfide. a. Write the...Problem 66E:
Calcium hydride reacts with water to form calcium hydroxide and hydrogen gas. a. Write a balanced...Problem 67E:
3.67 Automotive air bags infilate when sodium azide, NaN3 rapidly decomposes to its component...Problem 68E:
The complete combustion of octane, Cngs, a component of gasoline, proceeds as follows: 2 C8H18(l)+...Problem 69E:
3.69 A piece of aluminum foil 1.00 cm2 and 0.550-mm thick is allowed to react with bromine to form...Problem 70E:
Detonation of nitroglycerin proceeds as follows: a. If a sample containing 2.00 mL of nitroglycerin...Problem 71E:
3.71 The combustion of one mole of liquid ethanol, CH3CH2OH, produces 1367 KJ of heat.
Calculate...Problem 72E:
The combustion of one mole of liquid octane, CH3(CH2)6CH3 produces 5470 U of heat Calculate how much...Problem 73E:
a. Define the terms limiting reactant and excess reactant b. Why are the amounts of products formed...Problem 74E:
Define the terms theoretical yield, actual yield, and percent yield b. Why is the actual yield in a...Problem 75E:
3-75 Consider the mixture of ethanol, C2H5OH, and O2 shown in the accompanying diagram.
a Write a...Problem 76E:
Consider the mixture of propane, C3H8, and O2 shown here. Write a balanced equation for the...Problem 79E:
The fizz produced when an Alka-Seltzer tablet is dissolved in water is due to the reaction between...Problem 80E:
One of the steps in the commercial procas for converting ammonia to nitric acid is the conversion of...Problem 81E:
Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution...Problem 82E:
Solutions of sulfuric acid and Iead (ll) acetate react to form solid lead(ll) sulfate and a solution...Problem 83E:
When benzene (C6H6) reacts with bromine (Br2), bromobenzene (C6H5Br) is obtained: C6H5 + br2 C6H5Br...Problem 84E:
When ethane (C6H6) reacts with chlorine (Cl2), the main product is C2H5Cl, but other products...Problem 85E:
3.85 Hydrogen sulfide is an impurity in natural gas that must be removed. One common removal method...Problem 86AE:
386 When hydrogen sulfide gas is bubbled into a solution of sodium hydroxide, the reaction forms...Problem 87AE:
387 Write the balanced chemical equations for
a. the complete combustion of acetic acid (CH3COOH),...Problem 88AE:
If 1.5 mol C2H5OH, 1.5 mol C3H8, and 1.5 mol CH3CH2COCH3 are completely combusted in oxygen, which...Problem 89AE:
3.89 The effectiveness of nitrogen fertilizers depends on both their ability to deliver nitrogen to...Problem 90AE:
3.90
a. The molecular formula of acetylsalicylic acid (aspirin), one of the most common pain...Problem 91AE:
Very small semiconductor crystals, composed of approximately 1000 to 10,000 atoms, are palled...Problem 92AE:
a. One molecule of the antibiotic penicillin G has a mass of 5.342 x 10'21 g. What is the molar mass...Problem 93AE:
Serotonin is a compound that conducts nerve impulses in the brain. It contains 68.296 0, 6.86% H,...Problem 94AE:
3.94 The koala dines exclusively on eucalyptus leaves Its digestive system detoxifies the...Problem 95AE:
3.95 Vanillin, the dominant flavoring in vanilla, contains C, H, and 0. When 1.05 g of this...Problem 96AE:
3.96 An organic compound was found to contain only C, H, and Cl. When a 1.50-g sample of...Problem 97AE:
3.97 A compound, KBrO,, where x is unknown, is analyzed and found to contain 52-92% Br. What is the...Problem 98AE:
398 An element X forms an iodide (X13) and a chloride (XCl3). The iodide is quantitatively convened...Problem 99AE:
A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of...Problem 100AE:
3.100 A chemical plant uses electrical energy to decompose aqueous solutions of NaCI to give Cl2...Problem 101AE:
The fat stored in a camel’s hump is a source of both energy and water. Calculate the mass of H20...Problem 102AE:
3.102 When hydrocarbons are burned in a limited amount of air, both CO and CO, form. When 0-450 9...Problem 103AE:
3.103 A mixture of N2(g) and H2(g) reacts in a closed container to form ammonia, NH3(g). The...Problem 104AE:
3.104 A mixture containing KClO3, K2CO3, KHCO3, and KCI was heated, producing
CO2, O2, and H2O...Problem 105AE:
When a mixture of 10.0 g of acetylene (C2H2) and 10.0 g of oxygen (O2) is ignited, the resulting...Problem 106IE:
3.106 The semiconductor gallium arsenide, GaAs, is used in high-speed integrated circuits,...Problem 107IE:
3.107 Paclitaxel, C47H51NO14, is an anticancer compound that is difficult to make in the lab. One...Problem 108IE:
3.108 Consider a sample of calcium carbonate in the form of a cube measuring 2.005 in. on each...Problem 109IE:
3.109
a. You are given a cube of silver metal that measures 1.000 cm on each edge. The density of...Problem 110IE:
3.110
a. If an automobile travels 225 mi with a gas mileage of 20.5 mi/gal, how many kilograms of...Problem 112IE:
3.112 A particular coal contains 2.596 sulfur by mass. When this coal is burned at a power plant,...Problem 113IE:
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram...Problem 114IE:
3.114 The source of oxygen that drives he internal combustion engine in an automobile air. Air is...Browse All Chapters of This Textbook
Chapter 1 - Introduction: Matter, Energy, And MeasurementChapter 1.2 - Classifications Of MatterChapter 1.5 - Units Of MeasurementChapter 1.6 - Uncertainty In MeasurementChapter 1.7 - Dimensional AnalysisChapter 2 - Atoms, Molecules, And IonsChapter 2.3 - The Modern View Of Atomic StructureChapter 2.4 - Atomic WeightsChapter 2.5 - The Periodic TableChapter 2.6 - Molecules And Molecular Compounds
Chapter 2.7 - Ions And Ionic CompoundsChapter 2.8 - Naming Inorganic CompoundsChapter 2.9 - Some Simple Organic CompoundsChapter 3 - Chemical Reactions And Reaction StoichiometryChapter 3.1 - Chemical EquationsChapter 3.2 - Simple Patterns Of Chemical ReactivityChapter 3.3 - Formula WeightsChapter 3.4 - Avogadro's Number And The MoleChapter 3.5 - Empirical Formulas From AnalysesChapter 3.6 - Quantitative Information From Balanced EquationsChapter 3.7 - Limiting ReactantsChapter 4 - Reactions In Aqueous SolutionChapter 4.1 - General Properties Of Aqueous SolutionsChapter 4.2 - Precipitation ReactionsChapter 4.3 - Acids, Bases, And Neutralization ReactionsChapter 4.4 - Oxidation-reduction ReactionsChapter 4.5 - Concentrations Of SolutionsChapter 4.6 - Solutions Stoichiometry And Chemical AnalysisChapter 5 - ThermochemistryChapter 5.2 - The First Law Of ThermodynamicsChapter 5.3 - EnthalpyChapter 5.4 - Enthalpies Of ReactionChapter 5.5 - CalorimetryChapter 5.6 - Hess's LawChapter 5.7 - Enthalpies Of FormationChapter 5.8 - Bond EnthalpiesChapter 5.9 - Foods And FuelsChapter 6 - Electronic Structure Of AtomsChapter 6.1 - The Wave Nature Of LightChapter 6.2 - Quantized Energy And PhotonsChapter 6.3 - Line Spectra And The Bohr ModelChapter 6.4 - The Wave Behavior Of MatterChapter 6.5 - Quantum Mechanics And Atomic OrbitalsChapter 6.8 - Electron ConfigurationsChapter 6.9 - Electron Configurations And The Periodic TableChapter 7 - Periodic Properties Of The ElementsChapter 7.3 - Sizes Of Atoms And IonsChapter 7.4 - Ionization EnergyChapter 7.6 - Metals, Nonmetals, And MetalloidsChapter 7.7 - Trends Of Group 1a And Group 2a MetalsChapter 8 - Basic Concepts Of Chemical BondingChapter 8.2 - Ionic BondingChapter 8.3 - Covalent BondingChapter 8.4 - Bond Polarity And ElectronegativityChapter 8.5 - Drawing Lewis StructuresChapter 8.6 - Resonance StructuresChapter 8.7 - Exceptions Of The Octet RuleChapter 9 - Molecular Geometry And Bonding TheoriesChapter 9.2 - The Vsepr ModelChapter 9.3 - Molecular Shape And Molecular PolarityChapter 9.5 - Hybrid OrbitalsChapter 9.6 - Multiple BondsChapter 9.7 - Molecular OrbitalsChapter 9.8 - Bonding In Period 2 Diatomic MoleculesChapter 10 - GasesChapter 10.2 - PressureChapter 10.3 - The Gas LawsChapter 10.4 - The Ideal-gas EquationChapter 10.5 - Further Applications Of The Ideal-gas EquationChapter 10.6 - Gas Mixtures And Partial PressuresChapter 10.7 - The Kinetic-molecular Theory Of GasesChapter 10.8 - Molecular Effusion And DiffusionChapter 10.9 - Real Gases: Deviations From Ideal BehaviorChapter 11 - Liquids And Intermolecular ForcesChapter 11.2 - Intermolecular ForcesChapter 11.3 - Select Properties Of LiquidsChapter 11.4 - Phase ChangesChapter 11.5 - Vapor PressureChapter 11.6 - Phase DiagramChapter 11.7 - Liquid CrystalsChapter 12 - Solids And Modern MaterialsChapter 12.3 - Metallic SolidsChapter 12.5 - Ionic SolidChapter 12.7 - Covalent-network SolidsChapter 13 - Properties Of SolutionsChapter 13.3 - Factor Affecting SolubilityChapter 13.4 - Expressing Solution ConcentrationChapter 13.5 - Colligative PropertiesChapter 14 - Chemical KineticsChapter 14.2 - Reaction RatesChapter 14.3 - Concentration And Rate LawsChapter 14.4 - The Change Of Concentration With TimeChapter 14.5 - Temperature And RateChapter 14.6 - Reaction MechanismsChapter 15 - Chemical EquilibriumChapter 15.2 - The Equilibrium ConstantChapter 15.3 - Understanding And Working With Equilibrium ConstantChapter 15.4 - Heterogeneous EquilibriumChapter 15.5 - Calculating Equilibrium ConstantsChapter 15.6 - Applications Equilibrium ConstantsChapter 15.7 - Le Chatelier's PrincipleChapter 16 - Acid—base EquilibriumChapter 16.2 - Bronsted-lowery Acids And BasesChapter 16.3 - The Autoionization Of WaterChapter 16.4 - The Ph ScaleChapter 16.5 - Strong Acids And BasesChapter 16.6 - Weak AcidsChapter 16.7 - Weak BasesChapter 16.8 - Relation Between Ka And KbChapter 16.9 - Acid-base Properties Of Salt SolutionChapter 16.10 - Acid-base Behavior And Chemical StructureChapter 17 - Additional Aspects Of Aqueous EquilibriumChapter 17.1 - The Common Ion EffectChapter 17.2 - BuffersChapter 17.3 - Acid-base TitrationsChapter 17.4 - Solubility EquilibriaChapter 17.5 - Factor That Affect SolubilityChapter 17.6 - Precipitation And Separation Of IonsChapter 18 - Chemistry Of The EnvironmentChapter 18.1 - Earth's AtmosphereChapter 18.2 - Human Activities And Earth AtmosphereChapter 19 - Chemical ThermodynamicsChapter 19.1 - Spontaneous ProcessesChapter 19.2 - Entropy And Second Law Of ThermodynamicsChapter 19.3 - The Molecular Interpretation Of Entropy And The Third Law Of ThermodynamicsChapter 19.4 - Entropy Changes In Chemical ReactionsChapter 19.5 - Gibbs Free EnergyChapter 19.6 - Free Energy And TemperatureChapter 19.7 - Free Energy And Equilibrium ConstantChapter 20 - ElectrochemistryChapter 20.1 - Oxidation States And Oxidation-reduction ReactionsChapter 20.2 - Balancing Redox EquationsChapter 20.3 - Voltaic CellsChapter 20.4 - Cell Potentials Under Standard ConditionsChapter 20.5 - Free Energy And Redox ReactionsChapter 20.6 - Cell Potentials Under Nonstandard ConditionsChapter 20.9 - ElectrolysisChapter 21 - Nuclear ChemistryChapter 21.1 - Radioactivity And Nuclear EquationsChapter 21.2 - Patterns Of Nuclear StabilityChapter 21.3 - Nuclear TransmutationsChapter 21.4 - Rates Of Radioactive DecayChapter 21.6 - Energy Changes In Nuclear ReactionsChapter 22 - Chemistry Of The NonmetalsChapter 22.1 - Periodic Trends And Chemical ReactionsChapter 22.3 - Group 8a:the Noble GasesChapter 22.4 - Group 7a:the HalogensChapter 22.7 - NitrogenChapter 22.10 - The Other Group 4a:elements:si,ge,sn And PbChapter 23 - Transition Metals And Coordination ChemistryChapter 23.2 - Transition-metals ComplexesChapter 23.4 - Nomenclature And Isomerism In Coordination ChemistryChapter 23.5 - Color And Magnetism In Coordination ChemistryChapter 23.6 - Crystal-field TheoryChapter 24 - The Chemistry Of Life: Organic And Biological ChemistryChapter 24.2 - Introduction To HydrocarbonsChapter 24.3 - Alkenes,alkynes,and Aromatic HydrocarbonsChapter 24.4 - Organic Functional GroupsChapter 24.7 - Proteins
Sample Solutions for this Textbook
We offer sample solutions for CHEMISTRY THE CENTRAL SCIENCE >EBOOK< homework problems. See examples below:
The figure (i) represents the space filling molecular models of two spheres attached to each other...The sign of the electric charge on the particle is negative in the given diagram. This experiment...Chapter 3, Problem 1EGiven The three salts are named as sodium sulfide, sodium bicarbonate and sodium chloride. The...Chapter 5, Problem 1DEChapter 6, Problem 1DEThe alkali metals such as rubidium and cesium which has lower first ionization energies can be used...The heat of hydrogenation of acetylene is −1299.53 kJ/mol and the fuel value of 3.0 mol acetylene is...The energy absorbed by the given compound is calculated by the formula, Energy=Plank's...
The given unknown gas is a noble gas and the difference in molar masses of noble gases is much...The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding....Explanation: The given polymer is first dissolved in the buffer solution. The experiment is...According to Raoult’s law, the vapor pressure of a solution is equal to the product of the mole...Given The chemical equation for the given hypothetical reaction is, aA+bB→cC+dD The reactants...Explanation: The spectrometer is a device which splits light into the array of separate colors which...If the solution is acidic, it changes blue litmus paper into red and there is no change in color for...Explanation: The concentration of NaOH solution is calculated by considering the small volume of the...Explanation: The chemicals involved in fracking operations are hydrochloric acid, sodium chloride,...The relation between the standard free energy change, standard entropy change and standard enthalpy...GivenThe electrical potential output of the cell is 1.50 V . The external device draws the current...Explanation: Pitchblende is a uranium ore with excess amount of UO2 , on oxidation UO2 leads to the...The physical state of the substance depends upon the size of the substance. The size of the atoms...The reaction of the given coordination compound with the solution of AgNO3 solution gives the...Explanation: The buffer solution of hemoglobin is prepared first. This buffer solution of hemoglobin...
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